Us Solutions Manual To Accompany Elements Of Physical Chemistry 7e
7th Edition
ISBN: 9780198802259
Author: ATKINS
Publisher: Oxford University Press
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Chapter 8, Problem 8.3DQ
Interpretation Introduction
Interpretation:
The orbital approximation for the wave function of a many-electron atom and its limitations has to be described.
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What is the relationship between A and B?
H3C
A
Br
Cl
H3C
B
Br
relationship
(check all that apply)
O same molecule
O enantiomer
O diastereomer
structural isomer
O stereoisomer
isomer
O need more information to decide
O same molecule
☐ enantiomer
Br
Br
Br
CH3
Br
CI
CH3
O diastereomer
☐ structural isomer
☐ stereoisomer
isomer
O need more information to decide
O same molecule
O enantiomer
Odiastereomer
structural isomer
O stereoisomer
☐ isomer
O need more information to decide
b. Please complete the zig-zag conformation of the compound
(3R,4S)-3,4-dichloro-2,5-dimethylhexane by writing the respective atoms in the boxes.
4
c. Serricornin, the female-produced sex pheromone of the cigarette beetle, has the following structure.
OH
What is the maximum number of possible stereoisomers?
Is this structure a meso compound?
d. Please consider the natural product alkaloids shown below.
Are these two structures enantiomers, diastereomers or conformers?
H
HO
H
H
HN
HO
HN
R
R
с
R=H
cinchonidine
R=ET
cinchonine
H
Chapter 8 Solutions
Us Solutions Manual To Accompany Elements Of Physical Chemistry 7e
Ch. 8 - Prob. 8A.1STCh. 8 - Prob. 8A.2STCh. 8 - Prob. 8A.3STCh. 8 - Prob. 8A.4STCh. 8 - Prob. 8A.5STCh. 8 - Prob. 8B.2STCh. 8 - Prob. 8B.3STCh. 8 - Prob. 8B.4STCh. 8 - Prob. 8C.1STCh. 8 - Prob. 8C.2ST
Ch. 8 - Prob. 8D.1STCh. 8 - Prob. 8D.2STCh. 8 - Prob. 8D.3STCh. 8 - Prob. 8D.4STCh. 8 - Prob. 8D.5STCh. 8 - Prob. 8D.6STCh. 8 - Prob. 8D.7STCh. 8 - Prob. 8A.1ECh. 8 - Prob. 8A.2ECh. 8 - Prob. 8A.3ECh. 8 - Prob. 8A.6ECh. 8 - Prob. 8A.7ECh. 8 - Prob. 8A.8ECh. 8 - Prob. 8A.9ECh. 8 - Prob. 8A.10ECh. 8 - Prob. 8A.12ECh. 8 - Prob. 8B.1ECh. 8 - Prob. 8B.2ECh. 8 - Prob. 8B.3ECh. 8 - Prob. 8C.1ECh. 8 - Prob. 8C.2ECh. 8 - Prob. 8D.1ECh. 8 - Prob. 8D.2ECh. 8 - Prob. 8D.3ECh. 8 - Prob. 8D.4ECh. 8 - Prob. 8D.5ECh. 8 - Prob. 8D.6ECh. 8 - Prob. 8D.7ECh. 8 - Prob. 8D.8ECh. 8 - Prob. 8D.9ECh. 8 - Prob. 8D.11ECh. 8 - Prob. 8D.12ECh. 8 - Prob. 8.1DQCh. 8 - Prob. 8.2DQCh. 8 - Prob. 8.3DQCh. 8 - Prob. 8.4DQCh. 8 - Prob. 8.5DQCh. 8 - Prob. 8.6DQCh. 8 - Prob. 8.7DQCh. 8 - Prob. 8.8DQCh. 8 - Prob. 8.2PCh. 8 - Prob. 8.4PCh. 8 - Prob. 8.7PCh. 8 - Prob. 8.8PCh. 8 - Prob. 8.9PCh. 8 - Prob. 8.11PCh. 8 - Prob. 8.12P
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