Introductory Chemistry: Concepts and Critical Thinking (8th Edition)
8th Edition
ISBN: 9780134421377
Author: Charles H Corwin
Publisher: PEARSON
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Chapter 8, Problem 51E
Interpretation Introduction
Interpretation:
The empirical formula of tin oxide is to be calculated.
Concept introduction:
The empirical formula is the simplest whole number ratio of the atoms of the element present in the compound. The empirical formula is determined by two methods.
• Experimental synthesis data
• Percent composition
Percent composition is mostly used to determine empirical formula. In this method, after calculating the moles of each element in a compound, the mole ratio is simplified to a small whole number.
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From the following potentials, calculate the activity of Cl- in saturated KCl.
E0 (calomel electrode)= 0.268 V
E (calomel electrode, saturated KCl)= 0.241 V
Calculate the voltage of each of the following cells.
a) Fe(s)/Fe2+ (1.55 x 10-2 M)//Cu2+ (6.55 x 10-3 M)/Cu(s)
b) Pt, H2 (0.255 bar)/HCl (4.55 x 10-4 M), AgCl (sat'd)/Ag
Fe2+ +2e- = Fe E0= -0.44 V
Cu2+ + 2e- = Cu E0= 0.337 V
Ag+ + e- = Ag E0= 0.799 V
AgCl(s) + e- = Ag(s) + Cl- E0= 0.222 V
2H+ + 2e- = H2 E0= 0.000 V
A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol).
a) Write a balanced net reaction that can occur between species in this solution.
b) Calculate deltaG0 and K for the reaction.
c) Calculate E and deltaG for the conditions given.
Ce4+ + e- = Ce3+ E0= 1.70 V
MnO4- + 8H+ + 5e- = Mn2+ + 4H2O E0= 1.507 V
Chapter 8 Solutions
Introductory Chemistry: Concepts and Critical Thinking (8th Edition)
Ch. 8 - Prob. 1CECh. 8 - Prob. 2CECh. 8 - Prob. 3CECh. 8 - Prob. 4CECh. 8 - Prob. 5CECh. 8 - Prob. 6CECh. 8 - Prob. 7CECh. 8 - Prob. 8CECh. 8 - Prob. 9CECh. 8 - Prob. 10CE
Ch. 8 - Prob. 11CECh. 8 - Prob. 12CECh. 8 - Prob. 13CECh. 8 - Prob. 14CECh. 8 - Prob. 15CECh. 8 - Prob. 16CECh. 8 - Prob. 1KTCh. 8 - Prob. 2KTCh. 8 - Prob. 3KTCh. 8 - Prob. 4KTCh. 8 - Prob. 5KTCh. 8 - Prob. 6KTCh. 8 - Prob. 7KTCh. 8 - Prob. 8KTCh. 8 - Prob. 9KTCh. 8 - Prob. 10KTCh. 8 - Prob. 1ECh. 8 - Prob. 2ECh. 8 - Prob. 3ECh. 8 - Prob. 4ECh. 8 - Prob. 5ECh. 8 - Prob. 6ECh. 8 - Prob. 7ECh. 8 - Prob. 8ECh. 8 - Prob. 9ECh. 8 - Prob. 10ECh. 8 - Prob. 11ECh. 8 - Prob. 12ECh. 8 - Prob. 13ECh. 8 - Prob. 14ECh. 8 - Prob. 15ECh. 8 - Prob. 16ECh. 8 - Prob. 17ECh. 8 - Prob. 18ECh. 8 - Prob. 19ECh. 8 - Prob. 20ECh. 8 - Prob. 21ECh. 8 - Prob. 22ECh. 8 - Prob. 23ECh. 8 - Prob. 24ECh. 8 - Prob. 25ECh. 8 - Prob. 26ECh. 8 - Prob. 27ECh. 8 - Prob. 28ECh. 8 - Prob. 29ECh. 8 - Prob. 30ECh. 8 - Prob. 31ECh. 8 - Prob. 32ECh. 8 - Prob. 33ECh. 8 - Prob. 34ECh. 8 - Prob. 35ECh. 8 - Prob. 36ECh. 8 - Prob. 37ECh. 8 - Prob. 38ECh. 8 - Prob. 39ECh. 8 - Prob. 40ECh. 8 - Prob. 41ECh. 8 - Prob. 42ECh. 8 - Prob. 43ECh. 8 - Prob. 44ECh. 8 - Prob. 45ECh. 8 - Prob. 46ECh. 8 - Prob. 47ECh. 8 - Prob. 48ECh. 8 - Prob. 49ECh. 8 - Prob. 50ECh. 8 - Prob. 51ECh. 8 - Prob. 52ECh. 8 - Prob. 53ECh. 8 - Prob. 54ECh. 8 - Prob. 55ECh. 8 - Prob. 56ECh. 8 - Prob. 57ECh. 8 - Prob. 58ECh. 8 - Prob. 59ECh. 8 - Prob. 60ECh. 8 - Prob. 61ECh. 8 - Prob. 62ECh. 8 - Prob. 63ECh. 8 - Prob. 64ECh. 8 - Prob. 65ECh. 8 - Prob. 66ECh. 8 - Prob. 67ECh. 8 - Prob. 68ECh. 8 - Prob. 69ECh. 8 - Prob. 70ECh. 8 - Prob. 71ECh. 8 - Prob. 72ECh. 8 - Prob. 73ECh. 8 - Prob. 74ECh. 8 - Prob. 75ECh. 8 - Prob. 76ECh. 8 - Prob. 77ECh. 8 - Prob. 78ECh. 8 - Prob. 79ECh. 8 - Prob. 80ECh. 8 - Prob. 81ECh. 8 - Prob. 82ECh. 8 - Prob. 1STCh. 8 - Prob. 2STCh. 8 - Prob. 3STCh. 8 - Prob. 4STCh. 8 - Prob. 5STCh. 8 - Prob. 6STCh. 8 - Prob. 7STCh. 8 - Prob. 8STCh. 8 - Prob. 9STCh. 8 - Prob. 10STCh. 8 - Prob. 11STCh. 8 - Prob. 12STCh. 8 - Prob. 13STCh. 8 - Prob. 14STCh. 8 - Prob. 15ST
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