EBK GENERAL CHEMISTRY: THE ESSENTIAL CO
7th Edition
ISBN: 9780100257047
Author: Chang
Publisher: YUZU
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Chapter 8, Problem 8.96QP
Interpretation Introduction
Interpretation:
The melting point of francium
Concept Introduction:
Melting point: It is the temperature at which a substance changes from a solid into a liquid.
Boiling point: It is the temperature at which liquid converts to vapor (or) gas.
Down the group, boiling point decreases since the principal quantum number increases from to bottom and thus the size of orbital also increases which results in weak attraction by the nucleus
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AG/F-2° V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
PH
P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
-1
1
2
3
2
H,PO,
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
4. For the following complexes, draw the structures and give a d-electron count of the
metal:
a) Tris(acetylacetonato)iron(III)
b) Hexabromoplatinate(2-)
c) Potassium diamminetetrabromocobaltate(III)
(6 points)
2. Calculate the overall formation constant for [Fe(CN)6]³, given that the overall formation
constant for [Fe(CN)6] 4 is ~1032, and that:
Fe3+ (aq) + e
= Fe²+ (aq)
E° = +0.77 V
[Fe(CN)6]³ (aq) + e¯ = [Fe(CN)6] (aq) E° = +0.36 V
(4 points)
Chapter 8 Solutions
EBK GENERAL CHEMISTRY: THE ESSENTIAL CO
Ch. 8.2 - Practice Exercise An atom of a certain element has...Ch. 8.2 - Review of concepts
Identify the elements whose...Ch. 8.3 - Practice Exercise Arrange the following atoms in...Ch. 8.3 - Prob. 1RCCh. 8.3 - Prob. 2PECh. 8.3 - Prob. 2RCCh. 8.4 - Prob. 1PECh. 8.4 - Prob. 1RCCh. 8.5 - Prob. 1PECh. 8.5 - Prob. 1RC
Ch. 8.6 - Prob. 1PECh. 8.6 - Prob. 1RCCh. 8 - Prob. 8.1QPCh. 8 - Prob. 8.2QPCh. 8 - Prob. 8.3QPCh. 8 - Prob. 8.4QPCh. 8 - Prob. 8.5QPCh. 8 - Prob. 8.6QPCh. 8 - Prob. 8.7QPCh. 8 - Prob. 8.8QPCh. 8 - Prob. 8.9QPCh. 8 - Prob. 8.10QPCh. 8 - Prob. 8.11QPCh. 8 - Prob. 8.12QPCh. 8 - Prob. 8.13QPCh. 8 - 8.14 Use die first-row transition metals (Sc to...Ch. 8 - 8.15 In the periodic table, the element hydrogen...Ch. 8 - 8.16 A neutral atom of a certain element has 17...Ch. 8 - Prob. 8.17QPCh. 8 - Prob. 8.18QPCh. 8 - Prob. 8.19QPCh. 8 - Prob. 8.20QPCh. 8 - Prob. 8.21QPCh. 8 - 8.21 An ion M2+ derived from a metal in the first...Ch. 8 - Prob. 8.23QPCh. 8 - Prob. 8.24QPCh. 8 - Prob. 8.25QPCh. 8 - Prob. 8.26QPCh. 8 - Prob. 8.27QPCh. 8 - Prob. 8.28QPCh. 8 - Prob. 8.29QPCh. 8 - Prob. 8.30QPCh. 8 - 8.31 Which of these species are isoelectronic with...Ch. 8 - 8.32 Group the species that are isoelectronic:...Ch. 8 - Prob. 8.33QPCh. 8 - 8.34 How does atomic radius change as we move (a)...Ch. 8 - Prob. 8.35QPCh. 8 - Prob. 8.36QPCh. 8 - 8.37 On the basis of their positions in the...Ch. 8 - Prob. 8.38QPCh. 8 - 8.39 Which is the largest atom in Group 4A?
Ch. 8 - Prob. 8.40QPCh. 8 - Prob. 8.41QPCh. 8 - Prob. 8.42QPCh. 8 - Prob. 8.43QPCh. 8 - Prob. 8.44QPCh. 8 - Prob. 8.45QPCh. 8 - Prob. 8.46QPCh. 8 - Prob. 8.47QPCh. 8 - Prob. 8.48QPCh. 8 - 8.49 Define ionization energy. Ionization energy...Ch. 8 - Prob. 8.50QPCh. 8 - Prob. 8.51QPCh. 8 - Prob. 8.52QPCh. 8 - Prob. 8.53QPCh. 8 - Prob. 8.54QPCh. 8 - Prob. 8.55QPCh. 8 - Prob. 8.56QPCh. 8 - Prob. 8.57QPCh. 8 - Prob. 8.58QPCh. 8 - Prob. 8.59QPCh. 8 - Prob. 8.60QPCh. 8 - Prob. 8.61QPCh. 8 - Prob. 8.62QPCh. 8 - Prob. 8.63QPCh. 8 - Prob. 8.64QPCh. 8 - Prob. 8.65QPCh. 8 - Prob. 8.66QPCh. 8 - Prob. 8.67QPCh. 8 - 8.68 Why are the Group 1B elements more stable...Ch. 8 - Prob. 8.69QPCh. 8 - Prob. 8.70QPCh. 8 - Prob. 8.71QPCh. 8 - Prob. 8.72QPCh. 8 - Prob. 8.73QPCh. 8 - Prob. 8.74QPCh. 8 - Prob. 8.75QPCh. 8 - Prob. 8.76QPCh. 8 - Prob. 8.77QPCh. 8 - Prob. 8.78QPCh. 8 - Prob. 8.79QPCh. 8 - Prob. 8.80QPCh. 8 - Prob. 8.81QPCh. 8 - Prob. 8.82QPCh. 8 - Prob. 8.83QPCh. 8 - Prob. 8.84QPCh. 8 - Prob. 8.85QPCh. 8 - Prob. 8.86QPCh. 8 - Prob. 8.87QPCh. 8 - Prob. 8.88QPCh. 8 - Prob. 8.89QPCh. 8 - 8.90 Write the formulas and names of the oxides of...Ch. 8 - Prob. 8.91QPCh. 8 - Prob. 8.92QPCh. 8 - Prob. 8.93QPCh. 8 - Prob. 8.94QPCh. 8 - Prob. 8.95QPCh. 8 - Prob. 8.96QPCh. 8 - Prob. 8.97QPCh. 8 - Prob. 8.98QPCh. 8 - 8.99 Explain why the electron affinity of nitrogen...Ch. 8 - Prob. 8.100QPCh. 8 - Prob. 8.101QPCh. 8 - Prob. 8.102QPCh. 8 - Prob. 8.103QPCh. 8 - Prob. 8.104QPCh. 8 - Prob. 8.105QPCh. 8 - Prob. 8.106QPCh. 8 - Prob. 8.107SPCh. 8 - 8.108 In the late 1800s the British physicist Lord...Ch. 8 - Prob. 8.109SPCh. 8 - Prob. 8.110SPCh. 8 - Prob. 8.111SPCh. 8 - Prob. 8.112SPCh. 8 - Prob. 8.113SPCh. 8 - Prob. 8.114SP
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