Explanation The bond length of a molecule is inversely proportional to multiplicity of the bond. Greater the multiplicity of bond, shorter is the bond length. The Lewis structure for NO + as shown in Figure 1 below shows that there is N − O triple bond. Figure 1 The Lewis structure for NO 2 − as shown in Figure 2 below shows that there is one N − O double and one single bond. Figure 2 The Lewis structure for NO 3 − as shown in Figure 3 below shows that there is one N − O double and two N − O single bonds.

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Actinides

The elements in which the extra electron tends to enter the 5f-orbitals of (n–2)th main shell are considered 5f-block elements. They are also named actinides. Actinides include 15 elements, from atomic number 89 to 103.

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Chapter 8, Problem 56E

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To determine: The increasing order of N−O bond lengths in NO+ , NO2− and NO3−

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Chapter 8, Problem 55E

Chapter 8, Problem 57E

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22.22 For each compound, indicate which group on the ring is more strongly activating and then draw a structural formula of the major product formed by nitration of the compound. Br CHO (a) CH3 (b) (c) CHO CH3 SO₂H (d) ☑ OCHS NO₂ (e) (f) CO₂H NHCOCH3 NHCOCH, (h) CHS 22.23 The following molecules each contain two aromatic rings. (b) 000-100- H3C (a) (c) Which ring in each undergoes electrophilic aromatic substitution more readily? Draw the major product formed on nitration.

Chapter 8 Solutions

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Ch. 8.2 - Which of the these elements is most likely to from...Ch. 8.2 - Prob. 8.1.2PE Ch. 8.2 - Which of the following bond is the most polar? H-F...Ch. 8.2 - Prob. 8.2.2PE Ch. 8.3 - Prob. 8.3.1PE Ch. 8.3 - Prob. 8.3.2PE Ch. 8.4 - Which of the following bonds is the most polar? a....Ch. 8.4 - Which of the following bonds is most polar: S-Cl,...Ch. 8.4 - Prob. 8.5.1PE Ch. 8.4 - The dipole moment of chlorine monofluoride,...

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The increasing order of N − O bond lengths in NO + , NO 2 − and NO 3 −

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To determine: The increasing order of N−O bond lengths in NO+ , NO2− and NO3−

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Chapter 8 Solutions