PRINCIPLES+REACTIONS
8th Edition
ISBN: 9781337759632
Author: Masterton
Publisher: CENGAGE L
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Chapter 8, Problem 64QAP
The BTU (British thermal unit) is the unit of energy most commonly used in the United States. One
°C.)
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Chapter 8 Solutions
PRINCIPLES+REACTIONS
Ch. 8 - Principles of Heat Flow Titanium is a metal used...Ch. 8 - Prob. 2QAPCh. 8 - Copper is used in building the integrated...Ch. 8 - Mercury was once used in thermometers and...Ch. 8 - The specific heat of aluminum is 0.902J/gC. How...Ch. 8 - Chromium has a specific heat of 0.450J/gC. How...Ch. 8 - Magnesium sulfate is often used in first-aid hot...Ch. 8 - Sodium chloride is added in cooking to enhance the...Ch. 8 - When 375 mL of water (d=1.00g/mL) at 32C are mixed...Ch. 8 - How many mL of water at 10C (2 significant...
Ch. 8 - When one mol of KOH is neutralized by sulfuric...Ch. 8 - The heat of neutralization, Hneut, can be defined...Ch. 8 - Fructose is a sugar commonly found in fruit. A...Ch. 8 - In earlier times, ethyl ether was commonly used as...Ch. 8 - Isooctane is a primary component of gasoline and...Ch. 8 - Ethyl alcohol, C2H5OH, is the intoxicating agent...Ch. 8 - Acetic acid, HC2H3O2, is responsible for the sour...Ch. 8 - Acetylene, C2H2, is used in welding torches. It...Ch. 8 - Salicylic acid, C7H6O3, is one of the starting...Ch. 8 - Methanol (CH3OH) is also known as wood alcohol and...Ch. 8 - Nitrogen oxide (NO) has been found to be a key...Ch. 8 - Small amounts of oxygen gas can be prepared in the...Ch. 8 - In the late eighteenth century Priestley prepared...Ch. 8 - Prob. 24QAPCh. 8 - Strontium metal is responsible for the red color...Ch. 8 - Nitroglycerin, C3H5(NO3)3(l), is an explosive most...Ch. 8 - A typical fat in the body is glyceryl trioleate,...Ch. 8 - Use the same fat described in Question 27. (a)...Ch. 8 - Which requires the absorption of a greater amount...Ch. 8 - Which evolves more heat—freezing 100.0 g of...Ch. 8 - A student is asked to calculate the amount of heat...Ch. 8 - Follow the step-wise process outlined in Problem...Ch. 8 - A lead ore, galena, consisting mainly of lead(II)...Ch. 8 - A reaction used to produce the silicon for...Ch. 8 - Given the following thermochemical equations,...Ch. 8 - Given the following thermochemical equations:...Ch. 8 - Write thermochemical equations for the...Ch. 8 - Write thermochemical equations for the formation...Ch. 8 - Given 2Al2O3(s)4Al(s)+3O2(g)H=3351.4kJ (a) What is...Ch. 8 - Given 2Cr2O3(s)4Cr(s)+3O2(g)H=+2269.4kJ (a) What...Ch. 8 - Limestone, CaCO3, when subjected to a temperature...Ch. 8 - When hydrazine reacts with oxygen, nitrogen gas...Ch. 8 - Use Table 8.3 to obtain AHO for the following...Ch. 8 - Use Table 8.3 to obtain H for the following...Ch. 8 - Use the appropriate tables to calculate H for (a)...Ch. 8 - Use the appropriate tables to calculate H for (a)...Ch. 8 - When one mole of nitroglycerine, C3H5(NO3)3(l)...Ch. 8 - When one mole of calcium carbonate reacts with...Ch. 8 - Chlorine trifluoride is a toxic, intensely...Ch. 8 - When one mole of ethylene gas, C2H4, reacts with...Ch. 8 - Glucose, C6H12O6(s), (H f =1275.2kJ/mol) is...Ch. 8 - When ammonia reacts with dinitrogen oxide gas (H f...Ch. 8 - How many kJ are equal to 3.27 L atm of work?Ch. 8 - How many L atm are equal to 12.2 kJ of work?Ch. 8 - Find (a) E when a gas absorbs 18 J of heat and has...Ch. 8 - Calculate (a) q when a system does 54 J of work...Ch. 8 - Consider the following reaction in a vessel with a...Ch. 8 - Consider the following reaction in the vessel...Ch. 8 - Determine the difference between H and E at 25C...Ch. 8 - For the vaporization of one mole of bromine at...Ch. 8 - Consider the combustion of propane, C3H8, the fuel...Ch. 8 - Consider the combustion of one mole of methyl...Ch. 8 - Butane gas, C4H10, is sold to campers as bottled...Ch. 8 - The BTU (British thermal unit) is the unit of...Ch. 8 - Natural gas companies in the United States use the...Ch. 8 - Prob. 66QAPCh. 8 - Given the following reactions,...Ch. 8 - In World War II, the Germans made use of otherwise...Ch. 8 - Prob. 69QAPCh. 8 - Consider the reaction between methane and oxygen...Ch. 8 - Consider burning ethane gas, C2H6 in oxygen...Ch. 8 - On complete combustion at constant pressure, a...Ch. 8 - Microwave ovens convert radiation to energy. A...Ch. 8 - In 2010, 3.30109 gallons of gasoline were consumed...Ch. 8 - Some solar-heated homes use large beds of rocks to...Ch. 8 - Consider a solution prepared by dissolving 10.00 g...Ch. 8 - Draw a cylinder with a movable piston containing...Ch. 8 - Redraw the cylinder in Question 77 after work has...Ch. 8 - Which statement(s) is/are true about bond...Ch. 8 - Equal masses of liquid A, initially at 100C, and...Ch. 8 - Determine whether the statements given below are...Ch. 8 - An exothermic reaction is carried out in a...Ch. 8 - Determine whether the statements given below are...Ch. 8 - Microwave ovens emit microwave radiation that is...Ch. 8 - On a hot day, you take a six-pack ot a on a pcmc,...Ch. 8 - Prob. 86QAPCh. 8 - The thermite reaction was once used to weld rails:...Ch. 8 - A sample of sucrose, C12H22O11, is contaminated by...Ch. 8 - A wad of steel wool (specific heat=0.45J/gC) at...Ch. 8 - Consider a metal ion A2+ and its nitrate salt, In...
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- A 45-g aluminum spoon (specific heat 0.88 J/g C) at 24 C is placed in 180 mL (180 g) of coffee at 85 C and the temperature of the two become equal. (a) What is the final temperature when the two become equal? Assume that coffee has the same specific heat as water. (b) The first time a student solved this problem she got an answer of 88 C. Explain why this is clearly an incorrect answer.arrow_forwardA rebreathing gas mask contains potassium superoxide, KO2, which reacts with moisture in the breath to give oxygen. 4KO2(s)+2H2O(l)4KOH(s)+3O2(g) Estimate the grams of potassium superoxide required to supply a persons oxygen needs for one hour. Assume a person requires 1.00 102 kcal of energy for this time period. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 1.00 102 kcal of heat, calculate the amount of oxygen consumed and hence the amount of KO2 required. The ff0 for glucose(s) is 1273 kJ/mol.arrow_forwardHow much heat, in joules and in calories, must be added to a 75.0g iron block with a specific heat of 0.449 Jig C to increase its temperature from 25 C to its melting temperature of 1535 C?arrow_forward
- A piece of iron was heated to 95.4C and dropped into a constant-pressure calorimeter containing 284 g of water at 32.2C. The final temperature of the water and iron was 51.9C. Assuming that the calorimeter itself absorbs a negligible amount of heat, what was the mass (in grams) of the piece of iron? The specific heat of iron is 0.449 J/(gC), and the specific heat of water is 4.18 J/(gC).arrow_forwardNatural gas companies in the United States use the therm as a unit of energy. One therm is 1105 BTU. (a) How many joules are in one therm? (1J=9.48104BTU) (b) When propane gas, C3H8, is burned in oxygen, CO2 and steam are produced. How many therms of energy are given off by 1.00 mol of propane gas?arrow_forwardThe temperature of the cooling water as it leaves the hot engine of an automobile is 240 F. After it passes through the radiator it has a temperature of 175 F. Calculate the amount of heat transferred from the engine to the surroundings by one gallon of water with a specific heat of 4.184 J/g oC.arrow_forward
- 1-86 The specific heats of some elements at 25oC are as follows: aluminum = 0.215 cal/g · oC; carbon (graphite) = 0.170 caI/g oC; iron = 0.107 cal/g mercury = 0.033 1 caI/g oC. (a) Which element would require the smallest amount of heat to raise the temperature of 100 g of the element by 10oC? (b) If the same amount of heat needed to raise the temperature of 1 g of aluminum by 25oC were applied to 1 g of mercury, by how many degrees would its temperature be raised? (c) If a certain amount of heat is used to raise the temperature of 1.6 g of iron by 10oC, the temperature of 1 g of which element would also be raised by 10oC, using the same amount of heat?arrow_forwardThe specific heat of copper metal was determined by putting a piece of the metal weighing 35.4 g in hot water. The quantity of heat absorbed by the metal was calculated to be 47.0 J from the temperature drop of the water. What was the specific heat of the metal if the temperature of the metal rose 3.45C?arrow_forwardA piece of chocolate cake contains about 400 calories. A nutritional calorie is equal to 1000 calories (thermochemical calories), which is equal to 4.184 kJ. How many 8-in-high steps must a 180-lb man climb to expend the 400 Cal from the piece of cake? See Exercise 28 for the formula for potential energy.arrow_forward
- The equation for the fermentation of glucose to alcohol and carbon dioxide is: C6H12O6(aq) 2C2H5OH(aq) + 2CO2(g) The enthalpy change for the reaction is 67 kJ. Is this reaction exothermic or endothermic? Is energy, in the form of heat, absorbed or evolved as the reaction occurs?arrow_forwardChlorine dioxide, ClO2, is a reddish yellow gas used in bleaching paper pulp. The average speed of a ClO2 molecule at 25C is 306 m/s. What is the kinetic energy (in joules) of a ClO2 molecule moving at this speed?arrow_forwardDuring a recent winter month in Sheboygan, Wisconsin, it was necessary to obtain 3500 kWh of heat provided by a natural gas furnace with 89% efficiency to keep a small house warm (the efficiency of a gas furnace is the percent of the heat produced by combustion that is transferred into the house). (a) Assume that natural gas is pure methane and determine the volume of natural gas in cubic feet that was required to heat the house. The average temperature of the natural gas was 56 F; at this temperature and a pressure of 1 atm, natural gas has a density of 0.68 1 g/L. (b) How many gallons of LPG (liquefied petroleum gas) would be required to replace the natural gas used? Assume the LPG is liquid propane [ C3H8 : density, 0.5318 g/mL; enthalpy of combustion, 2219 Id/mo for the formation of CO2(g) and H2O(l) ] and the furnace used to burn the LPG has the same efficiency as the gas furnace. (c) What mass of carbon dioxide is produced by combustion of the methane used to heat the house? (d) What mass of water is produced by combustion of the methane used to heat the house? (e) What volume of air is required to provide the oxygen for the combustion of the methane used to heat the house? Air contains 23% oxygen by mass. The average density of air during the month was 1.22 g/L. (f) How many kilowatt—hours ( 1kWh=3.6106 J) of electricity would be required to provide the heat necessary to heat the house? Note electricity is 100% efficient in producing heat inside a house. (g) Although electricity is 100% efficient in producing heat inside a house, production and distribution of electricity is not 100% efficient. The efficiency of production and distribution of electricity produced in a coal-fired power plant is about 40%. A certain type of coal provides 2.26 kWh per pound upon combustion. What mass of this coal in kilograms will be required to produce the electrical energy necessary to heat the house if the efficiency of generation and distribution is 40%?arrow_forward
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