(a) Interpretation: The bond order of O 2 should be predicted. Concept introduction: Molecular orbital theory is a method that shows that how atomic orbitals combine with other or with each other to form bonding and antibonding orbitals. It is used to determine the molecular structure of a molecule.
(a) Interpretation: The bond order of O 2 should be predicted. Concept introduction: Molecular orbital theory is a method that shows that how atomic orbitals combine with other or with each other to form bonding and antibonding orbitals. It is used to determine the molecular structure of a molecule.
Solution Summary: The author explains Molecular Orbital Theory, a method that shows how atomic orbitals combine with other or with each other to form bonding and antibonding orbital.
Molecular orbital theory is a method that shows that how atomic orbitals combine with other or with each other to form bonding and antibonding orbitals. It is used to determine the molecular structure of a molecule.
Interpretation Introduction
(b)
Interpretation:
Whether an electron should be added or remove to increase the bond order of O2 should be predicted.
Concept introduction:
Molecular orbital theory is a method that shows that how atomic orbitals combine with other or with each other to form bonding and antibonding orbitals. It is used to determine the molecular structure of a molecule.
Interpretation Introduction
(c)
Interpretation:
The charge and bond order of new species made in part (b) should be predicted.
Concept introduction:
Molecular orbital theory is a method that shows that how atomic orbitals combine with other or with each other to form bonding and antibonding orbitals. It is used to determine the molecular structure of a molecule.
MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10
Consider the following reaction:
CH3OH(g)
CO(g) + 2H2(g)
(Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.)
Part A
Calculate AG for this reaction at 25 °C under the following conditions:
PCH₂OH
Pco
PH2
0.815 atm
=
0.140 atm
0.170 atm
Express your answer in kilojoules to three significant figures.
Ο ΑΣΦ
AG = -150
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kJ
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Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship:
AGrxn = AGrxn + RTInQ,
AGxn+RTInQ,
where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a
is the reaction quotient.
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Quantum Molecular Orbital Theory (PChem Lecture: LCAO and gerade ungerade orbitals); Author: Prof Melko;https://www.youtube.com/watch?v=l59CGEstSGU;License: Standard YouTube License, CC-BY