The full set of possible quantum numbers for the outermost electron in Rb atom is to be determined. Concept introduction: The electrons in the outermost occupied shell that determine the chemical properties of the elements are called the outermost electrons. The quantum numbers provide complete information about the electron. There are four quantum numbers as follows: 1. The principal quantum number and it is represented by n. It tells about the shell to which the electron belongs. 2. The azimuthal quantum number and it is represented by l. It tells about the subshell of the electrons. 3. The magnetic quantum number and it is represented by m l . It tells about the orbitals present in the subshell. The value of m l ranges from l to − l including 0. 4. The spin quantum number and it is represented by m s . It tells about the spin of the electron and its value can either be + 1 2 or − 1 2 .

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Answer 1

Question

Chapter 8, Problem 8.21P

(a)

Interpretation Introduction

Interpretation:

The full set of possible quantum numbers for the outermost electron in Rb atom is to be determined.

Concept introduction:

The electrons in the outermost occupied shell that determine the chemical properties of the elements are called the outermost electrons.

The quantum numbers provide complete information about the electron. There are four quantum numbers as follows:

1. The principal quantum number and it is represented by n. It tells about the shell to which the electron belongs.

2. The azimuthal quantum number and it is represented by l. It tells about the subshell of the electrons.

3. The magnetic quantum number and it is represented by ml. It tells about the orbitals present in the subshell. The value of ml ranges from l to −l including 0.

4. The spin quantum number and it is represented by ms. It tells about the spin of the electron and its value can either be +12 or −12.

(b)

Interpretation Introduction

Interpretation:

The full set of possible quantum numbers for the electron gained when an S− ion becomes an S2− ion is to be determined.

Concept introduction:

The quantum numbers provide complete information about the electron. There are four quantum numbers as follows:

1. The principal quantum number and it is represented by n. It tells about the shell to which the electron belongs.

2. The azimuthal quantum number and it is represented by l. It tells about the subshell of the electrons.

3. The magnetic quantum number and it is represented by ml. It tells about the orbitals present in the subshell. The value of ml ranges from l to −l including 0.

4. The spin quantum number and it is represented by ms. It tells about the spin of the electron and its value can either be +12 or −12.

(c)

Interpretation Introduction

Interpretation:

The full set of possible quantum numbers for the electron lost when an Ag atom ionizes is to be determined.

Concept introduction:

The quantum numbers provide complete information about the electron. There are four quantum numbers as follows:

1. The principal quantum number and it is represented by n. It tells about the shell to which the electron belongs.

2. The azimuthal quantum number and it is represented by l. It tells about the subshell of the electrons.

3. The magnetic quantum number and it is represented by ml. It tells about the orbitals present in the subshell. The value of ml ranges from l to −l including 0.

4. The spin quantum number and it is represented by ms. It tells about the spin of the electron and its value can either be +12 or −12.

(d)

Interpretation Introduction

Interpretation:

The full set of possible quantum numbers for the electron gained when an F− ion is formed from F atom is to be determined.

Concept introduction:

The quantum numbers provide complete information about the electron. There are four quantum numbers as follows:

1. The principal quantum number and it is represented by n. It tells about the shell to which the electron belongs.

2. The azimuthal quantum number and it is represented by l. It tells about the subshell of the electrons.

3. The magnetic quantum number and it is represented by ml. It tells about the orbitals present in the subshell. The value of ml ranges from l to −l including 0.

4. The spin quantum number and it is represented by ms. It tells about the spin of the electron and its value can either be +12 or −12.

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2. Write a complete mechanism for the reaction shown below. NaOCH LOCH₁ O₂N NO2 CH₂OH, 20 °C O₂N NO2

4. Propose a synthesis of the target molecules from the respective starting materials. a) b) LUCH C Br OH

The following mechanism for the gas phase reaction of H2 and ICI that is consistent with the observed rate law is: step 1 step 2 slow: H2(g) +ICI(g) → HCl(g) + HI(g) fast: ICI(g) + HI(g) → HCl(g) + |2(g) (1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not needed, leave it blank. + → + (2) Which species acts as a catalyst? Enter formula. If none, leave box blank: (3) Which species acts as a reaction intermediate? Enter formula. If none, leave box blank: (4) Complete the rate law for the overall reaction that is consistent with this mechanism. (Use the form k[A][B]"..., where '1' is understood (so don't write it) for m, n etc.) Rate =

Answer 2

Question

Chapter 8, Problem 8.21P

(a)

Interpretation Introduction

Interpretation:

The full set of possible quantum numbers for the outermost electron in Rb atom is to be determined.

Concept introduction:

The electrons in the outermost occupied shell that determine the chemical properties of the elements are called the outermost electrons.

The quantum numbers provide complete information about the electron. There are four quantum numbers as follows:

1. The principal quantum number and it is represented by n. It tells about the shell to which the electron belongs.

2. The azimuthal quantum number and it is represented by l. It tells about the subshell of the electrons.

3. The magnetic quantum number and it is represented by ml. It tells about the orbitals present in the subshell. The value of ml ranges from l to −l including 0.

4. The spin quantum number and it is represented by ms. It tells about the spin of the electron and its value can either be +12 or −12.

(b)

Interpretation Introduction

Interpretation:

The full set of possible quantum numbers for the electron gained when an S− ion becomes an S2− ion is to be determined.

Concept introduction:

The quantum numbers provide complete information about the electron. There are four quantum numbers as follows:

1. The principal quantum number and it is represented by n. It tells about the shell to which the electron belongs.

2. The azimuthal quantum number and it is represented by l. It tells about the subshell of the electrons.

3. The magnetic quantum number and it is represented by ml. It tells about the orbitals present in the subshell. The value of ml ranges from l to −l including 0.

4. The spin quantum number and it is represented by ms. It tells about the spin of the electron and its value can either be +12 or −12.

(c)

Interpretation Introduction

Interpretation:

The full set of possible quantum numbers for the electron lost when an Ag atom ionizes is to be determined.

Concept introduction:

The quantum numbers provide complete information about the electron. There are four quantum numbers as follows:

1. The principal quantum number and it is represented by n. It tells about the shell to which the electron belongs.

2. The azimuthal quantum number and it is represented by l. It tells about the subshell of the electrons.

3. The magnetic quantum number and it is represented by ml. It tells about the orbitals present in the subshell. The value of ml ranges from l to −l including 0.

4. The spin quantum number and it is represented by ms. It tells about the spin of the electron and its value can either be +12 or −12.

(d)

Interpretation Introduction

Interpretation:

The full set of possible quantum numbers for the electron gained when an F− ion is formed from F atom is to be determined.

Concept introduction:

The quantum numbers provide complete information about the electron. There are four quantum numbers as follows:

1. The principal quantum number and it is represented by n. It tells about the shell to which the electron belongs.

2. The azimuthal quantum number and it is represented by l. It tells about the subshell of the electrons.

3. The magnetic quantum number and it is represented by ml. It tells about the orbitals present in the subshell. The value of ml ranges from l to −l including 0.

4. The spin quantum number and it is represented by ms. It tells about the spin of the electron and its value can either be +12 or −12.

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Answer 3

Question

Chapter 8, Problem 8.21P

(a)

Interpretation Introduction

Interpretation:

The full set of possible quantum numbers for the outermost electron in Rb atom is to be determined.

Concept introduction:

The electrons in the outermost occupied shell that determine the chemical properties of the elements are called the outermost electrons.

The quantum numbers provide complete information about the electron. There are four quantum numbers as follows:

1. The principal quantum number and it is represented by n. It tells about the shell to which the electron belongs.

2. The azimuthal quantum number and it is represented by l. It tells about the subshell of the electrons.

3. The magnetic quantum number and it is represented by ml. It tells about the orbitals present in the subshell. The value of ml ranges from l to −l including 0.

4. The spin quantum number and it is represented by ms. It tells about the spin of the electron and its value can either be +12 or −12.

(b)

Interpretation Introduction

Interpretation:

The full set of possible quantum numbers for the electron gained when an S− ion becomes an S2− ion is to be determined.

Concept introduction:

The quantum numbers provide complete information about the electron. There are four quantum numbers as follows:

1. The principal quantum number and it is represented by n. It tells about the shell to which the electron belongs.

2. The azimuthal quantum number and it is represented by l. It tells about the subshell of the electrons.

3. The magnetic quantum number and it is represented by ml. It tells about the orbitals present in the subshell. The value of ml ranges from l to −l including 0.

4. The spin quantum number and it is represented by ms. It tells about the spin of the electron and its value can either be +12 or −12.

(c)

Interpretation Introduction

Interpretation:

The full set of possible quantum numbers for the electron lost when an Ag atom ionizes is to be determined.

Concept introduction:

The quantum numbers provide complete information about the electron. There are four quantum numbers as follows:

1. The principal quantum number and it is represented by n. It tells about the shell to which the electron belongs.

2. The azimuthal quantum number and it is represented by l. It tells about the subshell of the electrons.

3. The magnetic quantum number and it is represented by ml. It tells about the orbitals present in the subshell. The value of ml ranges from l to −l including 0.

4. The spin quantum number and it is represented by ms. It tells about the spin of the electron and its value can either be +12 or −12.

(d)

Interpretation Introduction

Interpretation:

The full set of possible quantum numbers for the electron gained when an F− ion is formed from F atom is to be determined.

Concept introduction:

The quantum numbers provide complete information about the electron. There are four quantum numbers as follows:

1. The principal quantum number and it is represented by n. It tells about the shell to which the electron belongs.

2. The azimuthal quantum number and it is represented by l. It tells about the subshell of the electrons.

3. The magnetic quantum number and it is represented by ml. It tells about the orbitals present in the subshell. The value of ml ranges from l to −l including 0.

4. The spin quantum number and it is represented by ms. It tells about the spin of the electron and its value can either be +12 or −12.

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Answer 4

Question

Chapter 8, Problem 8.21P

(a)

Interpretation Introduction

Interpretation:

The full set of possible quantum numbers for the outermost electron in Rb atom is to be determined.

Concept introduction:

The electrons in the outermost occupied shell that determine the chemical properties of the elements are called the outermost electrons.

The quantum numbers provide complete information about the electron. There are four quantum numbers as follows:

1. The principal quantum number and it is represented by n. It tells about the shell to which the electron belongs.

2. The azimuthal quantum number and it is represented by l. It tells about the subshell of the electrons.

3. The magnetic quantum number and it is represented by ml. It tells about the orbitals present in the subshell. The value of ml ranges from l to −l including 0.

4. The spin quantum number and it is represented by ms. It tells about the spin of the electron and its value can either be +12 or −12.

(b)

Interpretation Introduction

Interpretation:

The full set of possible quantum numbers for the electron gained when an S− ion becomes an S2− ion is to be determined.

Concept introduction:

The quantum numbers provide complete information about the electron. There are four quantum numbers as follows:

1. The principal quantum number and it is represented by n. It tells about the shell to which the electron belongs.

2. The azimuthal quantum number and it is represented by l. It tells about the subshell of the electrons.

3. The magnetic quantum number and it is represented by ml. It tells about the orbitals present in the subshell. The value of ml ranges from l to −l including 0.

4. The spin quantum number and it is represented by ms. It tells about the spin of the electron and its value can either be +12 or −12.

(c)

Interpretation Introduction

Interpretation:

The full set of possible quantum numbers for the electron lost when an Ag atom ionizes is to be determined.

Concept introduction:

The quantum numbers provide complete information about the electron. There are four quantum numbers as follows:

1. The principal quantum number and it is represented by n. It tells about the shell to which the electron belongs.

2. The azimuthal quantum number and it is represented by l. It tells about the subshell of the electrons.

3. The magnetic quantum number and it is represented by ml. It tells about the orbitals present in the subshell. The value of ml ranges from l to −l including 0.

4. The spin quantum number and it is represented by ms. It tells about the spin of the electron and its value can either be +12 or −12.

(d)

Interpretation Introduction

Interpretation:

The full set of possible quantum numbers for the electron gained when an F− ion is formed from F atom is to be determined.

Concept introduction:

The quantum numbers provide complete information about the electron. There are four quantum numbers as follows:

1. The principal quantum number and it is represented by n. It tells about the shell to which the electron belongs.

2. The azimuthal quantum number and it is represented by l. It tells about the subshell of the electrons.

3. The magnetic quantum number and it is represented by ml. It tells about the orbitals present in the subshell. The value of ml ranges from l to −l including 0.

4. The spin quantum number and it is represented by ms. It tells about the spin of the electron and its value can either be +12 or −12.

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Answer 5

Chapter 8, Problem 8.21P

(a)

Interpretation Introduction

Interpretation:

The full set of possible quantum numbers for the outermost electron in Rb atom is to be determined.

Concept introduction:

The electrons in the outermost occupied shell that determine the chemical properties of the elements are called the outermost electrons.

The quantum numbers provide complete information about the electron. There are four quantum numbers as follows:

1. The principal quantum number and it is represented by n. It tells about the shell to which the electron belongs.

2. The azimuthal quantum number and it is represented by l. It tells about the subshell of the electrons.

3. The magnetic quantum number and it is represented by ml. It tells about the orbitals present in the subshell. The value of ml ranges from l to −l including 0.

4. The spin quantum number and it is represented by ms. It tells about the spin of the electron and its value can either be +12 or −12.

(b)

Interpretation Introduction

Interpretation:

The full set of possible quantum numbers for the electron gained when an S− ion becomes an S2− ion is to be determined.

Concept introduction:

The quantum numbers provide complete information about the electron. There are four quantum numbers as follows:

1. The principal quantum number and it is represented by n. It tells about the shell to which the electron belongs.

2. The azimuthal quantum number and it is represented by l. It tells about the subshell of the electrons.

3. The magnetic quantum number and it is represented by ml. It tells about the orbitals present in the subshell. The value of ml ranges from l to −l including 0.

4. The spin quantum number and it is represented by ms. It tells about the spin of the electron and its value can either be +12 or −12.

(c)

Interpretation Introduction

Interpretation:

The full set of possible quantum numbers for the electron lost when an Ag atom ionizes is to be determined.

Concept introduction:

The quantum numbers provide complete information about the electron. There are four quantum numbers as follows:

1. The principal quantum number and it is represented by n. It tells about the shell to which the electron belongs.

2. The azimuthal quantum number and it is represented by l. It tells about the subshell of the electrons.

3. The magnetic quantum number and it is represented by ml. It tells about the orbitals present in the subshell. The value of ml ranges from l to −l including 0.

4. The spin quantum number and it is represented by ms. It tells about the spin of the electron and its value can either be +12 or −12.

(d)

Interpretation Introduction

Interpretation:

The full set of possible quantum numbers for the electron gained when an F− ion is formed from F atom is to be determined.

Concept introduction:

The quantum numbers provide complete information about the electron. There are four quantum numbers as follows:

1. The principal quantum number and it is represented by n. It tells about the shell to which the electron belongs.

2. The azimuthal quantum number and it is represented by l. It tells about the subshell of the electrons.

3. The magnetic quantum number and it is represented by ml. It tells about the orbitals present in the subshell. The value of ml ranges from l to −l including 0.

4. The spin quantum number and it is represented by ms. It tells about the spin of the electron and its value can either be +12 or −12.

Answer 6

Chapter 8, Problem 8.21P

(a)

Interpretation Introduction

Interpretation:

The full set of possible quantum numbers for the outermost electron in Rb atom is to be determined.

Concept introduction:

The electrons in the outermost occupied shell that determine the chemical properties of the elements are called the outermost electrons.

The quantum numbers provide complete information about the electron. There are four quantum numbers as follows:

1. The principal quantum number and it is represented by n. It tells about the shell to which the electron belongs.

2. The azimuthal quantum number and it is represented by l. It tells about the subshell of the electrons.

3. The magnetic quantum number and it is represented by ml. It tells about the orbitals present in the subshell. The value of ml ranges from l to −l including 0.

4. The spin quantum number and it is represented by ms. It tells about the spin of the electron and its value can either be +12 or −12.

Answer 7

Chapter 8, Problem 8.21P

(a)

Interpretation Introduction

Interpretation:

The full set of possible quantum numbers for the outermost electron in Rb atom is to be determined.

Concept introduction:

The electrons in the outermost occupied shell that determine the chemical properties of the elements are called the outermost electrons.

The quantum numbers provide complete information about the electron. There are four quantum numbers as follows:

1. The principal quantum number and it is represented by n. It tells about the shell to which the electron belongs.

2. The azimuthal quantum number and it is represented by l. It tells about the subshell of the electrons.

3. The magnetic quantum number and it is represented by ml. It tells about the orbitals present in the subshell. The value of ml ranges from l to −l including 0.

4. The spin quantum number and it is represented by ms. It tells about the spin of the electron and its value can either be +12 or −12.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The full set of possible quantum numbers for the electron gained when an S− ion becomes an S2− ion is to be determined.

Concept introduction:

The quantum numbers provide complete information about the electron. There are four quantum numbers as follows:

1. The principal quantum number and it is represented by n. It tells about the shell to which the electron belongs.

2. The azimuthal quantum number and it is represented by l. It tells about the subshell of the electrons.

3. The magnetic quantum number and it is represented by ml. It tells about the orbitals present in the subshell. The value of ml ranges from l to −l including 0.

4. The spin quantum number and it is represented by ms. It tells about the spin of the electron and its value can either be +12 or −12.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The full set of possible quantum numbers for the electron gained when an S− ion becomes an S2− ion is to be determined.

Concept introduction:

The quantum numbers provide complete information about the electron. There are four quantum numbers as follows:

1. The principal quantum number and it is represented by n. It tells about the shell to which the electron belongs.

2. The azimuthal quantum number and it is represented by l. It tells about the subshell of the electrons.

3. The magnetic quantum number and it is represented by ml. It tells about the orbitals present in the subshell. The value of ml ranges from l to −l including 0.

4. The spin quantum number and it is represented by ms. It tells about the spin of the electron and its value can either be +12 or −12.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The full set of possible quantum numbers for the electron lost when an Ag atom ionizes is to be determined.

Concept introduction:

The quantum numbers provide complete information about the electron. There are four quantum numbers as follows:

1. The principal quantum number and it is represented by n. It tells about the shell to which the electron belongs.

2. The azimuthal quantum number and it is represented by l. It tells about the subshell of the electrons.

3. The magnetic quantum number and it is represented by ml. It tells about the orbitals present in the subshell. The value of ml ranges from l to −l including 0.

4. The spin quantum number and it is represented by ms. It tells about the spin of the electron and its value can either be +12 or −12.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The full set of possible quantum numbers for the electron lost when an Ag atom ionizes is to be determined.

Concept introduction:

The quantum numbers provide complete information about the electron. There are four quantum numbers as follows:

1. The principal quantum number and it is represented by n. It tells about the shell to which the electron belongs.

2. The azimuthal quantum number and it is represented by l. It tells about the subshell of the electrons.

3. The magnetic quantum number and it is represented by ml. It tells about the orbitals present in the subshell. The value of ml ranges from l to −l including 0.

4. The spin quantum number and it is represented by ms. It tells about the spin of the electron and its value can either be +12 or −12.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The full set of possible quantum numbers for the electron gained when an F− ion is formed from F atom is to be determined.

Concept introduction:

The quantum numbers provide complete information about the electron. There are four quantum numbers as follows:

1. The principal quantum number and it is represented by n. It tells about the shell to which the electron belongs.

2. The azimuthal quantum number and it is represented by l. It tells about the subshell of the electrons.

3. The magnetic quantum number and it is represented by ml. It tells about the orbitals present in the subshell. The value of ml ranges from l to −l including 0.

4. The spin quantum number and it is represented by ms. It tells about the spin of the electron and its value can either be +12 or −12.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The full set of possible quantum numbers for the electron gained when an F− ion is formed from F atom is to be determined.

Concept introduction:

The quantum numbers provide complete information about the electron. There are four quantum numbers as follows:

1. The principal quantum number and it is represented by n. It tells about the shell to which the electron belongs.

2. The azimuthal quantum number and it is represented by l. It tells about the subshell of the electrons.

3. The magnetic quantum number and it is represented by ml. It tells about the orbitals present in the subshell. The value of ml ranges from l to −l including 0.

4. The spin quantum number and it is represented by ms. It tells about the spin of the electron and its value can either be +12 or −12.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 8.2 - Prob. 8.1AFP Ch. 8.2 - Prob. 8.1BFP Ch. 8.3 - Prob. 8.2AFP Ch. 8.3 - Prob. 8.2BFP Ch. 8.3 - Prob. 8.3AFP Ch. 8.3 - Prob. 8.3BFP Ch. 8.3 - Prob. 8.4AFP Ch. 8.3 - Prob. 8.4BFP Ch. 8.4 - Prob. 8.5AFP Ch. 8.4 - Prob. 8.5BFP

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