CHEM:ATOM FOC 2E CL (TEXT)
2nd Edition
ISBN: 9780393284218
Author: Stacey Lowery Bretz, Natalie Foster, Thomas R. Gilbert, Rein V. Kirss
Publisher: WW Norton & Co
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Question
Chapter 8, Problem 8.85QA
Interpretation Introduction
To find:
The change in the oxidation state of carbon in the reaction,
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5.
Count the electrons on the following complexes and state whether they follow the 18-
electron rule:
(3 points)
Fe(CO)5
Ni(PMe3)4
PMe3 is trimethylphosphine
Mn(CO)5Br
For questions 1-4, consider the following complexes:
[Co(CN)6]+,
[CoCl4]²,
[Cr(H2O)6]²+
2. Draw the corresponding d-orbital splitting for each of the complexes; predict the spin-
state (low-spin/high spin) for each of the complexes (if applicable); explain your arguments.
Calculate the crystal field stabilization energy for each complex (in Ao or At).
(6 points)
For questions 1-4, consider the following complexes:
[Co(CN)6]4,
[COC14]²,
[Cr(H2O)6]²+
1. Assign oxidation number to the metal, then indicate d-electron count. (3 points)
Chapter 8 Solutions
CHEM:ATOM FOC 2E CL (TEXT)
Ch. 8 - Prob. 8.1VPCh. 8 - Prob. 8.2VPCh. 8 - Prob. 8.3VPCh. 8 - Prob. 8.4VPCh. 8 - Prob. 8.5VPCh. 8 - Prob. 8.6VPCh. 8 - Prob. 8.7VPCh. 8 - Prob. 8.8VPCh. 8 - Prob. 8.9VPCh. 8 - Prob. 8.10VP
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