EBK CHEMISTRY FOR ENGINEERING STUDENTS,
4th Edition
ISBN: 9781337671439
Author: Holme
Publisher: CENGAGE LEARNING - CONSIGNMENT
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Question
Chapter 8, Problem 8.10PAE
Interpretation Introduction
Interpretation:
The lower coordination number for a cubic structure relative to a hexagonal structure should be explained.
Concept introduction:
- The atoms (molecules or ions) that constitute the solid can be arranged appropriately such that most of the space in the crystal is utilized.
- Greater the space occupied, greater is the packing efficiency
- The number of nearest neighbors surrounding a particular atom (molecule or ion) is called as coordination number.
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Students have asked these similar questions
Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 8 Solutions
EBK CHEMISTRY FOR ENGINEERING STUDENTS,
Ch. 8 - Prob. 1COCh. 8 - • describe the arrangement of atoms in the common...Ch. 8 - • use bind theory to describe bonding in solids.Ch. 8 - Prob. 4COCh. 8 - Prob. 5COCh. 8 - Prob. 6COCh. 8 - Prob. 7COCh. 8 - • explain the connection between intermolecular...Ch. 8 - Prob. 9COCh. 8 - Prob. 10CO
Ch. 8 - Prob. 8.1PAECh. 8 - Why is the C 60form of carbon called...Ch. 8 - Prob. 8.3PAECh. 8 - Prob. 8.4PAECh. 8 - What is the relationship between the structures of...Ch. 8 - Use the web to look up information on nanotubes....Ch. 8 - Prob. 8.7PAECh. 8 - Prob. 8.8PAECh. 8 - Prob. 8.9PAECh. 8 - Prob. 8.10PAECh. 8 - Prob. 8.11PAECh. 8 - Prob. 8.12PAECh. 8 - 8.13 What is the coordination number of atoms in...Ch. 8 - Prob. 8.14PAECh. 8 - Prob. 8.15PAECh. 8 - 8.16 Iridium forms a face-centered cubic lattice,...Ch. 8 - 8.17 Europium forms a body-centered cubic unit...Ch. 8 - 8.18 Manganese has a body-centered cubic unit cell...Ch. 8 - Prob. 8.19PAECh. 8 - 8.20 How many electrons per atom are delocalized...Ch. 8 - Prob. 8.21PAECh. 8 - Prob. 8.22PAECh. 8 - Prob. 8.23PAECh. 8 - 8.24 What is the key difference between metallic...Ch. 8 - 8.25 Draw a depiction of the band structure of a...Ch. 8 - Prob. 8.26PAECh. 8 - Prob. 8.27PAECh. 8 - Prob. 8.28PAECh. 8 - Prob. 8.29PAECh. 8 - Prob. 8.30PAECh. 8 - Prob. 8.31PAECh. 8 - Prob. 8.32PAECh. 8 - Prob. 8.33PAECh. 8 - Suppose that a device is using a 15.0-mg sample of...Ch. 8 - 8.35 What is an instantancous dipole?Ch. 8 - 8.36 Why are dispersion forces attractive?Ch. 8 - 8.37 If a molecule is not very polarizable, how...Ch. 8 - 8.38 What is the relationship between...Ch. 8 - 8.39 Under what circumstances are ion-dipole...Ch. 8 - 8.40 Which of the following compounds would be...Ch. 8 - 8.41 What is the specific feature of N, O, and F...Ch. 8 - Prob. 8.42PAECh. 8 - 8.43 Identify the kinds of intermolecular forces...Ch. 8 - Prob. 8.44PAECh. 8 - 8.45 Describe how interactions between molecules...Ch. 8 - 8.46 What makes a chemical compound volatile?Ch. 8 - 8.47 Answer each of the following questions with...Ch. 8 - 8.48 Why must the vapor pressure of a substance be...Ch. 8 - Prob. 8.49PAECh. 8 - Prob. 8.50PAECh. 8 - 8.51 Suppose that three unknown pure substances...Ch. 8 - 8.52 Rank the following hydrocarbons in order of...Ch. 8 - Prob. 8.53PAECh. 8 - Prob. 8.54PAECh. 8 - Prob. 8.55PAECh. 8 - Prob. 8.56PAECh. 8 - Prob. 8.57PAECh. 8 - Prob. 8.58PAECh. 8 - Prob. 8.59PAECh. 8 - Prob. 8.60PAECh. 8 - 8.61 Distinguish between a block copolymer and a...Ch. 8 - Prob. 8.62PAECh. 8 - Prob. 8.63PAECh. 8 - Prob. 8.64PAECh. 8 - Prob. 8.65PAECh. 8 - 8.66 What structural characteristics are needed...Ch. 8 - Prob. 8.67PAECh. 8 - Prob. 8.68PAECh. 8 - Prob. 8.69PAECh. 8 - Prob. 8.70PAECh. 8 - Prob. 8.71PAECh. 8 - Prob. 8.72PAECh. 8 - Prob. 8.73PAECh. 8 - Prob. 8.74PAECh. 8 - 8.75 Using pentagons, draw arrangements that...Ch. 8 - 8.76 Using circles, draw regular two-dimensional...Ch. 8 - 8.77 What is the difference between a bonding...Ch. 8 - Prob. 8.78PAECh. 8 - 8.79 Most gaseous compounds consist of small...Ch. 8 - 8.80 Why are dipole—dipole forces typically...Ch. 8 - 8.81 Carbon tetrachloride (CCl4) is a liquid at...Ch. 8 - Prob. 8.82PAECh. 8 - Prob. 8.83PAECh. 8 - Prob. 8.84PAECh. 8 - Prob. 8.85PAECh. 8 - Prob. 8.86PAECh. 8 - 8.87 Use the vapor pressure curves illustrated...Ch. 8 - Prob. 8.88PAECh. 8 - 8.89 The following data show the vapor pressure of...Ch. 8 - Prob. 8.90PAECh. 8 - Prob. 8.91PAECh. 8 - Prob. 8.92PAECh. 8 - Prob. 8.93PAECh. 8 - Prob. 8.94PAECh. 8 - Prob. 8.95PAECh. 8 - 8.96 A business manager wants to provide a wider...Ch. 8 - 8.97 The doping of semiconductors can be done with...Ch. 8 - 8.98 If you know the density of material and the...Ch. 8 - Prob. 8.99PAECh. 8 - Prob. 8.100PAECh. 8 - Prob. 8.101PAECh. 8 - Prob. 8.102PAECh. 8 - 8.103 Cryolite (Na3AlF6) is used in refining...Ch. 8 - Prob. 8.104PAECh. 8 - Prob. 8.105PAE
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