Concept explainers
Interpretation:
The mass of ethylene glycol required to cause a freezing point depression of -10oC is to be calculated.
Concept introduction:
The effect of addition of a non-volatile component to a solvent is that the freezing point of the solvent is reduced. This is called freezing point depression. The extent of freezing point depression is directly proportional to the amount of non-volatile solute added.
Addition of one mole of any non-volatile solute decreases the freezing point of one kilogram of water by 1.86oC
For example Nacl dissociates to give Na+ and Cl- Since there are two particles per mole of Nacl it reduces the freezing point calculated as follows:
The formula to calculate number of moles from mass is given asfollows:
The formula to calculate the depression in freezing point is as follows:
The formula to calculate the molarity is as follows:
Want to see the full answer?
Check out a sample textbook solutionChapter 8 Solutions
Connect One Semester Access Card for General, Organic, & Biological Chemistry
- Q4: Draw the Lewis structures for the cyanate ion (OCN) and the fulminate ion (CNO). Draw all possible resonance structures for each. Determine which form for each is the major resonance contributor.arrow_forwardIn the following molecule, indicate the hybridization and shape of the indicated atoms. CH3 N CH3 HÖ: H3C CI: ::arrow_forwardQ3: Draw the Lewis structures for nitromethane (CH3NO2) and methyl nitrite (CH3ONO). Draw at least two resonance forms for each. Determine which form for each is the major resonance contributor.arrow_forward
- Q1: Draw a valid Lewis structures for the following molecules. Include appropriate charges and lone pair electrons. If there is more than one Lewis structure available, draw the best structure. NH3 Sulfate Boron tetrahydride. C3H8 (linear isomer) OCN NO3 CH3CN SO2Cl2 CH3OH2*arrow_forwardQ2: Draw all applicable resonance forms for the acetate ion CH3COO. Clearly show all lone pairs, charges, and arrow formalism.arrow_forwardPlease correct answer and don't used hand raitingarrow_forward
- 9. The following reaction, which proceeds via the SN1/E1 mechanisms, gives three alkene products (A, B, C) as well as an ether (D). (a) Show how each product arises mechanistically. (b) For the alkenes, determine the major product and justify your answer. (c) What clues in the reaction as shown suggest that this reaction does not go by the SN2/E2 mechanism route? (CH3)2CH-CH-CH3 CH3OH 1 Bl CH3OH ⑧· (CH3)2 CH-CH=CH2 heat H ⑥③ (CH3)2 C = C = CH3 © СнЗ-С-Снаснз сна (CH 3 ) 2 C H G H CH 3 оснзarrow_forwardPlease Don't used hand raitingarrow_forward7. For the following structure: ← Draw structure as is - NO BI H H Fisher projections (a) Assign R/S configuration at all chiral centers (show all work). Label the chiral centers with an asterisk (*). (b) Draw an enantiomer and diastereomer of the above structure and assign R/S configuration at all chiral centers (again, show all work). (c) On the basis of the R/S system, justify your designation of the structures as being enantiomeric or diastereomeric to the original structure.arrow_forward
- Don't used Ai solutionarrow_forward1. For the following reactions, predict the major product. Show stereochemistry where appropriate. неу b) 7 HBr XV ROOR H₂504 c) N/ H20 H+2 d) ~ Pt c) f. MCPBA -> сна сла (solvent) (1)BH 3-THE (3) Надрон B177 H20 9)arrow_forwardFor the following reactions, predict the major product. Show stereochemistry where approarrow_forward
- Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningGeneral, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
- Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning