Student Solutions Manual for Ball's Physical Chemistry, 2nd
2nd Edition
ISBN: 9798214169019
Author: David W. Ball
Publisher: Cengage Learning US
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Chapter 8, Problem 8.28E
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3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Part I.
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff:
Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
and
(3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism
the formation of the products
For
Show the mechanism for these reactions
Chapter 8 Solutions
Student Solutions Manual for Ball's Physical Chemistry, 2nd
Ch. 8 - 8.1. What is the charge on a small sphere that is...Ch. 8 - 8.2. The force of attraction due to gravity...Ch. 8 - 8.3. Two small metallic bodies are given opposite...Ch. 8 - Prob. 8.4ECh. 8 - What is the force of attraction between a...Ch. 8 - Prob. 8.6ECh. 8 - 8.7. How much work is required to move a single...Ch. 8 - 8.8. Explain why an electromotive force is not, in...Ch. 8 - Prob. 8.9ECh. 8 - For each of the following reactions, determine the...
Ch. 8 - Prob. 8.11ECh. 8 - Prob. 8.12ECh. 8 - 8.13. Is the disproportionation reaction...Ch. 8 - Prob. 8.14ECh. 8 - Prob. 8.15ECh. 8 - Prob. 8.16ECh. 8 - Prob. 8.17ECh. 8 - 8.18. Determine and for each of the following...Ch. 8 - Prob. 8.19ECh. 8 - Prob. 8.20ECh. 8 - Prob. 8.21ECh. 8 - Prob. 8.22ECh. 8 - Prob. 8.23ECh. 8 - Prob. 8.24ECh. 8 - Prob. 8.25ECh. 8 - Prob. 8.26ECh. 8 - Prob. 8.27ECh. 8 - What is the Zn2+:Cu2+ ratio on a Daniell cell that...Ch. 8 - Prob. 8.29ECh. 8 - Determine the voltage of this reaction with the...Ch. 8 - The thermite reaction can act as the basis of an...Ch. 8 - A concentration cell has different concentrations...Ch. 8 - Prob. 8.34ECh. 8 - Prob. 8.35ECh. 8 - a What is the equilibrium constant for the...Ch. 8 - Prob. 8.37ECh. 8 - Prob. 8.38ECh. 8 - Prob. 8.39ECh. 8 - Prob. 8.40ECh. 8 - Prob. 8.41ECh. 8 - Consider the following formation reaction for HI:...Ch. 8 - Prob. 8.43ECh. 8 - 8.44. Determine an expression for , the change in...Ch. 8 - Prob. 8.45ECh. 8 - Prob. 8.46ECh. 8 - Determine the equilibrium constant for the...Ch. 8 - Prob. 8.48ECh. 8 - Prob. 8.49ECh. 8 - What is the solubility product constant of Hg2Cl2,...Ch. 8 - Prob. 8.51ECh. 8 - Prob. 8.52ECh. 8 - Prob. 8.53ECh. 8 - Prob. 8.54ECh. 8 - Prob. 8.55ECh. 8 - Prob. 8.56ECh. 8 - Prob. 8.57ECh. 8 - Show that a can be written as n+mnn+n+nn, where m...Ch. 8 - Prob. 8.59ECh. 8 - Prob. 8.60ECh. 8 - What molality of NaCl is necessary to have the...Ch. 8 - Prob. 8.62ECh. 8 - Prob. 8.63ECh. 8 - Calculate the molar enthalpy of formation of I(aq)...Ch. 8 - Prob. 8.65ECh. 8 - Hydrofluoric acid, HF(aq), is a weak acid that is...Ch. 8 - Prob. 8.68ECh. 8 - Prob. 8.69ECh. 8 - Prob. 8.70ECh. 8 - Prob. 8.71ECh. 8 - Prob. 8.72ECh. 8 - The mean activity coefficient for an aqueous...Ch. 8 - Human blood plasma is approximately 0.9NaCl. What...Ch. 8 - Under what conditions does the extended...Ch. 8 - Prob. 8.76ECh. 8 - Approximate the expected voltage for the following...Ch. 8 - Prob. 8.78ECh. 8 - Prob. 8.79ECh. 8 - Prob. 8.80ECh. 8 - a The salt NaNO3 can be thought of as...Ch. 8 - Prob. 8.82ECh. 8 - What is the estimated velocity for Cu2+ ions...Ch. 8 - Prob. 8.84ECh. 8 - Prob. 8.85ECh. 8 - Prob. 8.86ECh. 8 - Calculate a the solubility product constant for...
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- Draw the stepwise mechanismarrow_forwardDraw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forward
- Draw stepwise mechanismarrow_forwardPart I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forward
- What are the IUPAC Names of all the compounds in the picture?arrow_forward1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forward
- Li+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forwardQ4: Write organic product(s) of the following reactions and show the curved-arrow mechanism of the reactions. Br MeOH OSO2CH3 MeOHarrow_forwardProvide the correct IUPAC name for the compound shown here. Reset cis- 5- trans- ☑ 4-6- 2- 1- 3- di iso tert- tri cyclo sec- oct but hept prop hex pent yl yne ene anearrow_forward
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