
General, Organic, and Biochemistry
9th Edition
ISBN: 9780078021541
Author: Katherine J Denniston, Joseph J Topping, Dr Danae Quirk Dorr
Publisher: McGraw-Hill Education
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Chapter 8.2, Problem 8.10Q
Interpretation Introduction
Interpretation:
The concentration of hydroxide ion in the given hydrochloric acid solution has to be calculated.
Concept Introduction:
The equilibrium constant for water is the product of the hydronium and hydroxide ion concentrations and is called the ion product constant for water.
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Interpreting NMR spectra is a skill that often requires some
amount of practice, which, in turn, necessitates access to a
collection of NMR spectra. Beyond Labz Organic Synthesis and
Organic Qualitative Analysis have spectral libraries containing
over 700 1H NMR spectra. In this assignment, you will take
advantage of this by first predicting the NMR spectra for two
closely related compounds and then checking your predictions
by looking up the actual spectra in the spectra library. After
completing this assignment, you may wish to select other
compounds for additional practice.
1. Write the IUPAC names for the following two structures:
Question 2
Question 3
2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
11:14
...
worksheets.beyondlabz.com
3. To check your predictions, click this link for Interpreting
NMR Spectra 1. You will see a list of all the
-
compounds in the spectra library in alphabetical order by
IUPAC name. Hovering over a name in the list will show
the structure on the chalkboard. The four buttons on the
top of the Spectra tab in the tray are used to select the
different spectroscopic techniques for the selected
compound. Make sure the NMR button has been selected.
4. Scroll through the list of names to find the names for the
two compounds you have been given and click on the
name to display the NMR spectrum for each. In the NMR
tables below, list the chemical shift, the splitting, and
the number of hydrogens associated with each peak for
each compound. Compare your answers to your
predictions.
**Not all slots must be filled**
Peak
Chemical Shift (d)
Multiplicity
1
2
3
4
5
О
δα
HO-
H
-Br
δα
HO--
+
+
-Br
[B]
8+
HO-
-Br
δα
न
Chapter 8 Solutions
General, Organic, and Biochemistry
Ch. 8.1 - Classify CH3COO− as a Brønsted-Lowry acid or base,...Ch. 8.1 - Prob. 8.1QCh. 8.1 - Prob. 8.2QCh. 8.1 - Write an equation for the reversible reactions of...Ch. 8.1 - Prob. 8.4QCh. 8.1 - Prob. 8.5QCh. 8.1 - Prob. 8.6QCh. 8.1 - Prob. 8.2PPCh. 8.1 - Analysis of a patient’s blood sample indicated...Ch. 8.1 - Prob. 8.7Q
Ch. 8.1 - The hydroxide ion concentration in a sample of...Ch. 8.2 - Calculate the pH of a 1.0 × 10−4 M solution of...Ch. 8.2 - Calculate the [H3O+] of a solution of HNO3 that...Ch. 8.2 - Calculate the pH corresponding to a 1.0 × 10−2 M...Ch. 8.2 - Calculate the [H3O+] and [OH−] of a potassium...Ch. 8.2 - Prob. 8.8PPCh. 8.2 - Calculate the [H3O+] corresponding to pH =...Ch. 8.2 - Calculate the [OH–] of a 1.0 × 10–3 M solution of...Ch. 8.2 - Prob. 8.10QCh. 8.3 - Calculate the molar concentration of a sodium...Ch. 8.4 - A buffer solution is prepared in such a way that...Ch. 8.4 - Prob. 8.12PPCh. 8.4 - Prob. 8.11QCh. 8.4 - Prob. 8.12QCh. 8.4 - Prob. 8.13QCh. 8.4 - Prob. 8.14QCh. 8.4 - Prob. 8.15QCh. 8.4 - Prob. 8.16QCh. 8.4 - Prob. 8.17QCh. 8.4 - Explain how the pH of blood would change under...Ch. 8.4 - Write the Henderson-Hasselbalch expression for the...Ch. 8.4 - Prob. 8.20QCh. 8 - Prob. 8.21QPCh. 8 - Define a base according to the Arrhenius...Ch. 8 - What are the essential differences between the...Ch. 8 - Why is ammonia described as a Brønsted-Lowry base...Ch. 8 - Classify each of the following as either a...Ch. 8 - Classify each of the following as either a...Ch. 8 - Classify each of the following as either a...Ch. 8 - Classify each of the following as either a...Ch. 8 - Write an equation for the reaction of each of the...Ch. 8 - Write an equation for the reaction of each of the...Ch. 8 - Write the formula of the conjugate acid of CN−.
Ch. 8 - Write the formula of the conjugate acid of Br−.
Ch. 8 - Write the formula of the conjugate base of HI.
Ch. 8 - Write the formula of the conjugate base of HCOOH.
Ch. 8 - Write the formula of the conjugate acid of NO3−.
Ch. 8 - Write the formula of the conjugate acid of F−.
Ch. 8 - Which is the stronger base, NO3− or CN−?
Ch. 8 - Prob. 8.38QPCh. 8 - Prob. 8.39QPCh. 8 - Which is the stronger base, F− or CH3COO−?
Ch. 8 - Identify the conjugate acid-base pairs in each of...Ch. 8 - Identify the conjugate acid-base pairs in each of...Ch. 8 - Distinguish between the terms acid-base strength...Ch. 8 - Label each of the following as a strong or weak...Ch. 8 - Label each of the following as a strong or weak...Ch. 8 - Calculate the [H3O+] of an aqueous solution that...Ch. 8 - Calculate the [H3O+] of an aqueous solution that...Ch. 8 - Calculate the [OH−] of an aqueous solution that...Ch. 8 - Prob. 8.50QPCh. 8 - Prob. 8.51QPCh. 8 - What is the concentration of hydronium ions in an...Ch. 8 - Prob. 8.53QPCh. 8 - Consider two beakers, one containing 0.10 M NaOH...Ch. 8 - Calculate the pH of a solution that is:
1.0 × 10−2...Ch. 8 - Calculate the pH of a solution that is:
1.0 × 10−1...Ch. 8 - Calculate [H3O+] for a solution of nitric acid for...Ch. 8 - Calculate [H3O+] for a solution of hydrochloric...Ch. 8 - Prob. 8.59QPCh. 8 - Prob. 8.60QPCh. 8 - Calculate both [H3O+] and [OH−] for a solution for...Ch. 8 - Calculate both [H3O+] and [OH−] for a solution for...Ch. 8 - What is a neutralization reaction?
Ch. 8 - Describe the purpose of a titration.
Ch. 8 - Prob. 8.65QPCh. 8 - The pH of urine may vary between 4.5 and 8.2....Ch. 8 - Criticize the following statement: A lakewater...Ch. 8 - Can a dilute solution of a strong acid ever have a...Ch. 8 - What is the H3O+ concentration of a solution with...Ch. 8 - What is the H3O+ concentration of a solution with...Ch. 8 - Prob. 8.71QPCh. 8 - Prob. 8.72QPCh. 8 - Calculate the pH of a solution that has [H3O+] =...Ch. 8 - Calculate the pH of a solution that has [H3O+] =...Ch. 8 - Calculate the pH of a solution that has [OH−] =...Ch. 8 - Calculate the pH of a solution that has [OH−] =...Ch. 8 - Prob. 8.77QPCh. 8 - Prob. 8.78QPCh. 8 - Prob. 8.79QPCh. 8 - Prob. 8.80QPCh. 8 - Write an equation to represent the neutralization...Ch. 8 - Write an equation to represent the neutralization...Ch. 8 - Prob. 8.83QPCh. 8 - Prob. 8.84QPCh. 8 - Prob. 8.85QPCh. 8 - Prob. 8.86QPCh. 8 - Titration of 15.00 mL of HCl solution requires...Ch. 8 - Titration of 17.85 mL of HNO3 solution requires...Ch. 8 - Prob. 8.89QPCh. 8 - Prob. 8.90QPCh. 8 - Prob. 8.91QPCh. 8 - Prob. 8.92QPCh. 8 - Which of the following are capable of forming a...Ch. 8 - Which of the following are capable of forming a...Ch. 8 - Prob. 8.95QPCh. 8 - Prob. 8.96QPCh. 8 - Prob. 8.97QPCh. 8 - Prob. 8.98QPCh. 8 - For the equilibrium situation involving acetic...Ch. 8 - Prob. 8.100QPCh. 8 - Prob. 8.101QPCh. 8 - Prob. 8.102QPCh. 8 - Prob. 8.103QPCh. 8 - For the buffer system described in Question 8.105,...Ch. 8 - Prob. 8.105QPCh. 8 - Prob. 8.106QPCh. 8 - Prob. 8.107QPCh. 8 - Prob. 8.108QPCh. 8 - Prob. 1CPCh. 8 - Prob. 2CPCh. 8 - Prob. 5CP
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