PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
2nd Edition
ISBN: 9781285074788
Author: Ball
Publisher: CENGAGE L
bartleby

Concept explainers

Question
Book Icon
Chapter 8, Problem 8.84E
Interpretation Introduction

Interpretation:

The varying values of force on two unit charges, between a vacuum and some medium with a nonzero dielectric constant, are to be calculated. The same evaluations obtained for charges of same sign are to be explained and the results are to be compared with charges of opposite sign.

Concept introduction:

The force of attraction between two charged particles is directly proportional to the product of their charges and inversely proportional to the square of distance between them. The formula for determining force of attraction is given below.

F=q1q24πεoεrr2

In the above equation, F is the force of attraction between two charges, q1 and q2 are the charges, r is the distance between charges, εr is the dielectric constant of the medium and εo is the permittivity of free space. The value of εo is defined as 8.854×1012 C2 J1m1.

Expert Solution & Answer
Check Mark

Answer to Problem 8.84E

The varying values of force on two unit charges between a vacuum and some medium with a nonzero dielectric constant are calculated. The same evaluations are obtained for charges of same sign but having positive values. The results with charges of opposite sign are compared with that of same sign.

Explanation of Solution

The expression of force between unit charges of opposite sign in vacuum can be written as follows.

F=14×3.14×8.854×1012×r2

The expression of force between unit charges of opposite sign in medium (taking water) having dielectric constant (78) can be written as follows.

F=14×3.14×8.854×1012×78×r2

The table having the force between the two charges at distances ranging from 1Α to 25Α in 1Α increments is given below.

Distance (m) Force in vacuum(N) Force in medium(N)
1×1010 8.89×1029 1.43×1028
2×1010 2.25×1029 2.28×1027
3×1010 9.99×1028 1.16×1027
4×1010 5.62×1028 3.65×1027
5×1010 3.60×1028 8.92×1027
6×1010 2.50×1028 1.85×1026
7×1010 1.83×1028 3.42×1026
8×1010 1.40×1028 5.84×1026
9×1010 1.11×1028 9.36×1026
10×1010 8.99×1027 1.43×1025
11×1010 7.43×1027 2.09×1025
12×1010 6.24×1027 2.96×1025
13×1010 5.32×1027 4.07×1025
14×1010 4.59×1027 5.48×1025
15×1010 3.99×1027 7.22×1025
16×1010 3.51×1027 9.35×1025
17×1010 3.11×1027 1.19×1024
18×1010 2.77×1027 1.50×1024
19×1010 2.49×1027 1.86×1024
20×1010 2.25×1027 2.28×1024
21×1010 2.04×1027 2.77×1024
22×1010 1.86×1027 3.34×1024
23×1010 1.70×1027 3.99×1024
24×1010 1.56×1027 4.73×1024
25×1010 1.44×1027 5.57×1024

The expression of force between unit charges of same sign in vacuum can be written as follows.

F=14×3.14×8.854×1012×r2

The expression of force between unit charges of same sign in medium (taking water) having dielectric constant (78) can be written as follows.

F=14×3.14×8.854×1012×78×r2

The table having the force between the two charges having same sign at distances ranging from 1Α to 25Α in 1Α increments is given below.

Distance (m) Force in vacuum(N) Force in medium(N)
1×1010 8.89×1029 1.43×1028
2×1010 2.25×1029 2.28×1027
3×1010 9.99×1028 1.16×1027
4×1010 5.62×1028 3.65×1027
5×1010 3.60×1028 8.92×1027
6×1010 2.50×1028 1.85×1026
7×1010 1.83×1028 3.42×1026
8×1010 1.40×1028 5.84×1026
9×1010 1.11×1028 9.36×1026
10×1010 8.99×1027 1.43×1025
11×1010 7.43×1027 2.09×1025
12×1010 6.24×1027 2.96×1025
13×1010 5.32×1027 4.07×1025
14×1010 4.59×1027 5.48×1025
15×1010 3.99×1027 7.22×1025
16×1010 3.51×1027 9.35×1025
17×1010 3.11×1027 1.19×1024
18×1010 2.77×1027 1.50×1024
19×1010 2.49×1027 1.86×1024
20×1010 2.25×1027 2.28×1024
21×1010 2.04×1027 2.77×1024
22×1010 1.86×1027 3.34×1024
23×1010 1.70×1027 3.99×1024
24×1010 1.56×1027 4.73×1024
25×1010 1.44×1027 5.57×1024

The forcebetween unit charges of same sign and that between opposite sign is different. Forcebetween unit charges of same sign represents repulsion while that between opposite sign represent attraction.

Conclusion

The varying values of force on two unit charges between a vacuum and some medium with a nonzero dielectric constant are calculated. The same evaluations are obtained for charges of same sign but having positive values due to difference in charge. The results with charges of opposite sign are compared with that of the values of same sign.

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!
Students have asked these similar questions
The mobility of a Li+ ion in aqueous solution is 4.01 × 10−8 m2 s−1 V−1 at 25 °C. The potential difference between two electrodes separated by 5.00 mm and placed in the solution, is 24.0 V. What is the drift speed of the ion?
The mobility of a Rb+ ion in aqueous solution is 7.92 × 10−8 m2 s−1 V−1 at 25 °C. The potential difference between two electrodes, separated by 7.00 mm and placed in the solution, is 25.0 V. What is the drift speed of the Rb+ ion?
Assume the energy of hydrogen bonds per base pair to be 5.86 kJ·mol-1. Given two complementary strands of DNA containing 145 base pairs each, calculate the ratio of two separate strands to hydrogen-bonded double helix in solution at 319 K. ratio = 0

Chapter 8 Solutions

PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.

Ch. 8 - Prob. 8.11ECh. 8 - Prob. 8.12ECh. 8 - 8.13. Is the disproportionation reaction...Ch. 8 - Prob. 8.14ECh. 8 - Prob. 8.15ECh. 8 - Prob. 8.16ECh. 8 - Prob. 8.17ECh. 8 - 8.18. Determine and for each of the following...Ch. 8 - Prob. 8.19ECh. 8 - Prob. 8.20ECh. 8 - Prob. 8.21ECh. 8 - Prob. 8.22ECh. 8 - Prob. 8.23ECh. 8 - Prob. 8.24ECh. 8 - Prob. 8.25ECh. 8 - Prob. 8.26ECh. 8 - Prob. 8.27ECh. 8 - What is the Zn2+:Cu2+ ratio on a Daniell cell that...Ch. 8 - Prob. 8.29ECh. 8 - Determine the voltage of this reaction with the...Ch. 8 - The thermite reaction can act as the basis of an...Ch. 8 - A concentration cell has different concentrations...Ch. 8 - Prob. 8.34ECh. 8 - Prob. 8.35ECh. 8 - a What is the equilibrium constant for the...Ch. 8 - Prob. 8.37ECh. 8 - Prob. 8.38ECh. 8 - Prob. 8.39ECh. 8 - Prob. 8.40ECh. 8 - Prob. 8.41ECh. 8 - Consider the following formation reaction for HI:...Ch. 8 - Prob. 8.43ECh. 8 - 8.44. Determine an expression for , the change in...Ch. 8 - Prob. 8.45ECh. 8 - Prob. 8.46ECh. 8 - Determine the equilibrium constant for the...Ch. 8 - Prob. 8.48ECh. 8 - Prob. 8.49ECh. 8 - What is the solubility product constant of Hg2Cl2,...Ch. 8 - Prob. 8.51ECh. 8 - Prob. 8.52ECh. 8 - Prob. 8.53ECh. 8 - Prob. 8.54ECh. 8 - Prob. 8.55ECh. 8 - Prob. 8.56ECh. 8 - Prob. 8.57ECh. 8 - Show that a can be written as n+mnn+n+nn, where m...Ch. 8 - Prob. 8.59ECh. 8 - Prob. 8.60ECh. 8 - What molality of NaCl is necessary to have the...Ch. 8 - Prob. 8.62ECh. 8 - Prob. 8.63ECh. 8 - Calculate the molar enthalpy of formation of I(aq)...Ch. 8 - Prob. 8.65ECh. 8 - Hydrofluoric acid, HF(aq), is a weak acid that is...Ch. 8 - Prob. 8.68ECh. 8 - Prob. 8.69ECh. 8 - Prob. 8.70ECh. 8 - Prob. 8.71ECh. 8 - Prob. 8.72ECh. 8 - The mean activity coefficient for an aqueous...Ch. 8 - Human blood plasma is approximately 0.9NaCl. What...Ch. 8 - Under what conditions does the extended...Ch. 8 - Prob. 8.76ECh. 8 - Approximate the expected voltage for the following...Ch. 8 - Prob. 8.78ECh. 8 - Prob. 8.79ECh. 8 - Prob. 8.80ECh. 8 - a The salt NaNO3 can be thought of as...Ch. 8 - Prob. 8.82ECh. 8 - What is the estimated velocity for Cu2+ ions...Ch. 8 - Prob. 8.84ECh. 8 - Prob. 8.85ECh. 8 - Prob. 8.86ECh. 8 - Calculate a the solubility product constant for...
Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Text book image
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Text book image
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Text book image
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Text book image
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY