Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Textbook Question
Chapter 9, Problem 27QRT
A liquid has a ΔvapH of 38.7 kJ/mol and a boiling point of 110 °C at 1 atm pressure. Calculate the vapor pressure of the liquid at 97 °C.
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Q2: Ranking Acidity
a) Rank the labeled protons in the following molecule in order of increasing pKa. Briefly
explain the ranking. Use Table 2.2 as reference.
Ha
Нь
HC
H-N
Ha
OHe
b) Atenolol is a drug used to treat high blood pressure. Which of the indicated N-H bonds is
more acidic? Explain. (Hint: use resonance structures to help)
Name the functional groups on atenolol.
H
H-N
atenolol
Ν
H-N
OH Н
Answer d, e, and f
If the rotational constant of a molecule is B = 120 cm-1, it can be stated that the transition from 2←1:a) gives rise to a line at 120 cm-1b) is a forbidden transitionc) gives rise to a line at 240 cm-1d) gives rise to a line at 480 cm-1
Chapter 9 Solutions
Chemistry: The Molecular Science
Ch. 9.1 - Prob. 9.1CECh. 9.2 - Prob. 9.2CECh. 9.2 - Prob. 9.1PSPCh. 9.2 - What mass (g) of ethanol, CH3CH2OH(), can be...Ch. 9.3 - Prob. 9.3CECh. 9.3 - Prob. 9.4CECh. 9.3 - Prob. 9.3PSPCh. 9.4 - What types of solids are these substances? (a) The...Ch. 9.4 - Prob. 9.5PSPCh. 9.4 - Prob. 9.5E
Ch. 9.4 - Prob. 9.6CECh. 9.4 - Sublimation is an excellent means of purification...Ch. 9.4 - Prob. 9.6PSPCh. 9.4 - Prob. 9.8ECh. 9.4 - Prob. 9.9ECh. 9.5 - Predict which liquid—glycerol, HOCH2CH(OH)CH2OH,...Ch. 9.5 - Prob. 9.11CECh. 9.6 - Crystalline polonium has a primitive cubic unit...Ch. 9.6 - Calculate the unit cell edge length of copper...Ch. 9.6 - Vanadium metal crystallizes in a body-centered...Ch. 9.6 - Prob. 9.13ECh. 9.6 - Prob. 9.14ECh. 9.6 - Prob. 9.9PSPCh. 9.9 - Prob. 9.10PSPCh. 9.9 - The graph below is obtained when a liquid metal is...Ch. 9.9 - Look in Appendix D and compare the electron...Ch. 9.11 - Prob. 9.11PSPCh. 9 - Prob. ISPCh. 9 - Prob. IISPCh. 9 - Prob. IIISPCh. 9 - Prob. 1QRTCh. 9 - Prob. 2QRTCh. 9 - Prob. 3QRTCh. 9 - Prob. 4QRTCh. 9 - Prob. 5QRTCh. 9 - Prob. 6QRTCh. 9 - Which processes are endothermic? (a) Condensation...Ch. 9 - Prob. 8QRTCh. 9 - Prob. 9QRTCh. 9 - Prob. 10QRTCh. 9 - Prob. 11QRTCh. 9 - Prob. 12QRTCh. 9 - Prob. 13QRTCh. 9 - After exercising on a hot summer day and working...Ch. 9 - Prob. 15QRTCh. 9 - The molar vaporization enthalpy of methanol is...Ch. 9 - Prob. 17QRTCh. 9 - Mercury is highly toxic. Although it is a liquid...Ch. 9 - Prob. 19QRTCh. 9 - Prob. 20QRTCh. 9 - Prob. 21QRTCh. 9 - Prob. 22QRTCh. 9 - Prob. 23QRTCh. 9 - Prob. 24QRTCh. 9 - Prob. 25QRTCh. 9 - Prob. 26QRTCh. 9 - A liquid has a vapH of 38.7 kJ/mol and a boiling...Ch. 9 - Prob. 28QRTCh. 9 - The vapor pressure of ethanol, C2H5OH, at 50.0 C...Ch. 9 - Prob. 30QRTCh. 9 - Prob. 31QRTCh. 9 - Prob. 32QRTCh. 9 - Which would you expect to have the higher fusion...Ch. 9 - Prob. 34QRTCh. 9 - Prob. 35QRTCh. 9 - Prob. 36QRTCh. 9 - Prob. 37QRTCh. 9 - Prob. 38QRTCh. 9 - Prob. 39QRTCh. 9 - Prob. 40QRTCh. 9 - Prob. 41QRTCh. 9 - Prob. 42QRTCh. 9 - Prob. 43QRTCh. 9 - Prob. 44QRTCh. 9 - At the critical point for carbon dioxide, the...Ch. 9 - Prob. 46QRTCh. 9 - Prob. 47QRTCh. 9 - On the basis of the description given, classify...Ch. 9 - On the basis of the description given, classify...Ch. 9 - Prob. 50QRTCh. 9 - Prob. 51QRTCh. 9 - Prob. 52QRTCh. 9 - Prob. 53QRTCh. 9 - Prob. 54QRTCh. 9 - Prob. 55QRTCh. 9 - Prob. 56QRTCh. 9 - Prob. 57QRTCh. 9 - Prob. 58QRTCh. 9 - Prob. 59QRTCh. 9 - Prob. 60QRTCh. 9 - Prob. 61QRTCh. 9 - The ionic radii of Cs+ and Cl are 181 and 167 pm,...Ch. 9 - Prob. 63QRTCh. 9 - Prob. 64QRTCh. 9 - Prob. 65QRTCh. 9 - Tungsten has a body-centered cubic unit cell and...Ch. 9 - Prob. 67QRTCh. 9 - Prob. 68QRTCh. 9 - Prob. 69QRTCh. 9 - Prob. 70QRTCh. 9 - Prob. 71QRTCh. 9 - Prob. 72QRTCh. 9 - Prob. 73QRTCh. 9 - Prob. 74QRTCh. 9 - Prob. 75QRTCh. 9 - Prob. 76QRTCh. 9 - Prob. 77QRTCh. 9 - Prob. 78QRTCh. 9 - Prob. 79QRTCh. 9 - Prob. 80QRTCh. 9 - Which substance has the greatest electrical...Ch. 9 - Prob. 82QRTCh. 9 - Prob. 83QRTCh. 9 - Prob. 84QRTCh. 9 - Prob. 85QRTCh. 9 - Prob. 86QRTCh. 9 - What makes a glass different from a crystalline...Ch. 9 - Prob. 88QRTCh. 9 - Prob. 89QRTCh. 9 - Prob. 90QRTCh. 9 - Will a closed container of water at 70 C or an...Ch. 9 - Prob. 92QRTCh. 9 - Prob. 95QRTCh. 9 - Prob. 96QRTCh. 9 - Prob. 97QRTCh. 9 - Prob. 98QRTCh. 9 - Prob. 99QRTCh. 9 - Prob. 100QRTCh. 9 - Prob. 101QRTCh. 9 - Prob. 102QRTCh. 9 - Prob. 103QRTCh. 9 - Consider this information regarding two compounds....Ch. 9 - Prob. 105QRTCh. 9 - Prob. 106QRTCh. 9 - If you get boiling water at 100 C on your skin, it...Ch. 9 - Prob. 108QRTCh. 9 - The normal boiling point of SO2 is 263.1 K and...Ch. 9 - Butane is a gas at room temperature; however, if...Ch. 9 - Prob. 111QRTCh. 9 - Examine the nanoscale diagrams and the phase...Ch. 9 - Consider the phase diagram and heating-curve...Ch. 9 - Prob. 115QRTCh. 9 - Prob. 116QRTCh. 9 - The phase diagram for water over a relative narrow...Ch. 9 - Prob. 118QRTCh. 9 - Prob. 119QRTCh. 9 - Prob. 120QRTCh. 9 - Prob. 121QRTCh. 9 - Prob. 122QRTCh. 9 - Titanium metal crystallizes in a body-centered...Ch. 9 - Prob. 9.ACPCh. 9 - Prob. 9.BCPCh. 9 - Prob. 9.CCP
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