BNDL: ACP ORGANIC CHEMISTRY:CH EM 231(W/ACCESS CARD)
BNDL: ACP ORGANIC CHEMISTRY:CH EM 231(W/ACCESS CARD)
8th Edition
ISBN: 9781337687539
Author: Brown/Iverson/Anslyn/ Foote
Publisher: CENGAGE C
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Chapter 8, Problem 8.11P
Interpretation Introduction

Interpretation:

Reason for molecular weight of perfluromethylcyclohexane is three times that of methylcyclohexane, but its boiling point is lower than that of methylcyclohexane has to be identified.

Concept introduction:

Density of haloalkanes is more as halogens have larger mass-to-volume.

The carbon-halogen bond of alkyl halide is polarised.

Dipole moment increases, as the electronegativity of halogen and bond length increases.

Haloalkanes in liquid state has a combination of attractive forces, termed as van der Waals forces.

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Question 4 For the molecule shown below, (7 marks): A) Sketch the Newman projection for the view looking along the bond from the perspective of the arrow. B) Then, draw the Newman projection for each 60° rotation along the bond until it returns to the starting point. C) Clearly indicate which Newman projection is the one we see in the structure shown below, and clearly indicate which Newman projection is the highest in energy and which is the lowest in energy. H H Me 'H Me Me
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