Organic Chemistry As a Second Language: First Semester Topics
4th Edition
ISBN: 9781119110668
Author: David R. Klein
Publisher: WILEY
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Chapter 8.3, Problem 8.18P
Interpretation Introduction
Interpretation:
The hydroxide ion functions as a base or as a nucleophile in the given mechanistic step has to be identified.
Concept Introduction:
Nucleophile is the one which are capable of donating a pair of electrons. The one which is capable of accepting a pair of electrons are known as electrophiles. The atom that is poor in electron density is an electrophilic center.
The speed at which the nucleophile attacks an electrophile is known as nucleophilicity. In other words, the measure of
Nucleophilicity and Basicity appear parallel to each other in many cases. Water is a weak nucleophile and weak base. Hydroxide ion is a strong nucleophile and strong base. Hydroxide ion can function either as a base or as a nucleophile. If the hydroxide ion removes a proton means then it is acting as a base. If it attacks an electrophile means, then it is acting as a nucleophile.
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Br Br
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-C=C-Br
-CEC-C-C-
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F Br
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Br
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CH3CHFCHFC=CH
C(OH)Br2CHF(CH2)4CH2CH3
CH3(CH2)3CH=CH(CH2)2CH3
Name
1) 3-fluoro, 1-butene
2) 2-heptene
2,3-difluoro-
1-pentene
4) 6-iodo,4-methyl-
2-decyne
5) 4,4-dibromo-
1,2-butandiol
Complete structural formula
F
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Line formula
Condensed structural formula
N
F
CH2=CHCHFCH3
1.
Part 1: Naming Organic Compounds
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H₁C-C-CH3
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Br
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HC-CH-CH-C-OH
5. H₂C-CH-CH₂-OH
7.
OH
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CH
CH₂-CH₂
6.
сно
CH-CH-CH-CH₂-CH₂
H₁₂C-CH-CH-CH-CH₁₂-CH₁₂
8.
OH
Chapter 8 Solutions
Organic Chemistry As a Second Language: First Semester Topics
Ch. 8.2 - Prob. 8.2PCh. 8.2 - Prob. 8.3PCh. 8.2 - Prob. 8.4PCh. 8.2 - Prob. 8.5PCh. 8.2 - Prob. 8.6PCh. 8.2 - Prob. 8.7PCh. 8.2 - Prob. 8.8PCh. 8.2 - Prob. 8.9PCh. 8.2 - Prob. 8.10PCh. 8.2 - Prob. 8.11P
Ch. 8.2 - Prob. 8.12PCh. 8.2 - Prob. 8.13PCh. 8.2 - Prob. 8.14PCh. 8.3 - Prob. 8.15PCh. 8.3 - Prob. 8.16PCh. 8.3 - Prob. 8.17PCh. 8.3 - Prob. 8.18PCh. 8.3 - Prob. 8.19PCh. 8.3 - Prob. 8.20PCh. 8.4 - PROBLEMS Identify the sequence of arrow-pushing...Ch. 8.4 - Prob. 8.23PCh. 8.4 - Prob. 8.24PCh. 8.4 - Prob. 8.25PCh. 8.4 - Prob. 8.26PCh. 8.4 - Prob. 8.27PCh. 8.5 - Prob. 8.29PCh. 8.5 - Prob. 8.30PCh. 8.5 - Prob. 8.31PCh. 8.5 - Prob. 8.32PCh. 8.5 - Prob. 8.33PCh. 8.5 - Prob. 8.34P
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