EBK INTRODUCTORY CHEMISTRY: AN ACTIVE L
6th Edition
ISBN: 8220100547508
Author: CRACOLICE
Publisher: Cengage Learning US
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Chapter 9, Problem 10E
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Q4: Rank the relative nucleophilicity of halide ions in water solution and DMF solution,
respectively.
F CI
Br |
Q5: Determine which of the substrates will and will not react with NaSCH3 in an SN2 reaction to
have a reasonable yield of product.
NH2
Br
Br
Br
OH
Br
Q7: Rank the following groups in order of basicity, nucleophilicity, and leaving group ability.
a) H₂O, OH, CH3COOT
b) NH3, H₂O, H₂S
Q8: Rank the following compounds in order of increasing reactivity in a nucleophilic substitution
reaction with CN as the nucleophile.
Br
A
B
NH2
LL
F
C
D
OH
CI
LLI
E
Q9: Complete the missing entities for following reactions (e.g., major product(s), reactants,
and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for
reactions a) to d).
a)
H
"Cl
D
+
-OCH 3
Page 3 of 5
Chapter 9 Solutions
EBK INTRODUCTORY CHEMISTRY: AN ACTIVE L
Ch. 9 - Prob. 1ECh. 9 - Prob. 2ECh. 9 - Prob. 3ECh. 9 - Prob. 4ECh. 9 - Questions 5 through 12: Write the major species in...Ch. 9 - Prob. 6ECh. 9 - Questions 5 through 12: Write the major species in...Ch. 9 - Prob. 8ECh. 9 - Questions 5 through 12: Write the major species in...Ch. 9 - Question 5 through 12: Write the major species in...
Ch. 9 - Question 5 through 12: Write the major species in...Ch. 9 - Question 5 through 12: Write the major species in...Ch. 9 - Questions 13 through 18: For each reaction...Ch. 9 - Questions 13 through 18: For each reaction...Ch. 9 - Prob. 15ECh. 9 - Prob. 16ECh. 9 - Prob. 17ECh. 9 - Questions 13 through 18: For each reaction...Ch. 9 - Questions 19 through 24: For each pair of...Ch. 9 - Prob. 20ECh. 9 - Questions 19 through 24: For each pair of...Ch. 9 - Questions 19 through 24: For each pair of...Ch. 9 - Questions 19 through 24: For each pair of...Ch. 9 - Prob. 24ECh. 9 - Questions 25 through 28: Write the equation for...Ch. 9 - Prob. 26ECh. 9 - Prob. 27ECh. 9 - Prob. 28ECh. 9 - Questions 29 through 36: For each pair of...Ch. 9 - Prob. 30ECh. 9 - Questions 29 through 36: For each pair of...Ch. 9 - Prob. 32ECh. 9 - Questions 29 through36: For each pair of reactants...Ch. 9 - Questions 29 through36: For each pair of reactants...Ch. 9 - Questions 29 through36: For each pair of reactants...Ch. 9 - Questions 29 through 36: For each pair of...Ch. 9 - Write the net ionic equations for the...Ch. 9 - Prob. 38ECh. 9 - Questions 39 through 44: For each pair of...Ch. 9 - Prob. 40ECh. 9 - Questions 39 through 44: For each pair of...Ch. 9 - Prob. 42ECh. 9 - Questions 39 through 44: For each pair of...Ch. 9 - Prob. 44ECh. 9 - Questions 45 through 48: For each pair of...Ch. 9 - Prob. 46ECh. 9 - Questions 45 through 48: For each pair of...Ch. 9 - Prob. 48ECh. 9 - Prob. 49ECh. 9 - Prob. 50ECh. 9 - Prob. 51ECh. 9 - The remaining questions include all types of...Ch. 9 - Prob. 53ECh. 9 - Prob. 54ECh. 9 - Prob. 55ECh. 9 - Prob. 56ECh. 9 - Prob. 57ECh. 9 - Prob. 58ECh. 9 - Prob. 59ECh. 9 - The remaining questions include all types of...Ch. 9 - Prob. 61ECh. 9 - Prob. 62ECh. 9 - Prob. 63ECh. 9 - Prob. 64ECh. 9 - Prob. 65ECh. 9 - Prob. 66ECh. 9 - Prob. 67ECh. 9 - Prob. 68ECh. 9 - Prob. 69ECh. 9 - The remaining questions include all types of...Ch. 9 - Prob. 71ECh. 9 - Prob. 72ECh. 9 - The remaining questions include all types of...Ch. 9 - Prob. 74ECh. 9 - The remaining questions include all types of...Ch. 9 - Prob. 76ECh. 9 - Prob. 77ECh. 9 - Prob. 78ECh. 9 - Prob. 79ECh. 9 - Prob. 80ECh. 9 - Prob. 9.1TCCh. 9 - Write a brief description of the relationships...Ch. 9 - Write a brief description of the relationships...Ch. 9 - Prob. 3CLECh. 9 - Prob. 1PECh. 9 - Prob. 2PECh. 9 - Prob. 3PECh. 9 - Aluminum nitrate and sodium hydroxide solutions...Ch. 9 - A piece of solid zinc is dropped into hydrochloric...Ch. 9 - Chlorine gas is bubbled through a sodium bromide...Ch. 9 - Write the conventional, total ionic, and net ionic...Ch. 9 - Prob. 8PECh. 9 - Prob. 9PECh. 9 - Prob. 10PECh. 9 - Prob. 11PECh. 9 - Prob. 12PECh. 9 - Solutions of hydrobromic acid and barium hydroxide...Ch. 9 - Solutions of hydroiodic acid and sodium fluoride...Ch. 9 - Prob. 15PECh. 9 - Prob. 16PECh. 9 - A nitric acid solution is poured onto solid nickel...Ch. 9 - Prob. 18PECh. 9 - A skill you need for writing net ionic equations...Ch. 9 - Prob. 2ECECh. 9 - Prob. 3ECECh. 9 - Prob. 4ECECh. 9 - Prob. 5ECECh. 9 - Prob. 6ECECh. 9 - A skill you need for writing net ionic equations...Ch. 9 - A skill you need for writing net ionic equations...Ch. 9 - Prob. 9ECECh. 9 - Prob. 10ECECh. 9 - Prob. 11ECECh. 9 - A skill you need for writing net ionic equations...
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- Q10: (a) Propose a synthesis of C from A. (b) Propose a synthesis of C from B. Br Br ...\SCH 3 A B Carrow_forward9: Complete the missing entities for following reactions (e.g., major product(s), reactants, and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for reactions a) to d).arrow_forwardComplete the missing entities for following reactions (e.g., major product(s), reactants, and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for reactions a) to d).arrow_forward
- QUESTION 3: Provide the synthetic steps that convert the starting material into the product (no mechanism required). HO OH NH CH3 multiple steps 요요 H3Carrow_forwardQ6: Predict the effect of the changes given on the rate of the reaction below. CH3OH CH3Cl + NaOCH3 → CH3OCH3 + NaCl a) Change the substrate from CH3CI to CH31: b) Change the nucleophile from NaOCH 3 to NaSCH3: c) Change the substrate from CH3CI to (CH3)2CHCI: d) Change the solvent from CH3OH to DMSO.arrow_forwardQ3: Arrange each group of compounds from fastest SN2 reaction rate to slowest SN2 reaction rate. a) CI Cl فيكم H3C-Cl A B C D Br Br b) A B C Br H3C-Br Darrow_forward
- Q2: Group these solvents into either protic solvents or aprotic solvents. Acetonitrile (CH3CN), H₂O, Acetic acid (CH3COOH), Acetone (CH3COCH3), CH3CH2OH, DMSO (CH3SOCH3), DMF (HCON(CH3)2), CH3OHarrow_forwardSuppose the rate of evaporation in a hot, dry region is 1.76 meters per year, and the seawater there has a salinity of 35 ‰. Assuming a 93% yield, how much salt (NaCl) can be harvested each year from 1 km2 of solar evaporation ponds that use this seawater as a source?arrow_forwardhelparrow_forward
- Explain why only the lone pairs on the central atom are taken into consideration when predicting molecular shapearrow_forward(ME EX1) Prblm #9/10 Can you explain in detail (step by step) I'm so confused with these problems. For turmber 13 can u turn them into lewis dot structures so I can better understand because, and then as well explain the resonance structure part. Thanks for the help.arrow_forwardProblems 19 and 20: (ME EX1) Can you please explain the following in detail? I'm having trouble understanding them. Both problems are difficult for me to explain in detail, so please include the drawings and answers.arrow_forward
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