
(a)
Interpretation:
The direction of the equilibrium shift and the change that will be observed (color, amount of precipitate, etc.) in the given equilibria when the indicated stress is applied is to be predicted using the Le Chȃtelier’s principle.
Concept introduction:
The equilibrium constant is a parameter which describes the relationship between concentration of the reactants and the products at equilibrium stage. Equilibrium constant of a reaction is expressed by the ratio of concentration of product species raised to the power of their

Answer to Problem 8.54E
The shift in the equilibrium will be towards the right direction and dark purple color will be observed due to the formation of copper complex.
Explanation of Solution
According to the Le Chȃtelier’s principle the change in concentration, volume, pressure and temperature affects the equilibrium of the reaction.
The given equilibrium reaction is shown below.
It is considered that when
The shift in the equilibrium will be towards the right direction and dark purple color will be observed due to the formation of copper complex.
(b)
Interpretation:
The direction of the equilibrium shift and the change that will be observed (color, amount of precipitate, etc.) in the given equilibria when the indicated stress is applied is to be predicted using the Le Chȃtelier’s principle.
Concept introduction:
The equilibrium constant is a parameter which describes the relationship between concentration of the reactants and the products at equilibrium stage. Equilibrium constant of a reaction is expressed by the ratio of concentration of product species raised to the power of their stoichiometric coefficients to the concentration of reactant species raised to the power of their stoichiometric coefficients.

Answer to Problem 8.54E
The shift in the equilibrium will be towards the right direction and white solid will be formed due to the formation of lead chloride.
Explanation of Solution
According to the Le Chȃtelier’s principle the change in concentration, volume, pressure and temperature affects the equilibrium of the reaction.
The given equilibrium reaction is shown below.
It is considered that whenequilibrium mixture is cooled, the temperature on right hand side decreases. Hence, according to the Le Chȃtelier’s principle, the equilibrium will shift towards right direction to compensate the decrease in temperature. Thus, the white solid would be formed due to the formation of lead chloride.
The shift in the equilibrium will be towards the right direction and white solid will be formed due to the formation of lead chloride.
(c)
Interpretation:
The direction of the equilibrium shift and the change that will be observed (color, amount of precipitate, etc.) in the given equilibria when the indicated stress is applied is to be predicted using the Le Chȃtelier’s principle.
Concept introduction:
The equilibrium constant is a parameter which describes the relationship between concentration of the reactants and the products at equilibrium stage. Equilibrium constant of a reaction is expressed by the ratio of concentration of product species raised to the power of their stoichiometric coefficients to the concentration of reactant species raised to the power of their stoichiometric coefficients.

Answer to Problem 8.54E
The shift in the equilibrium will be towards the right direction and colorless gas will be liberated due to the formation of
Explanation of Solution
According to the Le Chȃtelier’s principle the change in concentration, volume, pressure and temperature affects the equilibrium of the reaction.
The given equilibrium reaction is shown below.
It is considered that when the some amount of
The shift in the equilibrium will be towards the right direction and colorless gas will be liberated due to the formation of
(d)
Interpretation:
The direction of the equilibrium shift and the change that will be observed (color, amount of precipitate, etc.) in the given equilibria when the indicated stress is applied is to be predicted using the Le Chȃtelier’s principle.
Concept introduction:
The equilibrium constant is a parameter which describes the relationship between concentration of the reactants and the products at equilibrium stage. Equilibrium constant of a reaction is expressed by the ratio of concentration of product species raised to the power of their stoichiometric coefficients to the concentration of reactant species raised to the power of their stoichiometric coefficients.

Answer to Problem 8.54E
The shift in the equilibrium will be towards the right direction and colorless gas will be liberated due to the formation of
Explanation of Solution
According to the Le Chȃtelier’s principle the change in concentration, volume, pressure and temperature affects the equilibrium of the reaction.
The given equilibrium reaction is shown below.
It is considered that whenequilibrium mixture is cooled, thus the temperature on right hand side decreases. Hence, according to the Le Chȃtelier’s principle, the equilibrium will shift towards right direction to compensate the decrease in temperature. Thus, the colorless gas will be liberated due to the formation of
The shift in the equilibrium will be towards the right direction and colorless gas will be liberated due to the formation of
(e)
Interpretation:
The direction of the equilibrium shift and the change that will be observed (color, amount of precipitate, etc.) in the given equilibria when the indicated stress is applied is to be predicted using the Le Chȃtelier’s principle.
Concept introduction:
The equilibrium constant is a parameter which describes the relationship between concentration of the reactants and the products at equilibrium stage. Equilibrium constant of a reaction is expressed by the ratio of concentration of product species raised to the power of their stoichiometric coefficients to the concentration of reactant species raised to the power of their stoichiometric coefficients.

Answer to Problem 8.54E
There will be no effect of catalyst on the equilibrium. The shift in the equilibrium will be towards the left direction due to the addition of
Explanation of Solution
According to the Le Chȃtelier’s principle the change in concentration, volume, pressure and temperature affects the equilibrium of the reaction.
The given equilibrium reaction is shown below.
It is considered that when catalyst and
There will be no effect of catalyst on the equilibrium. The shift in the equilibrium will be towards the left direction due to the addition of
Want to see more full solutions like this?
Chapter 8 Solutions
Study Guide with Student Solutions Manual for Seager/Slabaugh/Hansen's Chemistry for Today: General, Organic, and Biochemistry, 9th Edition
- The temperature on a sample of pure X held at 1.25 atm and -54. °C is increased until the sample boils. The temperature is then held constant and the pressure is decreased by 0.42 atm. On the phase diagram below draw a path that shows this set of changes. pressure (atm) 2 0 0 200 400 temperature (K) Xarrow_forwardQUESTION: Answer Question 5: 'Calculating standard error of regression' STEP 1 by filling in all the empty green boxes *The values are all provided in the photo attached*arrow_forwardpressure (atm) 3 The pressure on a sample of pure X held at 47. °C and 0.88 atm is increased until the sample condenses. The pressure is then held constant and the temperature is decreased by 82. °C. On the phase diagram below draw a path that shows this set of changes. 0 0 200 temperature (K) 400 аarrow_forward
- er your payment details | bar xb Home | bartleby x + aleksogi/x/isl.exe/1o u-lgNskr7j8P3jH-1Qs_pBanHhviTCeeBZbufuBYT0Hz7m7D3ZcW81NC1d8Kzb4srFik1OUFhKMUXzhGpw7k1 O States of Matter Sketching a described thermodynamic change on a phase diagram 0/5 The pressure on a sample of pure X held at 47. °C and 0.88 atm is increased until the sample condenses. The pressure is then held constant and the temperature is decreased by 82. °C. On the phase diagram below draw a path that shows this set of changes. pressure (atm) 1 3- 0- 0 200 Explanation Check temperature (K) 400 X Q Search L G 2025 McGraw Hill LLC. All Rights Reserved Terms of Use Privacy Cearrow_forward5.arrow_forward6.arrow_forward
- Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningGeneral Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning





