The major product of the reaction has to be predicted. Concept Introduction: Effect of delocalized electrons on the product of the reaction: The presence of delocalizes electrons while electrophilic addition or substitution the cation intermediate formed is shifted to stable carbocation form at higher rate, and that leads to the product. Rule: The stabilities of carbocation are, Benzyl cation = allyl cation = 3 ∘ carbocation > 2 ∘ carbocation > 1 ∘ carbocation > methyl cation > vinyl cation

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Answer 1

Question

Chapter 8.11, Problem 24P

Interpretation Introduction

Interpretation:

The major product of the reaction has to be predicted.

Concept Introduction:

Effect of delocalized electrons on the product of the reaction:

The presence of delocalizes electrons while electrophilic addition or substitution the cation intermediate formed is shifted to stable carbocation form at higher rate, and that leads to the product.

Rule: The stabilities of carbocation are,

Benzyl cation = allyl cation = 3∘carbocation > 2∘ carbocation > 1∘ carbocation > methyl cation > vinyl cation

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4. Draw and label all possible isomers for [M(py)3(DMSO)2(CI)] (py = pyridine, DMSO dimethylsulfoxide).

Answer 2

Question

Chapter 8.11, Problem 24P

Interpretation Introduction

Interpretation:

The major product of the reaction has to be predicted.

Concept Introduction:

Effect of delocalized electrons on the product of the reaction:

The presence of delocalizes electrons while electrophilic addition or substitution the cation intermediate formed is shifted to stable carbocation form at higher rate, and that leads to the product.

Rule: The stabilities of carbocation are,

Benzyl cation = allyl cation = 3∘carbocation > 2∘ carbocation > 1∘ carbocation > methyl cation > vinyl cation

Expert Solution & Answer

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Check out a sample textbook solution

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Answer 3

Question

Chapter 8.11, Problem 24P

Interpretation Introduction

Interpretation:

The major product of the reaction has to be predicted.

Concept Introduction:

Effect of delocalized electrons on the product of the reaction:

The presence of delocalizes electrons while electrophilic addition or substitution the cation intermediate formed is shifted to stable carbocation form at higher rate, and that leads to the product.

Rule: The stabilities of carbocation are,

Benzyl cation = allyl cation = 3∘carbocation > 2∘ carbocation > 1∘ carbocation > methyl cation > vinyl cation

Expert Solution & Answer

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Answer 4

Question

Chapter 8.11, Problem 24P

Interpretation Introduction

Interpretation:

The major product of the reaction has to be predicted.

Concept Introduction:

Effect of delocalized electrons on the product of the reaction:

The presence of delocalizes electrons while electrophilic addition or substitution the cation intermediate formed is shifted to stable carbocation form at higher rate, and that leads to the product.

Rule: The stabilities of carbocation are,

Benzyl cation = allyl cation = 3∘carbocation > 2∘ carbocation > 1∘ carbocation > methyl cation > vinyl cation

Expert Solution & Answer

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Answer 5

Chapter 8.11, Problem 24P

Interpretation Introduction

Interpretation:

The major product of the reaction has to be predicted.

Concept Introduction:

Effect of delocalized electrons on the product of the reaction:

The presence of delocalizes electrons while electrophilic addition or substitution the cation intermediate formed is shifted to stable carbocation form at higher rate, and that leads to the product.

Rule: The stabilities of carbocation are,

Benzyl cation = allyl cation = 3∘carbocation > 2∘ carbocation > 1∘ carbocation > methyl cation > vinyl cation

Answer 6

Chapter 8.11, Problem 24P

Interpretation Introduction

Interpretation:

The major product of the reaction has to be predicted.

Concept Introduction:

Effect of delocalized electrons on the product of the reaction:

The presence of delocalizes electrons while electrophilic addition or substitution the cation intermediate formed is shifted to stable carbocation form at higher rate, and that leads to the product.

Rule: The stabilities of carbocation are,

Benzyl cation = allyl cation = 3∘carbocation > 2∘ carbocation > 1∘ carbocation > methyl cation > vinyl cation

Answer 7

Chapter 8.11, Problem 24P

Interpretation Introduction

Interpretation:

The major product of the reaction has to be predicted.

Concept Introduction:

Effect of delocalized electrons on the product of the reaction:

The presence of delocalizes electrons while electrophilic addition or substitution the cation intermediate formed is shifted to stable carbocation form at higher rate, and that leads to the product.

Rule: The stabilities of carbocation are,

Benzyl cation = allyl cation = 3∘carbocation > 2∘ carbocation > 1∘ carbocation > methyl cation > vinyl cation

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 8.1 - Prob. 1P Ch. 8.1 - Prob. 2P Ch. 8.4 - Prob. 3P Ch. 8.5 - Prob. 4P Ch. 8.5 - Prob. 6P Ch. 8.6 - a. Predict the relative bond lengths of the three...Ch. 8.6 - Prob. 8P Ch. 8.6 - Prob. 9P Ch. 8.6 - Prob. 10P Ch. 8.7 - Prob. 11P

Solution Summary: The author analyzes the effect of delocalized electrons on the product of the reaction. The terminal alkene double bond abstracts proton from hydrogen bromide, forming secondary carbocation.

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