General, Organic, and Biochemistry
9th Edition
ISBN: 9780078021541
Author: Katherine J Denniston, Joseph J Topping, Dr Danae Quirk Dorr
Publisher: McGraw-Hill Education
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Chapter 8, Problem 8.25QP
(a)
Interpretation Introduction
Interpretation:
Hydronium ion has to be classified as Bronsted-Lowry acid or base or amphiprotic.
Concept Introduction:
Bronsted-Lowry acid: According to Brønsted-Lowry theory, an acid is a proton donor.
Bronsted-Lowry base: According to Brønsted-Lowry theory, a base is a proton acceptor.
Amphiprotic: It is a property of a compound which has both acid and base property. For example, water acts as acid in hydrogen chloride and base in ammonia.
(b)
Interpretation Introduction
Interpretation:
Hydroxide ion has to be classified as Bronsted-Lowry acid or base or amphiprotic.
Concept Introduction:
Refer to part a.
(c)
Interpretation Introduction
Interpretation:
Water has to be classified as Bronsted-Lowry acid or base or amphiprotic.
Concept Introduction:
Refer to part a.
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6. Draw the molecular orbital diagram shown to determine which of the following is paramagnetic.
B₂2+
B22+, B2, C22, B22- and N22+
Molecular Orbital Diagram
B2
C22-
B22-
N22+
Which molecule is paramagnetic?
Don't used hand raiting
EXERCISES: Complete the following exercises. You must show all work to receive full credit.
1. How many molecular orbitals can be built from the valence shell orbitals in O2?
2. Give the ground state electron configuration (e.g., 02s² 0*2s² П 2p²) for these molecules and deduce
its bond order.
Ground State Configuration
Bond Order
H2+
02
N2
Chapter 8 Solutions
General, Organic, and Biochemistry
Ch. 8.1 - Classify CH3COO− as a Brønsted-Lowry acid or base,...Ch. 8.1 - Prob. 8.1QCh. 8.1 - Prob. 8.2QCh. 8.1 - Write an equation for the reversible reactions of...Ch. 8.1 - Prob. 8.4QCh. 8.1 - Prob. 8.5QCh. 8.1 - Prob. 8.6QCh. 8.1 - Prob. 8.2PPCh. 8.1 - Analysis of a patient’s blood sample indicated...Ch. 8.1 - Prob. 8.7Q
Ch. 8.1 - The hydroxide ion concentration in a sample of...Ch. 8.2 - Calculate the pH of a 1.0 × 10−4 M solution of...Ch. 8.2 - Calculate the [H3O+] of a solution of HNO3 that...Ch. 8.2 - Calculate the pH corresponding to a 1.0 × 10−2 M...Ch. 8.2 - Calculate the [H3O+] and [OH−] of a potassium...Ch. 8.2 - Prob. 8.8PPCh. 8.2 - Calculate the [H3O+] corresponding to pH =...Ch. 8.2 - Calculate the [OH–] of a 1.0 × 10–3 M solution of...Ch. 8.2 - Prob. 8.10QCh. 8.3 - Calculate the molar concentration of a sodium...Ch. 8.4 - A buffer solution is prepared in such a way that...Ch. 8.4 - Prob. 8.12PPCh. 8.4 - Prob. 8.11QCh. 8.4 - Prob. 8.12QCh. 8.4 - Prob. 8.13QCh. 8.4 - Prob. 8.14QCh. 8.4 - Prob. 8.15QCh. 8.4 - Prob. 8.16QCh. 8.4 - Prob. 8.17QCh. 8.4 - Explain how the pH of blood would change under...Ch. 8.4 - Write the Henderson-Hasselbalch expression for the...Ch. 8.4 - Prob. 8.20QCh. 8 - Prob. 8.21QPCh. 8 - Define a base according to the Arrhenius...Ch. 8 - What are the essential differences between the...Ch. 8 - Why is ammonia described as a Brønsted-Lowry base...Ch. 8 - Classify each of the following as either a...Ch. 8 - Classify each of the following as either a...Ch. 8 - Classify each of the following as either a...Ch. 8 - Classify each of the following as either a...Ch. 8 - Write an equation for the reaction of each of the...Ch. 8 - Write an equation for the reaction of each of the...Ch. 8 - Write the formula of the conjugate acid of CN−.
Ch. 8 - Write the formula of the conjugate acid of Br−.
Ch. 8 - Write the formula of the conjugate base of HI.
Ch. 8 - Write the formula of the conjugate base of HCOOH.
Ch. 8 - Write the formula of the conjugate acid of NO3−.
Ch. 8 - Write the formula of the conjugate acid of F−.
Ch. 8 - Which is the stronger base, NO3− or CN−?
Ch. 8 - Prob. 8.38QPCh. 8 - Prob. 8.39QPCh. 8 - Which is the stronger base, F− or CH3COO−?
Ch. 8 - Identify the conjugate acid-base pairs in each of...Ch. 8 - Identify the conjugate acid-base pairs in each of...Ch. 8 - Distinguish between the terms acid-base strength...Ch. 8 - Label each of the following as a strong or weak...Ch. 8 - Label each of the following as a strong or weak...Ch. 8 - Calculate the [H3O+] of an aqueous solution that...Ch. 8 - Calculate the [H3O+] of an aqueous solution that...Ch. 8 - Calculate the [OH−] of an aqueous solution that...Ch. 8 - Prob. 8.50QPCh. 8 - Prob. 8.51QPCh. 8 - What is the concentration of hydronium ions in an...Ch. 8 - Prob. 8.53QPCh. 8 - Consider two beakers, one containing 0.10 M NaOH...Ch. 8 - Calculate the pH of a solution that is:
1.0 × 10−2...Ch. 8 - Calculate the pH of a solution that is:
1.0 × 10−1...Ch. 8 - Calculate [H3O+] for a solution of nitric acid for...Ch. 8 - Calculate [H3O+] for a solution of hydrochloric...Ch. 8 - Prob. 8.59QPCh. 8 - Prob. 8.60QPCh. 8 - Calculate both [H3O+] and [OH−] for a solution for...Ch. 8 - Calculate both [H3O+] and [OH−] for a solution for...Ch. 8 - What is a neutralization reaction?
Ch. 8 - Describe the purpose of a titration.
Ch. 8 - Prob. 8.65QPCh. 8 - The pH of urine may vary between 4.5 and 8.2....Ch. 8 - Criticize the following statement: A lakewater...Ch. 8 - Can a dilute solution of a strong acid ever have a...Ch. 8 - What is the H3O+ concentration of a solution with...Ch. 8 - What is the H3O+ concentration of a solution with...Ch. 8 - Prob. 8.71QPCh. 8 - Prob. 8.72QPCh. 8 - Calculate the pH of a solution that has [H3O+] =...Ch. 8 - Calculate the pH of a solution that has [H3O+] =...Ch. 8 - Calculate the pH of a solution that has [OH−] =...Ch. 8 - Calculate the pH of a solution that has [OH−] =...Ch. 8 - Prob. 8.77QPCh. 8 - Prob. 8.78QPCh. 8 - Prob. 8.79QPCh. 8 - Prob. 8.80QPCh. 8 - Write an equation to represent the neutralization...Ch. 8 - Write an equation to represent the neutralization...Ch. 8 - Prob. 8.83QPCh. 8 - Prob. 8.84QPCh. 8 - Prob. 8.85QPCh. 8 - Prob. 8.86QPCh. 8 - Titration of 15.00 mL of HCl solution requires...Ch. 8 - Titration of 17.85 mL of HNO3 solution requires...Ch. 8 - Prob. 8.89QPCh. 8 - Prob. 8.90QPCh. 8 - Prob. 8.91QPCh. 8 - Prob. 8.92QPCh. 8 - Which of the following are capable of forming a...Ch. 8 - Which of the following are capable of forming a...Ch. 8 - Prob. 8.95QPCh. 8 - Prob. 8.96QPCh. 8 - Prob. 8.97QPCh. 8 - Prob. 8.98QPCh. 8 - For the equilibrium situation involving acetic...Ch. 8 - Prob. 8.100QPCh. 8 - Prob. 8.101QPCh. 8 - Prob. 8.102QPCh. 8 - Prob. 8.103QPCh. 8 - For the buffer system described in Question 8.105,...Ch. 8 - Prob. 8.105QPCh. 8 - Prob. 8.106QPCh. 8 - Prob. 8.107QPCh. 8 - Prob. 8.108QPCh. 8 - Prob. 1CPCh. 8 - Prob. 2CPCh. 8 - Prob. 5CP
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