(a) Interpretation: Out of the two equilibrium illustrated the one having the equilibrium lying farther to the right is to be stated. Concept introduction: The saturated six-membered ring compounds are mostly expressed and explained in the chair conformations. This is because the chair conformation is the most stable conformation of cyclohexane. Thus, the chair conformation is most helpful in the studies of six-membered ring compounds. Cis-trans relation between the substituents is denoted by their axial and equatorial positions.

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Answer 1

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Chapter 8, Problem 8.57AP

Interpretation Introduction

(a)

Interpretation:

Out of the two equilibrium illustrated the one having the equilibrium lying farther to the right is to be stated.

Concept introduction:

The saturated six-membered ring compounds are mostly expressed and explained in the chair conformations. This is because the chair conformation is the most stable conformation of cyclohexane. Thus, the chair conformation is most helpful in the studies of six-membered ring compounds.

Cis-trans relation between the substituents is denoted by their axial and equatorial positions.

Interpretation Introduction

(b)

Interpretation:

The compound having a greater amount of gauche confirmation is to be stated.

Concept introduction:

The Newman projection is one of the representation to understand the stereochemistry of alkane compounds. In this projection, one carbon-carbon is chosen in which front carbon is represented by dot and back carbon by as a circle. The substituent is attached to the carbon in the Y shape.

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1. Using radii from Resource section 1 (p.901) and Born-Lande equation, calculate the lattice energy for PbS, which crystallizes in the NaCl structure. Then, use the Born-Haber cycle to obtain the value of lattice energy for PbS. You will need the following data following data: AH Pb(g) = 196 kJ/mol; AHƒ PbS = −98 kJ/mol; electron affinities for S(g)→S¯(g) is -201 kJ/mol; S¯(g) (g) is 640kJ/mol. Ionization energies for Pb are listed in Resource section 2, p.903. Remember that enthalpies of formation are calculated beginning with the elements in their standard states (S8 for sulfur). The formation of S2, AHF: S2 (g) = 535 kJ/mol. Compare the two values, and explain the difference. (8 points)

Answer 2

Question

Chapter 8, Problem 8.57AP

Interpretation Introduction

(a)

Interpretation:

Out of the two equilibrium illustrated the one having the equilibrium lying farther to the right is to be stated.

Concept introduction:

The saturated six-membered ring compounds are mostly expressed and explained in the chair conformations. This is because the chair conformation is the most stable conformation of cyclohexane. Thus, the chair conformation is most helpful in the studies of six-membered ring compounds.

Cis-trans relation between the substituents is denoted by their axial and equatorial positions.

Interpretation Introduction

(b)

Interpretation:

The compound having a greater amount of gauche confirmation is to be stated.

Concept introduction:

The Newman projection is one of the representation to understand the stereochemistry of alkane compounds. In this projection, one carbon-carbon is chosen in which front carbon is represented by dot and back carbon by as a circle. The substituent is attached to the carbon in the Y shape.

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Answer 3

Question

Chapter 8, Problem 8.57AP

Interpretation Introduction

(a)

Interpretation:

Out of the two equilibrium illustrated the one having the equilibrium lying farther to the right is to be stated.

Concept introduction:

The saturated six-membered ring compounds are mostly expressed and explained in the chair conformations. This is because the chair conformation is the most stable conformation of cyclohexane. Thus, the chair conformation is most helpful in the studies of six-membered ring compounds.

Cis-trans relation between the substituents is denoted by their axial and equatorial positions.

Interpretation Introduction

(b)

Interpretation:

The compound having a greater amount of gauche confirmation is to be stated.

Concept introduction:

The Newman projection is one of the representation to understand the stereochemistry of alkane compounds. In this projection, one carbon-carbon is chosen in which front carbon is represented by dot and back carbon by as a circle. The substituent is attached to the carbon in the Y shape.

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Answer 4

Question

Chapter 8, Problem 8.57AP

Interpretation Introduction

(a)

Interpretation:

Out of the two equilibrium illustrated the one having the equilibrium lying farther to the right is to be stated.

Concept introduction:

The saturated six-membered ring compounds are mostly expressed and explained in the chair conformations. This is because the chair conformation is the most stable conformation of cyclohexane. Thus, the chair conformation is most helpful in the studies of six-membered ring compounds.

Cis-trans relation between the substituents is denoted by their axial and equatorial positions.

Interpretation Introduction

(b)

Interpretation:

The compound having a greater amount of gauche confirmation is to be stated.

Concept introduction:

The Newman projection is one of the representation to understand the stereochemistry of alkane compounds. In this projection, one carbon-carbon is chosen in which front carbon is represented by dot and back carbon by as a circle. The substituent is attached to the carbon in the Y shape.

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Answer 5

Chapter 8, Problem 8.57AP

Interpretation Introduction

(a)

Interpretation:

Out of the two equilibrium illustrated the one having the equilibrium lying farther to the right is to be stated.

Concept introduction:

The saturated six-membered ring compounds are mostly expressed and explained in the chair conformations. This is because the chair conformation is the most stable conformation of cyclohexane. Thus, the chair conformation is most helpful in the studies of six-membered ring compounds.

Cis-trans relation between the substituents is denoted by their axial and equatorial positions.

Interpretation Introduction

(b)

Interpretation:

The compound having a greater amount of gauche confirmation is to be stated.

Concept introduction:

The Newman projection is one of the representation to understand the stereochemistry of alkane compounds. In this projection, one carbon-carbon is chosen in which front carbon is represented by dot and back carbon by as a circle. The substituent is attached to the carbon in the Y shape.

Answer 6

Chapter 8, Problem 8.57AP

Interpretation Introduction

(a)

Interpretation:

Out of the two equilibrium illustrated the one having the equilibrium lying farther to the right is to be stated.

Concept introduction:

The saturated six-membered ring compounds are mostly expressed and explained in the chair conformations. This is because the chair conformation is the most stable conformation of cyclohexane. Thus, the chair conformation is most helpful in the studies of six-membered ring compounds.

Cis-trans relation between the substituents is denoted by their axial and equatorial positions.

Answer 7

Chapter 8, Problem 8.57AP

Interpretation Introduction

(a)

Interpretation:

Out of the two equilibrium illustrated the one having the equilibrium lying farther to the right is to be stated.

Concept introduction:

The saturated six-membered ring compounds are mostly expressed and explained in the chair conformations. This is because the chair conformation is the most stable conformation of cyclohexane. Thus, the chair conformation is most helpful in the studies of six-membered ring compounds.

Cis-trans relation between the substituents is denoted by their axial and equatorial positions.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The compound having a greater amount of gauche confirmation is to be stated.

Concept introduction:

The Newman projection is one of the representation to understand the stereochemistry of alkane compounds. In this projection, one carbon-carbon is chosen in which front carbon is represented by dot and back carbon by as a circle. The substituent is attached to the carbon in the Y shape.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The compound having a greater amount of gauche confirmation is to be stated.

Concept introduction:

The Newman projection is one of the representation to understand the stereochemistry of alkane compounds. In this projection, one carbon-carbon is chosen in which front carbon is represented by dot and back carbon by as a circle. The substituent is attached to the carbon in the Y shape.

Answer 10

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Answer 13

Ch. 8 - Prob. 8.1P Ch. 8 - Prob. 8.2P Ch. 8 - Prob. 8.3P Ch. 8 - Prob. 8.4P Ch. 8 - Prob. 8.5P Ch. 8 - Prob. 8.6P Ch. 8 - Prob. 8.7P Ch. 8 - Prob. 8.8P Ch. 8 - Prob. 8.9P Ch. 8 - Prob. 8.10P

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