Which of the compounds would react faster in S N 1 / S N 2 / E1 / E2 has to be identified. Concept Introduction: E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide . The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon . S N 1 Reaction: it is a nucleophilic substitution reaction in which the rate determining step depends on one reactant. S N 2 Reaction: It is a nucleophilic substitution reaction in which the rate determining step depends on both of the molecules involved.

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Answer 1

Question

Chapter 8.9, Problem 21P

(a)

Interpretation Introduction

Interpretation:

Which of the compounds would react faster in SN1/SN2/E1/E2 has to be identified.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

SN1Reaction: it is a nucleophilic substitution reaction in which the rate determining step depends on one reactant.

SN2Reaction: It is a nucleophilic substitution reaction in which the rate determining step depends on both of the molecules involved.

(b)

Interpretation Introduction

Interpretation:

Which of the compounds would react faster in SN1/SN2/E1/E2 has to be identified.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

SN1Reaction: it is a nucleophilic substitution reaction in which the rate determining step depends on one reactant.

SN2Reaction: It is a nucleophilic substitution reaction in which the rate determining step depends on both of the molecules involved.

(c)

Interpretation Introduction

Interpretation:

Which of the compounds would react faster in SN1/SN2/E1/E2 has to be identified.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

SN1Reaction: it is a nucleophilic substitution reaction in which the rate determining step depends on one reactant.

SN2Reaction: It is a nucleophilic substitution reaction in which the rate determining step depends on both of the molecules involved.

(d)

Interpretation Introduction

Interpretation:

Which of the compounds would react faster in SN1/SN2/E1/E2 has to be identified.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

SN1Reaction: it is a nucleophilic substitution reaction in which the rate determining step depends on one reactant.

SN2Reaction: It is a nucleophilic substitution reaction in which the rate determining step depends on both of the molecules involved.

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When 15.00 mL of 3.00 M NaOH was mixed in a calorimeter with 12.80 mL of 3.00 M HCl, both initially at room temperature (22.00 C), the temperature increased to 29.30 C. The resultant salt solution had a mass of 27.80 g and a specific heat capacity of 3.74 J/Kg. What is heat capacity of the calorimeter (in J/C)? Note: The molar enthalpy of neutralization per mole of HCl is -55.84 kJ/mol. Which experimental number must be initialled by the Lab TA for the first run of Part 1 of the experiment? a) the heat capacity of the calorimeter b) Mass of sample c) Ti d) The molarity of the HCl e) Tf

Predict products for the Following organic rxn/s by writing the structurels of the correct products. Write above the line provided" your answer D2 ①CH3(CH2) 5 CH3 + D₂ (adequate)" + 2 mited) 19 Spark Spark por every item. 4 CH 3 11 3 CH 3 (CH2) 4 C-H + CH3OH CH2 CH3 + CH3 CH2OH 0 CH3 fou + KMnDy→ C43 + 2 KMn Dy→→ C-OH ") 0 C-OH 1110 (4.) 9+3 =C CH3 + HNO 3 0 + Heat> + CH3 C-OH + Heat CH2CH3 - 3 2 + D Heat H 3 CH 3 CH₂ CH₂ C = CH + 2 H₂ → 2 2

When 15.00 mL of 3.00 M NaOH was mixed in a calorimeter with 12.80 mL of 3.00 M HCl, both initially at room temperature (22.00 C), the temperature increased to 29.30 C. The resultant salt solution had a mass of 27.80 g and a specific heat capacity of 3.74 J/Kg. What is heat capacity of the calorimeter (in J/C)? Note: The molar enthalpy of neutralization per mole of HCl is -55.84 kJ/mol.

Answer 2

Question

Chapter 8.9, Problem 21P

(a)

Interpretation Introduction

Interpretation:

Which of the compounds would react faster in SN1/SN2/E1/E2 has to be identified.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

SN1Reaction: it is a nucleophilic substitution reaction in which the rate determining step depends on one reactant.

SN2Reaction: It is a nucleophilic substitution reaction in which the rate determining step depends on both of the molecules involved.

(b)

Interpretation Introduction

Interpretation:

Which of the compounds would react faster in SN1/SN2/E1/E2 has to be identified.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

SN1Reaction: it is a nucleophilic substitution reaction in which the rate determining step depends on one reactant.

SN2Reaction: It is a nucleophilic substitution reaction in which the rate determining step depends on both of the molecules involved.

(c)

Interpretation Introduction

Interpretation:

Which of the compounds would react faster in SN1/SN2/E1/E2 has to be identified.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

SN1Reaction: it is a nucleophilic substitution reaction in which the rate determining step depends on one reactant.

SN2Reaction: It is a nucleophilic substitution reaction in which the rate determining step depends on both of the molecules involved.

(d)

Interpretation Introduction

Interpretation:

Which of the compounds would react faster in SN1/SN2/E1/E2 has to be identified.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

SN1Reaction: it is a nucleophilic substitution reaction in which the rate determining step depends on one reactant.

SN2Reaction: It is a nucleophilic substitution reaction in which the rate determining step depends on both of the molecules involved.

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Answer 3

Question

Chapter 8.9, Problem 21P

(a)

Interpretation Introduction

Interpretation:

Which of the compounds would react faster in SN1/SN2/E1/E2 has to be identified.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

SN1Reaction: it is a nucleophilic substitution reaction in which the rate determining step depends on one reactant.

SN2Reaction: It is a nucleophilic substitution reaction in which the rate determining step depends on both of the molecules involved.

(b)

Interpretation Introduction

Interpretation:

Which of the compounds would react faster in SN1/SN2/E1/E2 has to be identified.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

SN1Reaction: it is a nucleophilic substitution reaction in which the rate determining step depends on one reactant.

SN2Reaction: It is a nucleophilic substitution reaction in which the rate determining step depends on both of the molecules involved.

(c)

Interpretation Introduction

Interpretation:

Which of the compounds would react faster in SN1/SN2/E1/E2 has to be identified.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

SN1Reaction: it is a nucleophilic substitution reaction in which the rate determining step depends on one reactant.

SN2Reaction: It is a nucleophilic substitution reaction in which the rate determining step depends on both of the molecules involved.

(d)

Interpretation Introduction

Interpretation:

Which of the compounds would react faster in SN1/SN2/E1/E2 has to be identified.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

SN1Reaction: it is a nucleophilic substitution reaction in which the rate determining step depends on one reactant.

SN2Reaction: It is a nucleophilic substitution reaction in which the rate determining step depends on both of the molecules involved.

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Answer 4

Question

Chapter 8.9, Problem 21P

(a)

Interpretation Introduction

Interpretation:

Which of the compounds would react faster in SN1/SN2/E1/E2 has to be identified.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

SN1Reaction: it is a nucleophilic substitution reaction in which the rate determining step depends on one reactant.

SN2Reaction: It is a nucleophilic substitution reaction in which the rate determining step depends on both of the molecules involved.

(b)

Interpretation Introduction

Interpretation:

Which of the compounds would react faster in SN1/SN2/E1/E2 has to be identified.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

SN1Reaction: it is a nucleophilic substitution reaction in which the rate determining step depends on one reactant.

SN2Reaction: It is a nucleophilic substitution reaction in which the rate determining step depends on both of the molecules involved.

(c)

Interpretation Introduction

Interpretation:

Which of the compounds would react faster in SN1/SN2/E1/E2 has to be identified.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

SN1Reaction: it is a nucleophilic substitution reaction in which the rate determining step depends on one reactant.

SN2Reaction: It is a nucleophilic substitution reaction in which the rate determining step depends on both of the molecules involved.

(d)

Interpretation Introduction

Interpretation:

Which of the compounds would react faster in SN1/SN2/E1/E2 has to be identified.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

SN1Reaction: it is a nucleophilic substitution reaction in which the rate determining step depends on one reactant.

SN2Reaction: It is a nucleophilic substitution reaction in which the rate determining step depends on both of the molecules involved.

Expert Solution & Answer

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Answer 5

Chapter 8.9, Problem 21P

(a)

Interpretation Introduction

Interpretation:

Which of the compounds would react faster in SN1/SN2/E1/E2 has to be identified.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

SN1Reaction: it is a nucleophilic substitution reaction in which the rate determining step depends on one reactant.

SN2Reaction: It is a nucleophilic substitution reaction in which the rate determining step depends on both of the molecules involved.

(b)

Interpretation Introduction

Interpretation:

Which of the compounds would react faster in SN1/SN2/E1/E2 has to be identified.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

SN1Reaction: it is a nucleophilic substitution reaction in which the rate determining step depends on one reactant.

SN2Reaction: It is a nucleophilic substitution reaction in which the rate determining step depends on both of the molecules involved.

(c)

Interpretation Introduction

Interpretation:

Which of the compounds would react faster in SN1/SN2/E1/E2 has to be identified.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

SN1Reaction: it is a nucleophilic substitution reaction in which the rate determining step depends on one reactant.

SN2Reaction: It is a nucleophilic substitution reaction in which the rate determining step depends on both of the molecules involved.

(d)

Interpretation Introduction

Interpretation:

Which of the compounds would react faster in SN1/SN2/E1/E2 has to be identified.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

SN1Reaction: it is a nucleophilic substitution reaction in which the rate determining step depends on one reactant.

SN2Reaction: It is a nucleophilic substitution reaction in which the rate determining step depends on both of the molecules involved.

Answer 6

Chapter 8.9, Problem 21P

(a)

Interpretation Introduction

Interpretation:

Which of the compounds would react faster in SN1/SN2/E1/E2 has to be identified.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

SN1Reaction: it is a nucleophilic substitution reaction in which the rate determining step depends on one reactant.

SN2Reaction: It is a nucleophilic substitution reaction in which the rate determining step depends on both of the molecules involved.

Answer 7

Chapter 8.9, Problem 21P

(a)

Interpretation Introduction

Interpretation:

Which of the compounds would react faster in SN1/SN2/E1/E2 has to be identified.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

SN1Reaction: it is a nucleophilic substitution reaction in which the rate determining step depends on one reactant.

SN2Reaction: It is a nucleophilic substitution reaction in which the rate determining step depends on both of the molecules involved.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Which of the compounds would react faster in SN1/SN2/E1/E2 has to be identified.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

SN1Reaction: it is a nucleophilic substitution reaction in which the rate determining step depends on one reactant.

SN2Reaction: It is a nucleophilic substitution reaction in which the rate determining step depends on both of the molecules involved.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Which of the compounds would react faster in SN1/SN2/E1/E2 has to be identified.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

SN1Reaction: it is a nucleophilic substitution reaction in which the rate determining step depends on one reactant.

SN2Reaction: It is a nucleophilic substitution reaction in which the rate determining step depends on both of the molecules involved.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Which of the compounds would react faster in SN1/SN2/E1/E2 has to be identified.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

SN1Reaction: it is a nucleophilic substitution reaction in which the rate determining step depends on one reactant.

SN2Reaction: It is a nucleophilic substitution reaction in which the rate determining step depends on both of the molecules involved.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Which of the compounds would react faster in SN1/SN2/E1/E2 has to be identified.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

SN1Reaction: it is a nucleophilic substitution reaction in which the rate determining step depends on one reactant.

SN2Reaction: It is a nucleophilic substitution reaction in which the rate determining step depends on both of the molecules involved.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Which of the compounds would react faster in SN1/SN2/E1/E2 has to be identified.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

SN1Reaction: it is a nucleophilic substitution reaction in which the rate determining step depends on one reactant.

SN2Reaction: It is a nucleophilic substitution reaction in which the rate determining step depends on both of the molecules involved.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Which of the compounds would react faster in SN1/SN2/E1/E2 has to be identified.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

SN1Reaction: it is a nucleophilic substitution reaction in which the rate determining step depends on one reactant.

SN2Reaction: It is a nucleophilic substitution reaction in which the rate determining step depends on both of the molecules involved.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 8.1 - Prob. 2P Ch. 8.1 - Does increasing the energy barrier for an SN2...Ch. 8.1 - Arrange the following alkyl bromides in order from...Ch. 8.2 - Prob. 7P Ch. 8.2 - Which reaction in each of the following pairs...Ch. 8.2 - Prob. 9P Ch. 8.2 - Prob. 11P Ch. 8.3 - Draw the substitution products that will be formed...Ch. 8.4 - Arrange the following alkyl halides in order from...Ch. 8.5 - Prob. 14P

Solution Summary: The author explains that E1 reaction is a nucleophilic substitution reaction in which the rate determining step depends on one reactant.

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Chapter 8 Solutions