The conversion of but − 1 − ene into butan − 1 − ol . Interpretation: The conversion of the given reactions is to be stated. Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-markovinokov’s rule. Anti Markovnikov’s rule states that the positive part of acid gets attached to that carbon atom in C=C bond which carries minimum number of hydrogen atoms and the negative part of acid gets attached to that carbon atom in C=C bond which has maximum number of hydrogen atoms.

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Answer 1

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Chapter 8.7A, Problem 8.11P

(a)

Interpretation Introduction

To determine: The conversion of but−1−ene into butan−1−ol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-markovinokov’s rule.

Anti Markovnikov’s rule states that the positive part of acid gets attached to that carbon atom in C=C bond which carries minimum number of hydrogen atoms and the negative part of acid gets attached to that carbon atom in C=C bond which has maximum number of hydrogen atoms.

(b)

Interpretation Introduction

To determine: The conversion of but−1−ene into butane−2−ol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Oxymercuration-demercuration is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

According to Markovnikov’s rule, the positive part of acid gets attached to that carbon atom in C=C bond which carries maximum number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has minimum number of hydrogen atoms.

The general steps followed by Oxymercuration-demercuration reaction are stated below:

Formation of mercurinium ion.

Attack of water on mercurinium ion to give alcohol.

Demercuration

(c)

Interpretation Introduction

To determine: The conversion of 2−bromo−2,4−dimethylpentane into 2,4−dimethylpentan−3−ol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti- Markovnikov’s rule.

Anti Markovnikov’s rule states that the positive part of acid gets attached to that carbon atom in C=C bond which carries minimum number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has maximum number of hydrogen atoms.

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Answer 2

Question

Chapter 8.7A, Problem 8.11P

(a)

Interpretation Introduction

To determine: The conversion of but−1−ene into butan−1−ol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-markovinokov’s rule.

Anti Markovnikov’s rule states that the positive part of acid gets attached to that carbon atom in C=C bond which carries minimum number of hydrogen atoms and the negative part of acid gets attached to that carbon atom in C=C bond which has maximum number of hydrogen atoms.

(b)

Interpretation Introduction

To determine: The conversion of but−1−ene into butane−2−ol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Oxymercuration-demercuration is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

According to Markovnikov’s rule, the positive part of acid gets attached to that carbon atom in C=C bond which carries maximum number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has minimum number of hydrogen atoms.

The general steps followed by Oxymercuration-demercuration reaction are stated below:

Formation of mercurinium ion.

Attack of water on mercurinium ion to give alcohol.

Demercuration

(c)

Interpretation Introduction

To determine: The conversion of 2−bromo−2,4−dimethylpentane into 2,4−dimethylpentan−3−ol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti- Markovnikov’s rule.

Anti Markovnikov’s rule states that the positive part of acid gets attached to that carbon atom in C=C bond which carries minimum number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has maximum number of hydrogen atoms.

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Answer 3

Question

Chapter 8.7A, Problem 8.11P

(a)

Interpretation Introduction

To determine: The conversion of but−1−ene into butan−1−ol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-markovinokov’s rule.

Anti Markovnikov’s rule states that the positive part of acid gets attached to that carbon atom in C=C bond which carries minimum number of hydrogen atoms and the negative part of acid gets attached to that carbon atom in C=C bond which has maximum number of hydrogen atoms.

(b)

Interpretation Introduction

To determine: The conversion of but−1−ene into butane−2−ol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Oxymercuration-demercuration is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

According to Markovnikov’s rule, the positive part of acid gets attached to that carbon atom in C=C bond which carries maximum number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has minimum number of hydrogen atoms.

The general steps followed by Oxymercuration-demercuration reaction are stated below:

Formation of mercurinium ion.

Attack of water on mercurinium ion to give alcohol.

Demercuration

(c)

Interpretation Introduction

To determine: The conversion of 2−bromo−2,4−dimethylpentane into 2,4−dimethylpentan−3−ol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti- Markovnikov’s rule.

Anti Markovnikov’s rule states that the positive part of acid gets attached to that carbon atom in C=C bond which carries minimum number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has maximum number of hydrogen atoms.

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Answer 4

Question

Chapter 8.7A, Problem 8.11P

(a)

Interpretation Introduction

To determine: The conversion of but−1−ene into butan−1−ol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-markovinokov’s rule.

Anti Markovnikov’s rule states that the positive part of acid gets attached to that carbon atom in C=C bond which carries minimum number of hydrogen atoms and the negative part of acid gets attached to that carbon atom in C=C bond which has maximum number of hydrogen atoms.

(b)

Interpretation Introduction

To determine: The conversion of but−1−ene into butane−2−ol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Oxymercuration-demercuration is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

According to Markovnikov’s rule, the positive part of acid gets attached to that carbon atom in C=C bond which carries maximum number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has minimum number of hydrogen atoms.

The general steps followed by Oxymercuration-demercuration reaction are stated below:

Formation of mercurinium ion.

Attack of water on mercurinium ion to give alcohol.

Demercuration

(c)

Interpretation Introduction

To determine: The conversion of 2−bromo−2,4−dimethylpentane into 2,4−dimethylpentan−3−ol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti- Markovnikov’s rule.

Anti Markovnikov’s rule states that the positive part of acid gets attached to that carbon atom in C=C bond which carries minimum number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has maximum number of hydrogen atoms.

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Answer 5

Chapter 8.7A, Problem 8.11P

(a)

Interpretation Introduction

To determine: The conversion of but−1−ene into butan−1−ol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-markovinokov’s rule.

Anti Markovnikov’s rule states that the positive part of acid gets attached to that carbon atom in C=C bond which carries minimum number of hydrogen atoms and the negative part of acid gets attached to that carbon atom in C=C bond which has maximum number of hydrogen atoms.

(b)

Interpretation Introduction

To determine: The conversion of but−1−ene into butane−2−ol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Oxymercuration-demercuration is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

According to Markovnikov’s rule, the positive part of acid gets attached to that carbon atom in C=C bond which carries maximum number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has minimum number of hydrogen atoms.

The general steps followed by Oxymercuration-demercuration reaction are stated below:

Formation of mercurinium ion.

Attack of water on mercurinium ion to give alcohol.

Demercuration

(c)

Interpretation Introduction

To determine: The conversion of 2−bromo−2,4−dimethylpentane into 2,4−dimethylpentan−3−ol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti- Markovnikov’s rule.

Anti Markovnikov’s rule states that the positive part of acid gets attached to that carbon atom in C=C bond which carries minimum number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has maximum number of hydrogen atoms.

Answer 6

Chapter 8.7A, Problem 8.11P

(a)

Interpretation Introduction

To determine: The conversion of but−1−ene into butan−1−ol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-markovinokov’s rule.

Anti Markovnikov’s rule states that the positive part of acid gets attached to that carbon atom in C=C bond which carries minimum number of hydrogen atoms and the negative part of acid gets attached to that carbon atom in C=C bond which has maximum number of hydrogen atoms.

Answer 7

Chapter 8.7A, Problem 8.11P

(a)

Interpretation Introduction

To determine: The conversion of but−1−ene into butan−1−ol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-markovinokov’s rule.

Anti Markovnikov’s rule states that the positive part of acid gets attached to that carbon atom in C=C bond which carries minimum number of hydrogen atoms and the negative part of acid gets attached to that carbon atom in C=C bond which has maximum number of hydrogen atoms.

Answer 8

(b)

Interpretation Introduction

To determine: The conversion of but−1−ene into butane−2−ol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Oxymercuration-demercuration is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

According to Markovnikov’s rule, the positive part of acid gets attached to that carbon atom in C=C bond which carries maximum number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has minimum number of hydrogen atoms.

The general steps followed by Oxymercuration-demercuration reaction are stated below:

Formation of mercurinium ion.

Attack of water on mercurinium ion to give alcohol.

Demercuration

Answer 9

(b)

Interpretation Introduction

To determine: The conversion of but−1−ene into butane−2−ol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Oxymercuration-demercuration is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

According to Markovnikov’s rule, the positive part of acid gets attached to that carbon atom in C=C bond which carries maximum number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has minimum number of hydrogen atoms.

The general steps followed by Oxymercuration-demercuration reaction are stated below:

Formation of mercurinium ion.

Attack of water on mercurinium ion to give alcohol.

Demercuration

Answer 10

(c)

Interpretation Introduction

To determine: The conversion of 2−bromo−2,4−dimethylpentane into 2,4−dimethylpentan−3−ol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti- Markovnikov’s rule.

Anti Markovnikov’s rule states that the positive part of acid gets attached to that carbon atom in C=C bond which carries minimum number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has maximum number of hydrogen atoms.

Answer 11

(c)

Interpretation Introduction

To determine: The conversion of 2−bromo−2,4−dimethylpentane into 2,4−dimethylpentan−3−ol.

Interpretation: The conversion of the given reactions is to be stated.

Concept introduction: Hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti- Markovnikov’s rule.

Anti Markovnikov’s rule states that the positive part of acid gets attached to that carbon atom in C=C bond which carries minimum number of hydrogen atoms and the negative part of acid will attach to that carbon atom in C=C bond which has maximum number of hydrogen atoms.

Answer 12

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Answer 13

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Answer 15

Ch. 8.3A - Predict the major products of the following...Ch. 8.3A - a. When 1 mole of buta-1,3-diene reacts with 1...Ch. 8.3B - Predict the major products of the following...Ch. 8.3B - Show how you would accomplish the following...Ch. 8.4B - Propose a mechanism to show how...Ch. 8.4B - Predict the products of the following hydration...Ch. 8.6 - a. Propose a mochansm fortho following reaction....Ch. 8.6 - Prob. 8.8P Ch. 8.6 - Prob. 8.9P Ch. 8.7A - Prob. 8.10P

Solution Summary: The author explains that hydroboration reaction is a two step reaction, which involves conversion of alkene into alcohol.

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