Introduction to General, Organic and Biochemistry
12th Edition
ISBN: 9780357119303
Author: Bettelheim, Frederick A., Brown, William H., Campbell, Mary K., FARRELL, Shawn O., Torres, Omar
Publisher: Cengage Learning
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Textbook Question
Chapter 8.11, Problem 8.11QC
Problem 8-11
What is the pH of a boric acid buffer solution containing 0.25 moI/L of boric acid, H3BO3 and 0.50 mol/L of its conjugate base? See Table 8-3 for the pKaof boric acid.
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Laser. Indicate the relationship between metastable state and stimulated emission.
The table includes macrostates characterized by 4 energy levels (&) that are
equally spaced but with different degrees of occupation.
a) Calculate the energy of all the macrostates (in joules). See if they all have
the same energy and number of particles.
b) Calculate the macrostate that is most likely to exist. For this macrostate,
show that the population of the levels is consistent with the Boltzmann
distribution.
macrostate 1 macrostate 2 macrostate 3
ε/k (K) Populations
Populations
Populations
300
5
3
4
200
7
9
8
100
15
17
16
0
33
31
32
DATO: k = 1,38×10-23 J K-1
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Chapter 8 Solutions
Introduction to General, Organic and Biochemistry
Ch. 8.3 - Problem 8-1 Draw the acid and base reactions for...Ch. 8.4 - Prob. 8.2QCCh. 8.5 - Prob. 8.3QCCh. 8.5 - Problem 8-4 Which is the stronger acid? (a)...Ch. 8.6 - Problem 8-5 Write the balanced net ionic equation...Ch. 8.7 - Problem 8-6 The [OH-] of an aqueous solution is M....Ch. 8.8 - Problem 8-7 (a) The [H3O+] of an acidic solution...Ch. 8.8 - Problem 8-8 The [OH-] of a solution is M. What are...Ch. 8.9 - Problem 8-9 Calculate the concentration of an...Ch. 8.10 - Problem 8-10 What is the pH of a buffer solution...
Ch. 8.11 - Problem 8-11 What is the pH of a boric acid buffer...Ch. 8.12 - Prob. 8.12QCCh. 8 - 8-13 Define (a) an Arrhenius acid and (b) an...Ch. 8 - 8-14 Write an equation for the reaction that takes...Ch. 8 - 8-15 Write an equation for the reaction that takes...Ch. 8 - 8-16 For each of the following, tell whether the...Ch. 8 - 8-17 For each of the following, tell whether the...Ch. 8 - 8-18 Which of these acids are monoprotic, which...Ch. 8 - 8-19 Define (a) a Brønsted—Lowry acid and (b) a...Ch. 8 - 8-20 Write the formula for the conjugate base of...Ch. 8 - 8-21 Write the formula for the conjugate base of...Ch. 8 - Prob. 10PCh. 8 - Prob. 11PCh. 8 - Prob. 12PCh. 8 - 8-25 Draw the acid and base reactions for the...Ch. 8 - Prob. 14PCh. 8 - Prob. 15PCh. 8 - 8-28 Will carbon dioxide be evolved as a gas when...Ch. 8 - Prob. 17PCh. 8 - Prob. 18PCh. 8 - Prob. 19PCh. 8 - Prob. 20PCh. 8 - 8-33 Write an equation for the reaction of HCI...Ch. 8 - 8-34 When a solution of sodium hydroxide is added...Ch. 8 - 8-35 Given the following values of [H3O+),...Ch. 8 - 8-36 Given the following values of [OH-],...Ch. 8 - 8-37 What is the pH of each solution given the...Ch. 8 - 8-38 What is the pH and pOH of each solution given...Ch. 8 - 8-39 What is the pH of each solution given the...Ch. 8 - Prob. 28PCh. 8 - 8-41 What is the [OH-] and pOH of each solution?...Ch. 8 - Prob. 30PCh. 8 - 8-43 What is the molarity of a solution made by...Ch. 8 - 8-44 What is the molarity of a solution made by...Ch. 8 - 8-45 Describe how you would prepare each of the...Ch. 8 - 8-46 If 25.0 mL of an aqueous solution of H2SO4...Ch. 8 - 8-47 A sample of 27.0 mL of 0.310 M NaOH is...Ch. 8 - 8-48 A 0.300 M solution of H2SO4 was used to...Ch. 8 - 8-49 A solution of NaOH base was titrated with...Ch. 8 - 8-50 The usual concentration of HCO3- ions in...Ch. 8 - 8-51 What is the end point of a titration?Ch. 8 - Prob. 40PCh. 8 - 8-53 Write equations to show what happens when, to...Ch. 8 - 8-54 Write equations to show what happens when, to...Ch. 8 - 8-55 We commonly refer to a buffer as consisting...Ch. 8 - Prob. 44PCh. 8 - Prob. 45PCh. 8 - 8-58 What is the connection between buffer action...Ch. 8 - Prob. 47PCh. 8 - 8-60 How is the buffer capacity affected by the...Ch. 8 - 8-61 Can 100 of 0.1 M phosphate buffer at pH 7.2...Ch. 8 - 8-62 What is the pH of a buffer solution made by...Ch. 8 - 8-63 The pH of a solution made by dissolving 1.0...Ch. 8 - Prob. 52PCh. 8 - Prob. 53PCh. 8 - Prob. 54PCh. 8 - Prob. 55PCh. 8 - 8-66 Calculate the pH of an aqueous solution...Ch. 8 - Prob. 57PCh. 8 - 8-68 If you have 100 mL of a 0.1 M buffer made of...Ch. 8 - Prob. 59PCh. 8 - Prob. 60PCh. 8 - 8-71 Explain why you do not need to know the...Ch. 8 - Prob. 62PCh. 8 - Prob. 63PCh. 8 - Prob. 64PCh. 8 - Prob. 65PCh. 8 - 8-76 (Chemical Connections 8B) Name the most...Ch. 8 - Prob. 67PCh. 8 - Prob. 68PCh. 8 - 8-79 (Chemical Connections 8D) Another form of the...Ch. 8 - Prob. 70PCh. 8 - Prob. 71PCh. 8 - 8-82 Assume that you have a dilute solution of HCI...Ch. 8 - Prob. 73PCh. 8 - Prob. 74PCh. 8 - Prob. 75PCh. 8 - 8-86 Following are three organic acids and the...Ch. 8 - 8-87 The pKavalue of barbituric acid is 5.0. If...Ch. 8 - Prob. 78PCh. 8 - Prob. 79PCh. 8 - Prob. 80PCh. 8 - Prob. 81PCh. 8 - Prob. 82PCh. 8 - 8-93 Do a 1.0 M CH3COOH solution and a 1.0 M HCI...Ch. 8 - 8-94 Suppose you wish to make a buffer whose pH is...Ch. 8 - Prob. 85PCh. 8 - 8-96 Suppose you want to make a CH3COOH/CH3COO-...Ch. 8 - Prob. 87PCh. 8 - 8-98 When a solution prepared by dissolving 4.00 g...Ch. 8 - Prob. 89PCh. 8 - Prob. 90PCh. 8 - 8-101 Suppose you have an aqueous solution...Ch. 8 - Prob. 92PCh. 8 - 8-103 Suppose you have a phosphate buffer...Ch. 8 - Prob. 94PCh. 8 - Prob. 95PCh. 8 - Prob. 96PCh. 8 - 8-107 Following are pH ranges for several human...Ch. 8 - Prob. 98PCh. 8 - Prob. 99PCh. 8 - 8-108 What is the ratio of HPO42-/H2PO4- in a...Ch. 8 - Prob. 101PCh. 8 - 8-110 A concentrated hydrochloric acid solution...Ch. 8 - 8-111 The volume of an adult's stomach ranges from...Ch. 8 - 8-112 Consider an initial 0.040 M hypobromous acid...Ch. 8 - Prob. 105PCh. 8 - Prob. 106PCh. 8 - 8-115 When a solution prepared by dissolving 0.125...Ch. 8 - 8-116 A railroad tank car derails and spills 26...Ch. 8 - Prob. 109PCh. 8 - Prob. 110PCh. 8 - Prob. 111P
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