MASTERING CHEMISTRY:THE CENTRAL SCIENCE
13th Edition
ISBN: 9781269712538
Author: Brown
Publisher: PEARSON
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Textbook Question
Chapter 8, Problem 42E
Write out the ground-state electron configurations of
- Ti3+,
- Ru2+,
- Au3+,
- Mn4+,
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Relative Intensity
Part VI. consider the multi-step reaction below for compounds
A, B, and C.
These compounds were subjected to mass spectrometric analysis and
the following spectra for A, B, and C was obtained.
Draw the structure of B and C and match all three compounds
to the correct spectra.
Relative Intensity
Relative Intensity
100
HS-NJ-0547
80
60
31
20
S1
84
M+
absent
10
30
40
50
60
70
80
90
100
100-
MS2016-05353CM
80-
60
40
20
135 137
S2
164 166
0-m
25
50
75
100
125
150
m/z
60
100
MS-NJ-09-43
40
20
20
80
45
S3
25
50
75
100
125
150
175
m/z
Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Chapter 8 Solutions
MASTERING CHEMISTRY:THE CENTRAL SCIENCE
Ch. 8.2 - Prob. 8.1.1PECh. 8.2 - Prob. 8.1.2PECh. 8.2 - Prob. 8.2.1PECh. 8.2 - Prob. 8.2.2PECh. 8.3 - Prob. 8.3.1PECh. 8.3 - Prob. 8.3.2PECh. 8.4 - Prob. 8.4.1PECh. 8.4 - Prob. 8.4.2PECh. 8.4 - Prob. 8.5.1PECh. 8.4 - Prob. 8.5.2PE
Ch. 8.5 - Prob. 8.6.1PECh. 8.5 - Prob. 8.6.2PECh. 8.5 - Prob. 8.7.1PECh. 8.5 - Prob. 8.7.2PECh. 8.5 - Prob. 8.8.1PECh. 8.5 - Prob. 8.8.2PECh. 8.5 - Prob. 8.9.1PECh. 8.5 - Prob. 8.9.2PECh. 8.6 - Prob. 8.10.1PECh. 8.6 - Prob. 8.10.2PECh. 8.7 - Prob. 8.11.1PECh. 8.7 - Write the formulas for the following compounds,...Ch. 8.7 - Prob. 8.12.1PECh. 8.7 - Prob. 8.12.2PECh. 8 - Prob. 1DECh. 8 - Prob. 1ECh. 8 - The three graphs below show the variation in...Ch. 8 - Prob. 3ECh. 8 - Prob. 4ECh. 8 - Prob. 5ECh. 8 - Prob. 6ECh. 8 - The partial Lewis structure that follows Is for a...Ch. 8 - Prob. 8ECh. 8 - Prob. 9ECh. 8 - Prob. 10ECh. 8 - Prob. 11ECh. 8 - Prob. 12ECh. 8 - Prob. 13ECh. 8 - Prob. 14ECh. 8 - Prob. 15ECh. 8 - Prob. 16ECh. 8 - Prob. 17ECh. 8 - Prob. 18ECh. 8 - What is the name of the compound [Rh(NH3)4Cl2]Cl ?...Ch. 8 - Prob. 20ECh. 8 - Which of the following complexes has an optical...Ch. 8 - Prob. 22ECh. 8 - Prob. 23ECh. 8 - Prob. 24ECh. 8 - Prob. 25ECh. 8 - Prob. 26ECh. 8 - Prob. 27ECh. 8 - Prob. 28ECh. 8 - Prob. 29ECh. 8 - Prob. 30ECh. 8 - Prob. 31ECh. 8 - Prob. 32ECh. 8 - Prob. 33ECh. 8 - Prob. 34ECh. 8 - Prob. 35ECh. 8 - Prob. 36ECh. 8 - Prob. 37ECh. 8 - Prob. 38ECh. 8 - Prob. 39ECh. 8 - Prob. 40ECh. 8 - Prob. 41ECh. 8 - Write out the ground-state electron configurations...Ch. 8 - Prob. 43ECh. 8 - Prob. 44ECh. 8 - Prob. 45ECh. 8 - Prob. 46ECh. 8 - Prob. 47ECh. 8 - Prob. 48ECh. 8 - Prob. 49ECh. 8 - Prob. 50ECh. 8 - Prob. 51ECh. 8 - Indicate the coordination number and the oxidation...Ch. 8 - Prob. 53ECh. 8 - Prob. 54ECh. 8 - Prob. 55ECh. 8 - Prob. 56ECh. 8 - (a) Do the C—C bond lengths in benzene alternate...Ch. 8 - Prob. 58ECh. 8 - Prob. 59ECh. 8 - Write the formula for each of the following...Ch. 8 - Prob. 61ECh. 8 - Prob. 62ECh. 8 - Prob. 63ECh. 8 - Prob. 64ECh. 8 - Prob. 65ECh. 8 - Prob. 66ECh. 8 - Prob. 67ECh. 8 - Prob. 68ECh. 8 - Prob. 69ECh. 8 - Prob. 70ECh. 8 - Prob. 71ECh. 8 - Prob. 72ECh. 8 - Prob. 73ECh. 8 - Prob. 74ECh. 8 - Prob. 75ECh. 8 - Prob. 76ECh. 8 - Prob. 77AECh. 8 - Prob. 78AECh. 8 - Prob. 79AECh. 8 - Prob. 80AECh. 8 - Prob. 81AECh. 8 - Prob. 82AECh. 8 - Prob. 83AECh. 8 - Prob. 84AECh. 8 - 23.62 For each of the following metals, write the...Ch. 8 - Prob. 86AECh. 8 - Prob. 87AECh. 8 - Prob. 88AECh. 8 - Prob. 89AECh. 8 - Prob. 90AECh. 8 - (a) Determine the formal charge on the chlorine...Ch. 8 - Prob. 92AECh. 8 - Prob. 93AECh. 8 - Prob. 94AECh. 8 - Prob. 95AECh. 8 - Prob. 96AECh. 8 - Prob. 97AECh. 8 - Prob. 98AECh. 8 - Prob. 99AECh. 8 - Prob. 100AECh. 8 - Prob. 101IECh. 8 - Prob. 102IECh. 8 - Prob. 103IECh. 8 - Prob. 104IECh. 8 - Prob. 105IECh. 8 - Prob. 106IECh. 8 - Prob. 107IECh. 8 - Prob. 108IECh. 8 - Prob. 109IECh. 8 - Prob. 110IECh. 8 -
8.11 I Consider benzene (C6H6) in the gas phase....Ch. 8 -
8.112 Average bond enthalpies are generally...Ch. 8 - Prob. 113IE
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