Elements Of Physical Chemistry
Elements Of Physical Chemistry
7th Edition
ISBN: 9780198796701
Author: ATKINS, P. W. (peter William), De Paula, Julio
Publisher: Oxford University Press
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Chapter 8, Problem 8.4P

(a)

Interpretation Introduction

Interpretation:

The wavelength of the next line in the given series of lines of spectrum of atomic hydrogen has to be identified.

(a)

Expert Solution
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Explanation of Solution

All the lines in the hydrogen spectrum suits the Rydberg formula.

    1λ=RH(1n21-1n22)WhereλisthewavelengthoftheemittedphotonR is Rydberg’s constantZ is the atomic number (1 for H, 2 for He)n1 and n2 are the principal quantum numbers for the initial and final states

Find n1 from the value of  λmax, which arises from the transition of n1+1n1.

    1λmaxRH=1n21-(1n1+1)2=2n1+1n21(n1+1)2λmaxRH=n21(n1+1)22n1+1=(656.46×10-9m)×(109677×102m-1)=7.20hencen1=2,asdeterminedbytrialanderrorsubstitution.Therefore,thetransitionsaregivenas,υ=1λ=(109677cm-1)×(14-1n22)n2=3,4,5,6Nextlinehasn2=7υ=1λ=(109677cm-1)×(14-149)=397.13nm

The energy needed to ionize the atom is obtained by allowing n2

    υ=1λ=(109677cm-1)×(14-0)=27419cm-1υ=3.40ev

(b)

Interpretation Introduction

Interpretation:

The ionization energy of hydrogen atom when it is in lower state of transition has to be identified.

(b)

Expert Solution
Check Mark

Explanation of Solution

The energy needed to ionize the atom is obtained by allowing n2

    υ=1λ=(109677cm-1)×(14-0)=27419cm-11cm-1=1.2398×10-4evυ=3.40ev

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