Chemistry Atoms First2e
Chemistry Atoms First2e
2nd Edition
ISBN: 9781947172647
Author: OpenStax
Publisher: OpenStax College
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Chapter 8, Problem 80E

One method of analyzing amino acids is the van Slyke method. The characteristic amino groups ( NH 2 ) in protein material are allowed to react with nitrous acid. HNO 2 , to form N 2 gas. From the volume of the gas, the amount of amino acid can be determined. A 0.0604-g sample of a biological sample containing glycine, CH 2 ( NH 2 ) COOH , was analyzed by the van Slyke method and yielded 3.70 mL of N 2 collected over water at a pressure of 735 torr and 29 °C. What was the percentage of glycine in the sample?

CH 2 ( NH 2 ) CO 2 H + HNO 2 CH 2 ( OH ) CO 2 H + H 2 O + N 2

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Chapter 8 Solutions

Chemistry Atoms First2e

Ch. 8 - Consider this scenario and answer the following...Ch. 8 - Why is it necessary to use a nonvolatile liquid in...Ch. 8 - The pressure of a sample of gas is measured at sea...Ch. 8 - The pressure of a sample of gas is measured with...Ch. 8 - The pressure of a sample of gas is measured at sea...Ch. 8 - The pressure of a sample of gas ¡s measured a sea...Ch. 8 - How would the use of a volatile liquid affect the...Ch. 8 - Sometimes leaving a bicycle in the sun on a hot...Ch. 8 - Explain how the volume of the bubbles exhausted by...Ch. 8 - One way to state Boyle’s law is All other things...Ch. 8 - An alternate way to state Avogadro’s law is A1l...Ch. 8 - How would the graph in Figure 8.12 change if the...Ch. 8 - How would the graph in Figure 8.13 change if the...Ch. 8 - In addition to the data found in Figure 8.13, what...Ch. 8 - Determine the volume of 1 mol of CH4 gas at 150 K...Ch. 8 - Determine the pressure of the gas in the syringe...Ch. 8 - A spray can is used until it is empty except for...Ch. 8 - What is the temperature of an 11.2-L sample of...Ch. 8 - À 2.50-L volume of hydrogen measured at —196 C is...Ch. 8 - A balloon inflated with three breaths of air has a...Ch. 8 - A weather balloon contains 8.80 moles of helium at...Ch. 8 - The volume of an automobile air bag was 66.8 L...Ch. 8 - How many moles of gaseous boron trifluoride, BF3,...Ch. 8 - Iodine, I2, is a solid at room temperature but...Ch. 8 - How many grams of gas are present in each of the...Ch. 8 - A high altitude balloon is filled with 1041104 L...Ch. 8 - A cylinder of medical oxygen has a volume of 3S.4...Ch. 8 - A large scuba tank (Figure 8.16) with a volume of...Ch. 8 - A 20.0-L cylinder containing 11.34 kg of butane,...Ch. 8 - While resting, the average 70-kg human male...Ch. 8 - For a given amount of gas showing ideal behavior,...Ch. 8 - A liter of methane gas, CH4, at STP contains more...Ch. 8 - The effect of chlorofluorocarbons (such as CCl2F2)...Ch. 8 - As 1 g of (lie radioactive element radium decays...Ch. 8 - A balloon with a volume of 100.21 L at 21 C and...Ch. 8 - If the temperature of a fixed amount of a gas is...Ch. 8 - If the volume of a fixed amount of a gas is...Ch. 8 - What is the density of laughing gas, dinitrogen...Ch. 8 - Calculate the density of Freon 12, CF2Cl2, at 30.0...Ch. 8 - Which is denser at the same temperature and...Ch. 8 - A cylinder of O2(g) used in breathing by patients...Ch. 8 - What is the molar mass of a gas if 0.0494 g of the...Ch. 8 - What is the molar mass of a gas if 0.281 g of the...Ch. 8 - How could you show experimentally that the...Ch. 8 - The density of a certain gaseous fluoride of...Ch. 8 - Consider this question: What is the molecular...Ch. 8 - A 36.0—L cylinder of a gas used for calibration of...Ch. 8 - A cylinder of a gas mixture used for calibration...Ch. 8 - A sample of gas isolated from unrefined petroleum...Ch. 8 - A mixture of 0.200 g of 1.00 g of and 0.820 g of...Ch. 8 - Most mixtures of hydrogen gas with oxygen gas are...Ch. 8 - A commercial mercury vapor analyzer can detect in...Ch. 8 - A sample of carbon monoxide was collected over...Ch. 8 - In an experiment in a general chemistry...Ch. 8 - Joseph Priestley first prepared pure oxygen by...Ch. 8 - Cavendish prepared hydrogen in 176G by the novel...Ch. 8 - The chlorofluorocarbon CCl2F2 can be recycled into...Ch. 8 - Automobile air bags are inflated with nitrogen...Ch. 8 - Lime, CaO, is produced by heating calcium...Ch. 8 - Before small batteries were available, carbide...Ch. 8 - Calculate the volume of oxygen required to burn...Ch. 8 - What volume of O2 at STP is required to oxidize...Ch. 8 - Consider the following questions: (a) What is the...Ch. 8 - Methanol, CH3OH, is produced industrially by the...Ch. 8 - What volume of oxygen a 423.0 K and a pressure of...Ch. 8 - A 230-L sample of a colorless gas at STP...Ch. 8 - Ethanol, C2H5OH, is produced industrially from...Ch. 8 - One molecule of hemoglobin will combine with four...Ch. 8 - A sample of a compound of xenon and fluorine was...Ch. 8 - One method of analyzing amino acids is the van...Ch. 8 - A balloon filled with helium gas takes 6 hours to...Ch. 8 - Explain why the numbers of molecules are not...Ch. 8 - Starting with the definition of rate of effusion...Ch. 8 - Heavy water, D2O (molar mass = 20.03 g mol-1). can...Ch. 8 - Which of the following gases diffuse more slowly...Ch. 8 - During the discussion of gaseous diffusion for...Ch. 8 - Calculate the relative rate of diffusion of...Ch. 8 - A gas of unknown identity diffuses at a rate of...Ch. 8 - When two cotton plugs. one moistened with ammonia...Ch. 8 - Using the postulates of the kinetic molecular...Ch. 8 - Can the speed of a given molecule in a gas double...Ch. 8 - Describe what happens o the average kinetic energy...Ch. 8 - The distribution of molecular velocities in a...Ch. 8 - What is the ratio of the average kinetic energy of...Ch. 8 - A 1-L sample of CO initially at STP is heated to...Ch. 8 - The root mean square speed of H2, molecules at 25...Ch. 8 - Answer the following questions: (a) Is the...Ch. 8 - Show that the ratio of the rate of diffusion of...Ch. 8 - Graphs showing the behavior of several different...Ch. 8 - Explain why the plot of PV for CO2 differs from...Ch. 8 - Under which of the following sets of conditions...Ch. 8 - Describe the factors responsible for the deviation...Ch. 8 - For which of the following gases should the...Ch. 8 - A 0.245-L flask contains 0.467 mol CO2 at 159 C....Ch. 8 - Answer the following questions: (a) If XX behaved...
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