(A)
Interpretation:
The vapor pressure at
Concept Introduction:
The Peng-Robinson equation is,
Here, molar volume is
The expression of the parameter used in calculation of a for Peng-Robinson EOS is,
The expression to obtain the relative temperature at the critical point is,
Here, system temperature is T.
The expression to obtain the value of
The expression to obtain the value of parameter a at the critical point is,
The expression to obtain the parameter
The expression to obtain the parameter b is,
The expression of compressibility factor is,
The residual properties of A is,
The residual properties of B is,
The expression of fugacity of a compound as described by the Peng-Robinson equation is,
(B)
Interpretation:
The fugacity of saturated vapor at
(C)
Interpretation:
The fugacity of saturated liquid at
(D)
Interpretation:
The fugacity of compressed liquid at
Concept Introduction:
The Poynting equation to obtain fugacity in liquid phase at 500 bar is,
Here, saturated pressure is
(E)
Interpretation:
The normal boiling point.
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Chapter 8 Solutions
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