
Basic Chemistry
6th Edition
ISBN: 9780134878119
Author: Timberlake, Karen C. , William
Publisher: Pearson,
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Chapter 8.2, Problem 16PP
When ethanol
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Question 5: Name the following compound in two ways
using side chain and using prefix amine (Common name
and IUPAC name both)
CH3NH2
CH3CH2NHCH3
CH₂CH₂N(CH3)2
Draw the structure of diethyl methyl amine
Question 6. Write the balanced combustion reaction
for:
a. Hexane
b. Propyne
c. 2-pentene
Question 7: Write the following electrophilic
substitution reactions of benzene:
Hint: Use notes if you get confused
a. Halogenation reaction:
b. Nitration reaction :
c. Sulphonation reaction:
d. Alkylation reaction:
e. Aceylation reaction:
Question 4. Name the following structures
○
CH3-C-N-H
H
CH3CH2-C-N-H
H
CH3CH2-C-N-CH3
H
A. Add Water to below compound which 2-methyl 2-butene (addition Reaction)
H₂C
CH₂
CH,
+ H₂O-> ?
Major product?
Minor product?
B. Add Bromine to the compound which 2-methyl 2-butene (addition Reaction)
CH₂
CH₂
+ Br₂→ ?
Major product and Minor product both are same in this?
C. Add Hydrogen Bromide to the compound which 2-methyl 2-butene (addition
Reaction)
H,C
CH₂
CH₂
+ HBr
Major product?
Minor product?
D. Add Hydrogen to the compound which 2-methyl 2-butene (addition Reaction)
CH₂
CH₂
+ H₂
Major product and Minor product both are same in this?
Chapter 8 Solutions
Basic Chemistry
Ch. 8.1 - State the number of atoms of oxygen in the...Ch. 8.1 - State the number of atoms of oxygen in the...Ch. 8.1 - Prob. 3PPCh. 8.1 - Determine whether each of the following equations...Ch. 8.1 - All of the following are balanced equations. State...Ch. 8.1 - All of the following are balanced equations. State...Ch. 8.2 - Balance each of the following chemical...Ch. 8.2 - Balance each of the following chemical...Ch. 8.2 - Prob. 9PPCh. 8.2 - Prob. 10PP
Ch. 8.2 - Balance each of the following chemical...Ch. 8.2 - Prob. 12PPCh. 8.2 - Write a balanced equation using the correct...Ch. 8.2 - Write a balanced equation using the correct...Ch. 8.2 - Dinitrogen oxide, also known as laughing gas, is a...Ch. 8.2 - When ethanol C2H6O(aq) is consumed, it reacts with...Ch. 8.2 - In the body, the amino acid alanine C3H7NO2(aq)...Ch. 8.2 - Prob. 18PPCh. 8.3 - Classify each of the following as a combination,...Ch. 8.3 - Classify each of the following as a combination,...Ch. 8.3 - Classify each of the following as a combination,...Ch. 8.3 - Classify each of the following as a combination,...Ch. 8.3 - Using Table 8.3, predict the products that would...Ch. 8.3 - Using Table 8.3, predict the products that would...Ch. 8.4 - Prob. 25PPCh. 8.4 - Identify each of the following as an oxidation or...Ch. 8.4 - Prob. 27PPCh. 8.4 - In each of the following, identify the reactant...Ch. 8.4 - In the mitochondria of human cells, energy is...Ch. 8.4 - Prob. 30PPCh. 8.4 - When linoleic acid, an unsaturated fatty acid,...Ch. 8.4 - Prob. 32PPCh. 8.4 - a. During cellular respiration, aqueous glucose...Ch. 8.4 - Aqueous fatty acids undergo reaction with oxygen...Ch. 8 - The chapter sections to review are shown in...Ch. 8 - The chapter sections to review are shown in...Ch. 8 - The chapter sections to review are shown in...Ch. 8 - The chapter sections to review are shown in...Ch. 8 - Prob. 39UTCCh. 8 - The chapter sections to review are shown in...Ch. 8 - Prob. 41UTCCh. 8 - If blue spheres represent nitrogen atoms, purple...Ch. 8 - Identify the type of reaction for each of the...Ch. 8 - Identify the type of reaction for each of the...Ch. 8 - Balance each of the following chemical equations,...Ch. 8 - Balance each of the following chemical equations,...Ch. 8 - Predict the products and write a balanced equation...Ch. 8 - Prob. 48APPCh. 8 - Write a balanced equation for each of the...Ch. 8 - Write a balanced equation for each of the...Ch. 8 - Prob. 51APPCh. 8 - Prob. 52APPCh. 8 - Prob. 53CPCh. 8 - Prob. 54CPCh. 8 - Prob. 55CPCh. 8 - Prob. 56CPCh. 8 - The following problems are related to the topics...Ch. 8 - Prob. 58CPCh. 8 - Prob. 59CPCh. 8 - In the following diagram, if red spheres are the...
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- 36) Complete the following multi-step reactions showing applications of enolate ions arising from ketones, esters, malonic ester, and keto ester, etc. (30 pts) (1) A NaOH, H₂O+ heat A NaOEt EtO OEt (11) EOH, H+ H. B LDA, H₂O+ -78°C B (i) NaOMe, Et-Br (ii) H₂O+, heat EtOOC (III) COOEt B A (i) NaOEt LiAlH 4-bromo-2-butene H₂O+ (ii) H3O+, heat Write the mechanism for Aldol Condensation (I A or B), and Claisen Condensation (II A).arrow_forward31) Complete two sets of reactions involving (R)-4-methyl-pent-2-ol producing racemic mixture of tertiary alcohols (D) and ketone derivative (C). Illustrate the mechanism of B and C or D. (25 pts) O OH 0 K2Cr2O7 Ph-CH2-Br, Mg, H2SO4 THF, H3O* (A) (D) Racemic mixture TsCl, Py (B) KCN, DMSO Ph-CH2-Br, Mg, THF, H3O+ (C) Mechanism for reactions B and C:arrow_forwardManoharan Mariappan, Ph.D., Dept. of Natur. Sci., NFC, Tallahassee, FL 33) Synthesize the aromatic compound containing para-substituted carbonyl compound starting from benzene. Illustrate the mechanism for reaction A. 1) NU (25 pts) A FeCl B (i) HNO3, H2SO4 (II) Sn, HCl(aq) NH₂ NO₂-D NH₂ (i) MeCO2Me, heat C (ii) K2Cr2O7/H2SO4 D (ii) SOCl2 (iii) 2 Et-NH2 Mechanism for reaction for the nitration of alkyl benzene (B-i): Characterize the product compound arising from the reaction D by IR and IH NMR spectral data: IR data (cm): 'H NMR data: Draw the structure and assign the chemical shift with the spin-splitting.arrow_forward
- Write structural formulas for the major products by doing addition reactions 1. You must add H2 as Pt is catalyst it does not take part in reactions only speed up the process H₂ CH2=CH-CH3 Pt 2. Add HCI break it into H and Cl CH3 HCI 3. Add Br2 only CC14 is catalyst CH3-CH=CH2 B12 CCl4 4. Add water to this and draw major product, H2SO4 is catalyst you have add water H20 in both the reaction below H₂SO4 CH3-CH=CH2 CH3 H2SO4/H₂O CH3-C=CH2 reflux ?arrow_forwardPlan the synthesis of the following compound using the starting material provided and any other reagents needed as long as carbon based reagents have 3 carbons or less. Either the retrosynthesis or the forward synthesis (mechanisms are not required but will be graded if provided) will be accepted if all necessary reagents and intermediates are shown (solvents and temperature requirements are not needed unless specifically involved in the reaction, i.e. DMSO in the Swern oxidation or heat in the KMnO4 oxidation). H Harrow_forwardHint These are benzene substitution reactions. ALCI3 and UV light are catalyst no part in reactions and triangle A means heating. A. Add ethyl for Et in benzene ring alkylation reaction EtCl = CH3CH2CL 1) EtC1 / AlCl3 / A ? B: Add Br to benzene ring ( substitution) 2) Br₂ / uv light ? C Add (CH3)2 CHCH2 in benzene ring ( substitution) (CH3)2CHCH,C1 / AICI, ?arrow_forward
- Draw the mechanism to make the alcohol 2-hexanol. Draw the Mechanism to make the alcohol 1-hexanol.arrow_forwardDraw the mechanism for the formation of diol by starting with 1-pentanal in... basic conditions then acidic conditions then draw the mechanism for the formation of a carboxylic acid from your product.arrow_forwardIdentify each chiral carbon as either R or S. Identify the overall carbohydrates as L or Darrow_forward
- Ethers can be formed via acid-catalyzed acetal formation. Draw the mechanism for the molecule below and ethanol.arrow_forwardHOCH, H HO CH-OH OH H OH 11 CH₂OH F II OH H H 0 + H OHarrow_forwardDraw the mechanism for the formation of diol by starting with one pen and all in... basic conditions then acidic conditions then draw the mechanism for the formation of a carboxylic acid from your product.arrow_forward
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