Chemistry: Structure and Properties
1st Edition
ISBN: 9780321834683
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 9, Problem 17E
Interpretation Introduction
To determine: What is an
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Provide photos of models of the following molecules. (Include a key for identification of the atoms)
1,2-dichloropropane
2,3,3-trimethylhexane
2-bromo-3-methybutane
Please draw the structure in the box that is consistent with all the spectral data and
alphabetically label all of the equivalent protons in the structure (Ha, Hb, Hc....) in order to assign all
the proton NMR peaks. The integrations are computer generated and approximate the number of
equivalent protons. Molecular formula: C13H1802
14
13
12
11
10
11 (ppm)
Structure with assigned H peaks
2.08
3.13
A 0.10 M solution of acetic acid (CH3COOH, Ka = 1.8 x 10^-5) is titrated with a 0.0250 M solution of magnesium hydroxide (Mg(OH)2). If 10.0 mL of the acid solution is titrated with 10.0 mL of the base solution, what is the pH of the resulting solution?
Chapter 9 Solutions
Chemistry: Structure and Properties
Ch. 9 - Prob. 1SAQCh. 9 - What mass (in grams) of Mg(NO3)2 is present in 145...Ch. 9 - Prob. 3SAQCh. 9 - Potassium iodide reacts with lead(ll) nitrate in...Ch. 9 - Which solution forms a precipitate when mixed with...Ch. 9 - What is the net ionic equation for the reaction...Ch. 9 - What is the net ionic equation for the reaction...Ch. 9 - What is the net ionic equation for the reaction...Ch. 9 - What is the oxidation state of carbon in CO32-? +3...Ch. 9 - Prob. 10SAQ
Ch. 9 - Prob. 11SAQCh. 9 - What is an aqueous solution? What is the...Ch. 9 - What is molarity? How is it useful?Ch. 9 - Explain how a strong electrolyte, a weak...Ch. 9 - What is an acid? Explain the difference between a...Ch. 9 - What does it mean for a compound to be soluble?...Ch. 9 - What are the solubility rules? How are they...Ch. 9 - Which cations and anions form compounds that are...Ch. 9 - What is a precipitation reaction? Give an example.Ch. 9 - How can you predict whether a precipitation...Ch. 9 - Explain how a molecular equation, a complete ionic...Ch. 9 - Prob. 11ECh. 9 - Prob. 12ECh. 9 - Prob. 13ECh. 9 - Explain the principles behind an acid-base...Ch. 9 - Prob. 15ECh. 9 - Which reactant types give rise to gas-evolution...Ch. 9 - Prob. 17ECh. 9 - What are oxidation states? How can oxidation...Ch. 9 - What happens to a substance when it becomes...Ch. 9 - In a redox reaction, which reactant is the...Ch. 9 - Prob. 21ECh. 9 - Prob. 22ECh. 9 - What is the molarity of NO3- in each solution?...Ch. 9 - What is the molarity of Cl- in each solution?...Ch. 9 - Prob. 25ECh. 9 - Prob. 26ECh. 9 - A laboratory procedure calls for making 400.0 mL...Ch. 9 - Prob. 28ECh. 9 - If 123 mL of a 1.1 M glucose solution is diluted...Ch. 9 - If 3.5 L of a 4.8 M SrCl2 solution is diluted to...Ch. 9 - To what volume should you dilute 50.0 mL of a 12 M...Ch. 9 - Prob. 32ECh. 9 - Consider the precipitation reaction:...Ch. 9 - Consider the reaction:...Ch. 9 - What is the minimum amount of 6.0 M H2SO4...Ch. 9 - What molarity of ZnCl2forms when 25.0 g of zinc...Ch. 9 - You mix a 25.0 mL sample of a 1.20 M potassium...Ch. 9 - Prob. 38ECh. 9 - For each compound (all water soluble), would you...Ch. 9 - Classify each compound as a strong electrolyte or...Ch. 9 - Determine whether each compound is soluble or...Ch. 9 - Prob. 42ECh. 9 - Prob. 43ECh. 9 - Complete and balance each equation. If no reaction...Ch. 9 - Write a molecular equation for the precipitation...Ch. 9 - Write a molecular equation for the precipitation...Ch. 9 - Write balanced complete ionic and net ionic...Ch. 9 - Write balanced complete ionic and net ionic...Ch. 9 - Mercury ions (Hg22+) can be removed from solution...Ch. 9 - Lead ions can be removed from solution by...Ch. 9 - Name each acid. Hl(aq) HNO3(aq) H2CO3(aq)Ch. 9 - Name each acid HCI(aq) HClO2(aq) H2SO4(aq)Ch. 9 - Provide the formula for each acid hydrofluoric...Ch. 9 - Provide the formula for each acid phosphoric acid...Ch. 9 - Write balanced molecular and net ionic equations...Ch. 9 - Write balanced molecular and net ionic equations...Ch. 9 - Complete and balance each acid-base equation...Ch. 9 - Complete and balance each acid-base equation...Ch. 9 - A 25.00-mL sample of an unknown HClO4solution...Ch. 9 - A 30.00-mL sample of an unknown H3PO4 solution is...Ch. 9 - Complete and balance each gas-evolution equation:...Ch. 9 - Prob. 62ECh. 9 - Write a balanced equation for the reaction between...Ch. 9 - Prob. 64ECh. 9 - Assign oxidation states to each atom in each...Ch. 9 - Prob. 66ECh. 9 - Prob. 67ECh. 9 - Prob. 68ECh. 9 - Determine whether or not each reaction is a redox...Ch. 9 - Determine whether or not each reaction is a redox...Ch. 9 - Prob. 71ECh. 9 - Prob. 72ECh. 9 - People often use sodium bicarbonate as an antacid...Ch. 9 - Toilet bowl cleaners often contain hydrochloric...Ch. 9 - Prob. 75ECh. 9 - Prob. 76ECh. 9 - Predict the products and write a balanced...Ch. 9 - Predict the products and write a balanced...Ch. 9 - Prob. 79ECh. 9 - Prob. 80ECh. 9 - Prob. 81ECh. 9 - A solution contains Cr3+ ion and Mg2+ ion. The...Ch. 9 - Find the volume of 0.110 M hydrochloric acid...Ch. 9 - Find the volume of 0.150 M sulfuric acid necessary...Ch. 9 - Treatment of gold metal with BrF3 and KF produces...Ch. 9 - We prepare a solution by mixing 0.10 L of 0.12 M...Ch. 9 - A solution contains Ag +and Hg2+ions. The addition...Ch. 9 - The water in lakes that have been acidified by...Ch. 9 - Recall from Section 8.5 that sodium carbonate is...Ch. 9 - A solution contains one or more of the following...Ch. 9 - A solution contains one or more of the following...Ch. 9 - Prob. 92ECh. 9 - Prob. 93ECh. 9 - Prob. 94ECh. 9 - Prob. 95E
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- Firefly luciferin exhibits three rings. Identify which of the rings are aromatic. Identify which lone pairs are involved in establishing aromaticity. The lone pairs are labeled A-D below.arrow_forwardA 0.10 M solution of acetic acid (CH3COOH, Ka = 1.8 x 10^-5) is titrated with a 0.0250 M solution of magnesium hydroxide (Mg(OH)2). If 10.0 mL of the acid solution is titrated with 10.0 mL of the base solution, what is the pH of the resulting solution?arrow_forwardGiven a complex reaction with rate equation v = k1[A] + k2[A]2, what is the overall reaction order?arrow_forward
- Please draw the structure in the box that is consistent with all the spectral data and alphabetically label all of the equivalent protons in the structure (Ha, Hb, Hc....) in order to assign all the proton NMR peaks. The integrations are computer generated and approximate the number of equivalent protons. Molecular formula: C13H1802 14 13 12 11 10 11 (ppm) Structure with assigned H peaks 2.08 3.13arrow_forwardCHEMICAL KINETICS. One of the approximation methods for solving the rate equation is the steady-state approximation method. Explain what it consists of.arrow_forwardCHEMICAL KINETICS. One of the approximation methods for solving the rate equation is the limiting or determining step approximation method. Explain what it consists of.arrow_forward
- CHEMICAL KINETICS. Indicate the approximation methods for solving the rate equation.arrow_forwardTRANSMITTANCE เบบ Please identify the one structure below that is consistent with the 'H NMR and IR spectra shown and draw its complete structure in the box below with the protons alphabetically labeled as shown in the NMR spectrum and label the IR bands, including sp³C-H and sp2C-H stretch, indicated by the arrows. D 4000 OH LOH H₂C CH3 OH H₂C OCH3 CH3 OH 3000 2000 1500 HAVENUMBERI-11 1000 LOCH3 Draw your structure below and label its equivalent protons according to the peak labeling that is used in the NMR spectrum in order to assign the peaks. Integrals indicate number of equivalent protons. Splitting patterns are: s=singlet, d=doublet, m-multiplet 8 3Hb s m 1Hd s 3Hf m 2Hcd 2Had 1He 鄙视 m 7 7 6 5 4 3 22 500 T 1 0arrow_forwardRelative Transmittance 0.995 0.99 0.985 0.98 Please draw the structure that is consistent with all the spectral data below in the box and alphabetically label the equivalent protons in the structure (Ha, Hb, Hc ....) in order to assign all the proton NMR peaks. Label the absorption bands in the IR spectrum indicated by the arrows. INFRARED SPECTRUM 1 0.975 3000 2000 Wavenumber (cm-1) 1000 Structure with assigned H peaks 1 3 180 160 140 120 100 f1 (ppm) 80 60 40 20 0 C-13 NMR note that there are 4 peaks between 120-140ppm Integral values equal the number of equivalent protons 10.0 9.0 8.0 7.0 6.0 5.0 4.0 3.0 2.0 1.0 0.0 fl (ppm)arrow_forward
- Calculate the pH of 0.0025 M phenol.arrow_forwardIn the following reaction, the OH- acts as which of these? NO2-(aq) + H2O(l) ⇌ OH-(aq) + HNO2(aq)arrow_forwardUsing spectra attached, can the unknown be predicted? Draw the predicition. Please explain and provide steps. Molecular focrmula:C16H13ClOarrow_forward
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