The authenticity of the statement that the hypothetical molecule B − A = B cannot exist should be determined. Concept Introduction: The existence of a molecule depends on fulfillment of octet rule. The molecules in which all the atoms complete their octet exist.

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Answer 1

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Chapter 8, Problem 95IE

(a)

Interpretation Introduction

Interpretation: The authenticity of the statement that the hypothetical molecule B−A=B cannot exist should be determined.

Concept Introduction: The existence of a molecule depends on fulfillment of octet rule. The molecules in which all the atoms complete their octet exist.

(b)

Interpretation Introduction

Interpretation: The authenticity of the statement that if resonance was important, the molecule would have identical A−B bond lengths should be determined.

Concept Introduction:Resonance is due to the presence of conjugated double bond in the molecule. Due to this, the bond lengths in the molecule are equal.

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-AG|F=2E|V 3. Before proceeding with this problem you may want to glance at p. 466 of your textbook where various oxo-phosphorus derivatives and their oxidation states are summarized. Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14: Acidic solution -0.93 +0.38 -0.51 -0.06 H3PO4 →H4P206 H3PO3 H3PO2 → P→ PH3 -0.28 -0.50 → -0.50 Basic solution 3-1.12 -1.57 -2.05 -0.89 PO HPO →→H2PO2 P PH3 -1.73 a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the formation and reduction of H4P2O6 (-0.93/+0.38V). Calculate the values of AG's for both processes; comment. (3 points) 0.5 PH, 0.0 -0.5- 2 3 9 3 -1.5 -2.0 Pa H,PO H,PO H,PO -3 -1 0 2 4 Oxidation state, N 2 b) Frost diagram for phosphorus under acidic conditions is shown. Identify possible disproportionation and comproportionation processes; write out chemical equations describing them. (2 points) c) Elemental phosphorus tends to disproportionate under basic conditions. Use data in…

These two reactions appear to start with the same starting materials but result in different products. How do the chemicals know which product to form? Are both products formed, or is there some information missing that will direct them a particular way?

What would be the best choices for the missing reagents 1 and 3 in this synthesis? 1. PPh3 3 1 2 2. n-BuLi • Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like. • Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is. • Note: if one of your reagents needs to contain a halogen, use bromine. Explanation Check Click and drag to start drawing a structure. 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Priva ×

Answer 2

Question

Chapter 8, Problem 95IE

(a)

Interpretation Introduction

Interpretation: The authenticity of the statement that the hypothetical molecule B−A=B cannot exist should be determined.

Concept Introduction: The existence of a molecule depends on fulfillment of octet rule. The molecules in which all the atoms complete their octet exist.

(b)

Interpretation Introduction

Interpretation: The authenticity of the statement that if resonance was important, the molecule would have identical A−B bond lengths should be determined.

Concept Introduction:Resonance is due to the presence of conjugated double bond in the molecule. Due to this, the bond lengths in the molecule are equal.

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Answer 3

Question

Chapter 8, Problem 95IE

(a)

Interpretation Introduction

Interpretation: The authenticity of the statement that the hypothetical molecule B−A=B cannot exist should be determined.

Concept Introduction: The existence of a molecule depends on fulfillment of octet rule. The molecules in which all the atoms complete their octet exist.

(b)

Interpretation Introduction

Interpretation: The authenticity of the statement that if resonance was important, the molecule would have identical A−B bond lengths should be determined.

Concept Introduction:Resonance is due to the presence of conjugated double bond in the molecule. Due to this, the bond lengths in the molecule are equal.

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Answer 4

Question

Chapter 8, Problem 95IE

(a)

Interpretation Introduction

Interpretation: The authenticity of the statement that the hypothetical molecule B−A=B cannot exist should be determined.

Concept Introduction: The existence of a molecule depends on fulfillment of octet rule. The molecules in which all the atoms complete their octet exist.

(b)

Interpretation Introduction

Interpretation: The authenticity of the statement that if resonance was important, the molecule would have identical A−B bond lengths should be determined.

Concept Introduction:Resonance is due to the presence of conjugated double bond in the molecule. Due to this, the bond lengths in the molecule are equal.

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Answer 5

Chapter 8, Problem 95IE

(a)

Interpretation Introduction

Interpretation: The authenticity of the statement that the hypothetical molecule B−A=B cannot exist should be determined.

Concept Introduction: The existence of a molecule depends on fulfillment of octet rule. The molecules in which all the atoms complete their octet exist.

(b)

Interpretation Introduction

Interpretation: The authenticity of the statement that if resonance was important, the molecule would have identical A−B bond lengths should be determined.

Concept Introduction:Resonance is due to the presence of conjugated double bond in the molecule. Due to this, the bond lengths in the molecule are equal.

Answer 6

Chapter 8, Problem 95IE

(a)

Interpretation Introduction

Interpretation: The authenticity of the statement that the hypothetical molecule B−A=B cannot exist should be determined.

Concept Introduction: The existence of a molecule depends on fulfillment of octet rule. The molecules in which all the atoms complete their octet exist.

Answer 7

Chapter 8, Problem 95IE

(a)

Interpretation Introduction

Interpretation: The authenticity of the statement that the hypothetical molecule B−A=B cannot exist should be determined.

Concept Introduction: The existence of a molecule depends on fulfillment of octet rule. The molecules in which all the atoms complete their octet exist.

Answer 8

(b)

Interpretation Introduction

Interpretation: The authenticity of the statement that if resonance was important, the molecule would have identical A−B bond lengths should be determined.

Concept Introduction:Resonance is due to the presence of conjugated double bond in the molecule. Due to this, the bond lengths in the molecule are equal.

Answer 9

(b)

Interpretation Introduction

Interpretation: The authenticity of the statement that if resonance was important, the molecule would have identical A−B bond lengths should be determined.

Concept Introduction:Resonance is due to the presence of conjugated double bond in the molecule. Due to this, the bond lengths in the molecule are equal.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 8.2 - Which of the these elements is most likely to from...Ch. 8.2 - Prob. 8.1.2PE Ch. 8.2 - Which of the following bond is the most polar? H-F...Ch. 8.2 - Prob. 8.2.2PE Ch. 8.3 - Prob. 8.3.1PE Ch. 8.3 - Prob. 8.3.2PE Ch. 8.4 - Which of the following bonds is the most polar? a....Ch. 8.4 - Which of the following bonds is most polar: S-Cl,...Ch. 8.4 - Prob. 8.5.1PE Ch. 8.4 - The dipole moment of chlorine monofluoride,...

The authenticity of the statement that the hypothetical molecule B − A = B cannot exist should be determined. Concept Introduction: The existence of a molecule depends on fulfillment of octet rule. The molecules in which all the atoms complete their octet exist.

Concept explainers

Interpretation: The authenticity of the statement that the hypothetical molecule B−A=B cannot exist should be determined.

Concept Introduction: The existence of a molecule depends on fulfillment of octet rule. The molecules in which all the atoms complete their octet exist.

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Chapter 8 Solutions

The authenticity of the statement that the hypothetical molecule B − A = B cannot exist should be determined. Concept Introduction: The existence of a molecule depends on fulfillment of octet rule. The molecules in which all the atoms complete their octet exist.

Concept explainers

Interpretation: The authenticity of the statement that the hypothetical molecule B−A=B cannot exist should be determined. Concept Introduction: The existence of a molecule depends on fulfillment of octet rule. The molecules in which all the atoms complete their octet exist.

Want to see the full answer?

Chapter 8 Solutions

Interpretation: The authenticity of the statement that the hypothetical molecule B−A=B cannot exist should be determined.

Concept Introduction: The existence of a molecule depends on fulfillment of octet rule. The molecules in which all the atoms complete their octet exist.