Atkins' Physical Chemistry 11e
11th Edition
ISBN: 9780192575135
Author: Peter Atkins; Julio de Paula; James Keeler
Publisher: Oxford University Press Academic UK
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Chapter 8, Problem 8B.4DQ
Interpretation Introduction
Interpretation:
The self-consistent field procedure for calculating the form of the orbitals and the energies of many electron-atoms has to be described.
Concept introduction:
Hydrogen is a single electron species. All other elements present in the periodic table represents the many-electron species. Many-electron species are influenced by the electron-electron repulsion. The energy and the form of the orbitals of many electron-atoms are calculated by the self-consistent field procedure.
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1. Consider the following molecular-level diagrams of a titration.
O-HA molecule
-Aion
°°
о
°
(a)
о
(b)
(c)
(d)
a. Which diagram best illustrates the microscopic representation for the
EQUIVALENCE POINT in a titration of a weak acid (HA) with sodium.
hydroxide?
(e)
Answers to the remaining 6 questions will be hand-drawn on paper and submitted as a single
file upload below:
Review of this week's reaction:
H₂NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H₂O --->
H₂NC(=NH)N(CH3)CH2COOH (creatine)
Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing
the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts)
Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts)
Q9. Explain with drawing why the C-N bond shown in creatine structure below can or cannot rotate. (3
pts)
NH2(C=NH)-N(CH)CH2COOH
This bond
Q10. Draw two tautomers of creatine using line structures. (Note: this question is valid because problem
Q9 is valid). (4 pts)
Q11. Mechanism. After seeing and understanding the mechanism of creatine synthesis, students should
be ready to understand the first half of one of the Grignard reactions presented in a past…
Propose a synthesis pathway for the
following transformations. b) c) d)
Chapter 8 Solutions
Atkins' Physical Chemistry 11e
Ch. 8 - Prob. 8A.1STCh. 8 - Prob. 8A.2STCh. 8 - Prob. 8A.3STCh. 8 - Prob. 8C.2STCh. 8 - Prob. 8C.3STCh. 8 - Prob. 8A.1DQCh. 8 - Prob. 8A.2DQCh. 8 - Prob. 8A.3DQCh. 8 - Prob. 8A.1AECh. 8 - Prob. 8A.1BE
Ch. 8 - Prob. 8A.2AECh. 8 - Prob. 8A.2BECh. 8 - Prob. 8A.3AECh. 8 - Prob. 8A.3BECh. 8 - Prob. 8A.4AECh. 8 - Prob. 8A.4BECh. 8 - Prob. 8A.5AECh. 8 - Prob. 8A.5BECh. 8 - Prob. 8A.6AECh. 8 - Prob. 8A.6BECh. 8 - Prob. 8A.7AECh. 8 - Prob. 8A.7BECh. 8 - Prob. 8A.9AECh. 8 - Prob. 8A.10AECh. 8 - Prob. 8A.10BECh. 8 - Prob. 8A.11AECh. 8 - Prob. 8A.11BECh. 8 - Prob. 8A.12AECh. 8 - Prob. 8A.12BECh. 8 - Prob. 8A.1PCh. 8 - Prob. 8A.2PCh. 8 - Prob. 8A.3PCh. 8 - Prob. 8A.4PCh. 8 - Prob. 8A.6PCh. 8 - Prob. 8A.7PCh. 8 - Prob. 8A.8PCh. 8 - Prob. 8A.9PCh. 8 - Prob. 8A.10PCh. 8 - Prob. 8A.11PCh. 8 - Prob. 8B.1DQCh. 8 - Prob. 8B.2DQCh. 8 - Prob. 8B.3DQCh. 8 - Prob. 8B.4DQCh. 8 - Prob. 8B.1AECh. 8 - Prob. 8B.1BECh. 8 - Prob. 8B.2AECh. 8 - Prob. 8B.2BECh. 8 - Prob. 8B.3AECh. 8 - Prob. 8B.3BECh. 8 - Prob. 8B.4AECh. 8 - Prob. 8B.4BECh. 8 - Prob. 8B.5AECh. 8 - Prob. 8B.5BECh. 8 - Prob. 8B.1PCh. 8 - Prob. 8B.2PCh. 8 - Prob. 8B.3PCh. 8 - Prob. 8B.4PCh. 8 - Prob. 8B.5PCh. 8 - Prob. 8C.1DQCh. 8 - Prob. 8C.2DQCh. 8 - Prob. 8C.3DQCh. 8 - Prob. 8C.4DQCh. 8 - Prob. 8C.1AECh. 8 - Prob. 8C.1BECh. 8 - Prob. 8C.2AECh. 8 - Prob. 8C.2BECh. 8 - Prob. 8C.3AECh. 8 - Prob. 8C.3BECh. 8 - Prob. 8C.4AECh. 8 - Prob. 8C.4BECh. 8 - Prob. 8C.5AECh. 8 - Prob. 8C.5BECh. 8 - Prob. 8C.6AECh. 8 - Prob. 8C.6BECh. 8 - Prob. 8C.7AECh. 8 - Prob. 8C.7BECh. 8 - Prob. 8C.8AECh. 8 - Prob. 8C.8BECh. 8 - Prob. 8C.9AECh. 8 - Prob. 8C.9BECh. 8 - Prob. 8C.10AECh. 8 - Prob. 8C.10BECh. 8 - Prob. 8C.11AECh. 8 - Prob. 8C.11BECh. 8 - Prob. 8C.12AECh. 8 - Prob. 8C.12BECh. 8 - Prob. 8C.13AECh. 8 - Prob. 8C.13BECh. 8 - Prob. 8C.14AECh. 8 - Prob. 8C.14BECh. 8 - Prob. 8C.1PCh. 8 - Prob. 8C.2PCh. 8 - Prob. 8C.3PCh. 8 - Prob. 8C.4PCh. 8 - Prob. 8C.5PCh. 8 - Prob. 8C.6PCh. 8 - Prob. 8C.7PCh. 8 - Prob. 8C.8PCh. 8 - Prob. 8C.9PCh. 8 - Prob. 8C.10PCh. 8 - Prob. 8C.11PCh. 8 - Prob. 8C.12PCh. 8 - Prob. 8.1IACh. 8 - Prob. 8.2IACh. 8 - Prob. 8.3IA
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