Chemistry (7th Edition)
7th Edition
ISBN: 9780321943170
Author: John E. McMurry, Robert C. Fay, Jill Kirsten Robinson
Publisher: PEARSON
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Chapter 8, Problem 8.55SP
Predict values for all bond angles in dimethyl sulfoxide, a powerful solvent used in veterinary medicine to treat inflammation.
Dimethyl sulfoxide
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HF is a weak acid.
acids:
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1.0 L of a 0.5 M HF
solution.
bases:
Х
other: ☐
acids:
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1.0 L of a solution that is
1.4M in both HF and NaF.
bases:
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that NH3 is a weak base.
acids: ☐
1.8 mol of HCl is added to
1.0 L of a 1.0M NH3
bases: ☐
solution.
other: ☐
0.18 mol of HNO3 is added
to 1.0 L of a solution that is
1.4M in both NH3 and
NH₁Br.
acids:
bases: ☐
other: ☐
0,0,...
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000
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B
1
Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NH3 (g) = N2 (g) +3H₂
—N2 (g) AGº = 34. kJ
Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this
system:
rise
Under these conditions, will the pressure of NH 3 tend to rise or fall?
☐ x10
fall
Х
Is it possible to reverse this tendency by adding H₂?
In other words, if you said the pressure of NH 3 will tend to rise, can that
be changed to a tendency to fall by adding H₂? Similarly, if you said the
pressure of NH3 will tend to fall, can that be changed to a tendency to
rise by adding H₂?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of H₂ needed to reverse it.
Round your answer to 2 significant digits.
yes
no
atm
00.
18
Ar
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Chapter 8 Solutions
Chemistry (7th Edition)
Ch. 8 - Prob. 8.1PCh. 8 - Prob. 8.2ACh. 8 - PRACTICE 8.3 Acetic acid, CH3CO2H , is the main...Ch. 8 - APPLY 8.4 Benzene, C6H6 , is a cyclic molecule in...Ch. 8 - PRACTICE 8.5 Identify the orbitals that overlap to...Ch. 8 - APPLY 8.6 Describe the bonding in propane, C3H8 ,...Ch. 8 - PRACTICE 8.7 Describe the hybridization of the...Ch. 8 - APPLY 8.8 Describe the hybridization of each...Ch. 8 - PRACTICE 8.9 Describe the hybridization of the...Ch. 8 - APPLY 8.10 Describe the hybridization of the...
Ch. 8 - Prob. 8.11PCh. 8 - Conceptual APPLY 8.12 Match the following...Ch. 8 - Prob. 8.13PCh. 8 - Prob. 8.14ACh. 8 - Prob. 8.15PCh. 8 - Prob. 8.16ACh. 8 - Prob. 8.17PCh. 8 - Prob. 8.18ACh. 8 - Prob. 8.19PCh. 8 - Prob. 8.20ACh. 8 - Prob. 8.21PCh. 8 - Prob. 8.22ACh. 8 - PRACTICE 8.23 Draw two resonance structures for...Ch. 8 - APPLY 8.24 Draw two resonance structures for the...Ch. 8 - Prob. 8.25PCh. 8 - Prob. 8.26PCh. 8 - PROBLEM 8.27 Identify which of the following...Ch. 8 - Prob. 8.28PCh. 8 - Prob. 8.29PCh. 8 - Prob. 8.30PCh. 8 - Prob. 8.31CPCh. 8 - Prob. 8.32CPCh. 8 - Prob. 8.33CPCh. 8 - Prob. 8.34CPCh. 8 - Prob. 8.35CPCh. 8 - Prob. 8.36CPCh. 8 - Prob. 8.37CPCh. 8 - Prob. 8.38CPCh. 8 - Prob. 8.39CPCh. 8 - Prob. 8.40CPCh. 8 - Two dichioroethylene molecules with the same...Ch. 8 - Prob. 8.42SPCh. 8 - Prob. 8.43SPCh. 8 - Prob. 8.44SPCh. 8 - How many charge clouds are there around the...Ch. 8 - Prob. 8.46SPCh. 8 - Prob. 8.47SPCh. 8 - What shape do you expect for each of the following...Ch. 8 - Prob. 8.49SPCh. 8 - Prob. 8.50SPCh. 8 - Prob. 8.51SPCh. 8 - Prob. 8.52SPCh. 8 - Prob. 8.53SPCh. 8 - Acrylonitrile is used as the starting material for...Ch. 8 - Predict values for all bond angles in dimethyl...Ch. 8 - Oceanographers study the mixing of water masses by...Ch. 8 - Prob. 8.57SPCh. 8 - Prob. 8.58SPCh. 8 - Prob. 8.59SPCh. 8 - Prob. 8.60SPCh. 8 - Prob. 8.61SPCh. 8 - Prob. 8.62SPCh. 8 - Prob. 8.63SPCh. 8 - Prob. 8.64SPCh. 8 - Prob. 8.65SPCh. 8 - Oxaloacetic acid is an intermediate involved in...Ch. 8 - The atoms in the amino acid glycine are connected...Ch. 8 - Prob. 8.68SPCh. 8 - Prob. 8.69SPCh. 8 - Prob. 8.70SPCh. 8 - 8.71 What is the difference between London...Ch. 8 - 8.72 What are the most important kinds of...Ch. 8 - Of the substances Xe,CH3Cl,HF, which has: (a) The...Ch. 8 - 8.74 Methanol boils nearlyhigher than methane, but...Ch. 8 - Prob. 8.75SPCh. 8 - Prob. 8.76SPCh. 8 - Prob. 8.77SPCh. 8 - Prob. 8.78SPCh. 8 - Prob. 8.79SPCh. 8 - Prob. 8.80SPCh. 8 - 8.81 Draw three-dimensional structures of PCl3 and...Ch. 8 - Prob. 8.82SPCh. 8 - Prob. 8.83SPCh. 8 - Prob. 8.84SPCh. 8 - Prob. 8.85SPCh. 8 - 8.86 A liquid sample contains methylamine (CH3NH2)...Ch. 8 - Prob. 8.87SPCh. 8 - Prob. 8.88SPCh. 8 - Prob. 8.89SPCh. 8 - Prob. 8.90SPCh. 8 - Prob. 8.91SPCh. 8 - Prob. 8.92SPCh. 8 - Prob. 8.93SPCh. 8 - Prob. 8.94SPCh. 8 - Prob. 8.95SPCh. 8 - Prob. 8.96SPCh. 8 - Prob. 8.98CPCh. 8 - Prob. 8.99CPCh. 8 - Prob. 8.100CPCh. 8 - Prob. 8.101CPCh. 8 - Prob. 8.102CPCh. 8 - Prob. 8.103CPCh. 8 - Prob. 8.104CPCh. 8 - Prob. 8.105CPCh. 8 - Prob. 8.106CPCh. 8 - Prob. 8.107CPCh. 8 - Prob. 8.108CPCh. 8 - Prob. 8.109CPCh. 8 - The odor of cinnamon oil is due to cinnamaldehyde,...Ch. 8 - Prob. 8.111CPCh. 8 - Prob. 8.112CPCh. 8 - Prob. 8.113CPCh. 8 - Prob. 8.114CPCh. 8 - Prob. 8.115CPCh. 8 - Prob. 8.116CPCh. 8 - Prob. 8.117CPCh. 8 - Prob. 8.118CPCh. 8 - Prob. 8.119MPCh. 8 - Prob. 8.120MPCh. 8 - Prob. 8.121MP
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