Structural formua of the product formed when each alkene is treated with one equivalent of NBS in C H 2 C l 2 in presence of light has to be drawn. Concept introduction: Bromine does not act as good source for free radical bromination on allylic C-H bonds since it will simply add to the alkene. • NBS: N-bromosuccinimide: using NBS with low concentration of Bromine molecule, that catalyzed by HBr leads to th eproduct. • Allylic susbstitution using NBS involves a net double substitution i.e, B r in NBs is exchanged by the hydrogen in alkene.

Question

The fire releases 2.80 x 107 Joules of heat energy for each liter of oil burned. The water starts out at 24.5 °C, raising the water's temperature up to 100 °C, and then raises the temperature of the resulting steam up to 325 °C. How many liters of water will be needed to absorb the heat from the fire in this way, for each 1.0 liter of crude oil burned? 4186 J/(kg°C) = heat of water 2020 J/(kg°C) = heat of steam 2,256,000 (i.e. 2.256 x 106) J/kg = latent heat of vaporization for water (at the boiling point of 100 °C).

Answer 1

Question

Chapter 8, Problem 8.26P

(a)

Interpretation Introduction

Interpretation:

Structural formua of the product formed when each alkene is treated with one equivalent of NBS in CH2Cl2 in presence of light has to be drawn.

Concept introduction:

Bromine does not act as good source for free radical bromination on allylic C-H bonds since it will simply add to the alkene.

• NBS: N-bromosuccinimide: using NBS with low concentration of Bromine molecule, that catalyzed by HBr leads to th eproduct.

• Allylic susbstitution using NBS involves a net double substitution i.e, Br in NBs is exchanged by the hydrogen in alkene.

(b)

Interpretation Introduction

Interpretation:

Structural formua of the product formed when each alkene is treated with one equivalent of NBS in CH2Cl2 in presence of light has to be drawn.

Concept introduction:

Bromine does not act as good source for free radical bromination on allylic C-H bonds since it will simply add to the alkene.

• NBS: N-bromosuccinimide: using NBS with low concentration of Bromine molecule, that catalyzed by HBr leads to th eproduct.

• Allylic susbstitution using NBS involves a net double substitution i.e, Br in NBs is exchanged by the hydrogen in alkene.

(c)

Interpretation Introduction

Interpretation:

Structural formua of the product formed when each alkene is treated with one equivalent of NBS in CH2Cl2 in presence of light has to be drawn.

Concept introduction:

Bromine does not act as good source for free radical bromination on allylic C-H bonds since it will simply add to the alkene.

• NBS: N-bromosuccinimide: using NBS with low concentration of Bromine molecule, that catalyzed by HBr leads to th eproduct.

• Allylic susbstitution using NBS involves a net double substitution i.e, Br in NBs is exchanged by the hydrogen in alkene.

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