Bundle: Introductory Chemistry: An Active Learning Approach, 6th + OWLv2, 1 term (6 months) Printed Access Card
6th Edition
ISBN: 9781305717367
Author: Mark S. Cracolice, Ed Peters
Publisher: Cengage Learning
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Textbook Question
Chapter 8, Problem 41E
Questions 31 to 66: Write the equation for the reaction described or for the most likely reaction between given reactants.
Ammonium sulfide is added to a solution of copper
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You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you
manipulated and exploited the acid-base chemistry of one or more of the compounds in your
mixture to facilitate their separation into different phases. The key to understanding how liquid-
liquid extractions work is by knowing which layer a compound is in, and in what protonation state.
The following liquid-liquid extraction is different from the one you performed in Experiment
4, but it uses the same type of logic. Your task is to show how to separate apart Compound
A and Compound B.
. Complete the following flowchart of a liquid-liquid extraction. Handwritten work is
encouraged.
•
Draw by hand (neatly) only the appropriate organic compound(s) in the boxes.
.
Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4
and 5.
•
Box 7a requires the solvent (name is fine).
•
Box 7b requires one inorganic compound.
• You can neatly complete this assignment by hand and…
b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;'
The compound has the ff electronic transitions: 0%o* and no a*
1H NMR Spectrum
(CDCl3, 400 MHz)
3.5
3.0
2.5
2.0
1.5
1.0
0.5 ppm
13C{H} NMR Spectrum
(CDCl3, 100 MHz)
Solvent
80
70
60
50
40
30
20
10
0 ppm
ppm
¹H-13C me-HSQC Spectrum
ppm
(CDCl3, 400 MHz)
5
¹H-¹H COSY Spectrum
(CDCl3, 400 MHz)
0.5
10
3.5
3.0
2.5
2.0
1.5 1.0
10
15
20
20
25
30
30
-35
-1.0
1.5
-2.0
-2.5
3.0
-3.5
0.5
ppm
3.5
3.0
2.5
2.0
1.5
1.0
0.5
ppm
Show work with explanation. don't give Ai generated solution
Chapter 8 Solutions
Bundle: Introductory Chemistry: An Active Learning Approach, 6th + OWLv2, 1 term (6 months) Printed Access Card
Ch. 8 - Consider the following particulate-level...Ch. 8 - Prob. 2ECh. 8 - The left box of the following diagram shows the...Ch. 8 - Draw a box and then sketch five space-filling...Ch. 8 - Prob. 5ECh. 8 - Consider the reaction of the elements antimony and...Ch. 8 - Write a balanced the chemical equation to...Ch. 8 - Write and balance the equation for the reaction of...Ch. 8 - Questions 9 to 30: Write the equation for each...Ch. 8 - Prob. 10E
Ch. 8 - Questions 9 to 30: Write the equation for each...Ch. 8 - Prob. 12ECh. 8 - Questions 9 to 30: Write the equation for each...Ch. 8 - Prob. 14ECh. 8 - Questions 9 to 30: write the equations for each...Ch. 8 - Prob. 16ECh. 8 - Questions 9 to 30: write the equations for each...Ch. 8 - Questions 9 to 30: write the equations for each...Ch. 8 - Questions 9 to 30: Write the equation for each...Ch. 8 - Prob. 20ECh. 8 - Questions 9 to 30: Write the equation for each...Ch. 8 - Questions 9 to 30: Write the equation for each...Ch. 8 - Questions 9 to 30: Write the equation for each...Ch. 8 - Prob. 24ECh. 8 - Questions 9 to 30: Write the equation for each...Ch. 8 - Prob. 26ECh. 8 - Questions 9 to 30: Write the equation for each...Ch. 8 - Prob. 28ECh. 8 - Sodium hydroxide is added to phosphoric acid.Ch. 8 - A reaction occurs when aqueous solutions of...Ch. 8 - Lead II nitrate solution reacts with a solution of...Ch. 8 - A precipitate forms when aqueous solutions of...Ch. 8 - Questions 31 to 66: Write the equation for the...Ch. 8 - Prob. 34ECh. 8 - Questions 31 to 66: Write the equation for the...Ch. 8 - Prob. 36ECh. 8 - Questions 31 to 66: Write the equation for the...Ch. 8 - Prob. 38ECh. 8 - Questions 31 to 66: Write the equation for the...Ch. 8 - Prob. 40ECh. 8 - Questions 31 to 66: Write the equation for the...Ch. 8 - Prob. 42ECh. 8 - Phosphorous tribromide is produced when...Ch. 8 - Prob. 44ECh. 8 - Prob. 45ECh. 8 - Prob. 46ECh. 8 - Prob. 47ECh. 8 - Prob. 48ECh. 8 - Questions 31 to 66: Write the equation for the...Ch. 8 - Prob. 50ECh. 8 - Questions 31 to 66: Write the equation for the...Ch. 8 - Prob. 52ECh. 8 - Questions 31 to 66: Write the equation for the...Ch. 8 - Prob. 54ECh. 8 - Prob. 55ECh. 8 - Prob. 56ECh. 8 - Prob. 57ECh. 8 - Prob. 58ECh. 8 - Prob. 59ECh. 8 - Prob. 60ECh. 8 - Questions 31 to 66:-Write the equation for the...Ch. 8 - Prob. 62ECh. 8 - Questions 31 to 66: Write the equation for the...Ch. 8 - Prob. 64ECh. 8 - Questions 31 to 66: Write the equation for the...Ch. 8 - Prob. 66ECh. 8 - Prob. 67ECh. 8 - Classify each of the following statements as true...Ch. 8 - Prob. 69ECh. 8 - Prob. 70ECh. 8 - Acid rain is rainfall that contains sulfuric acid...Ch. 8 - One of the harmful effects of acid rain is its...Ch. 8 - The tarnish that appears on silver is silver...Ch. 8 - Prob. 74ECh. 8 - One source of the pure tungsten (Z=74) filament...Ch. 8 - Prob. 76ECh. 8 - Prob. 77ECh. 8 - Prob. 78ECh. 8 - Prob. 79ECh. 8 - Prob. 8.1TCCh. 8 - Prob. 8.2TCCh. 8 - Prob. 8.3TCCh. 8 - Prob. 1PECh. 8 - Prob. 2PECh. 8 - Prob. 3PECh. 8 - Prob. 4PECh. 8 - Prob. 5PECh. 8 - Prob. 6PECh. 8 - Prob. 7PECh. 8 - Prob. 8PECh. 8 - Lead reacts with a solution of copper (II)...Ch. 8 - Prob. 10PECh. 8 - Prob. 11PECh. 8 - Prob. 1ECECh. 8 - Prob. 2ECECh. 8 - Prob. 3ECECh. 8 - Prob. 4ECECh. 8 - Prob. 5ECECh. 8 - Prob. 6ECECh. 8 - Prob. 7ECECh. 8 - Prob. 8ECECh. 8 - Prob. 9ECECh. 8 - Prob. 10ECECh. 8 - Prob. 11ECECh. 8 - Prob. 12ECECh. 8 - Prob. 1EBECh. 8 - Prob. 2EBECh. 8 - Prob. 3EBECh. 8 - Prob. 4EBECh. 8 - Prob. 5EBECh. 8 - Prob. 6EBECh. 8 - Prob. 7EBECh. 8 - Prob. 8EBECh. 8 - Prob. 9EBECh. 8 - Prob. 10EBECh. 8 - Prob. 11EBECh. 8 - Prob. 12EBECh. 8 - Prob. 13EBECh. 8 - Prob. 14EBECh. 8 - Prob. 15EBECh. 8 - Prob. 16EBECh. 8 - Prob. 17EBECh. 8 - Prob. 18EBECh. 8 - Prob. 19EBECh. 8 - Prob. 20EBECh. 8 - Prob. 21EBECh. 8 - Balance the following equations, for which correct...Ch. 8 - Prob. 23EBECh. 8 - Prob. 24EBECh. 8 - Prob. 25EBE
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- Redraw the flowchartarrow_forwardredraw the flowchart with boxes and molecules written in themarrow_forwardPart I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward
- • Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peakarrow_forwardCould you redraw these and also explain how to solve them for me pleasarrow_forwardNonearrow_forward
- Draw the curved-arrow mechanism with the drawings of the molecules, not just abbreviations. -NO₂ Sn, HCl (aq) E D H (CH3CO)₂O -NH2 CH3arrow_forwardWhat is/are the product(s) of the following reaction? Select all that apply. * HI A B C OD OH A B OH D Carrow_forwardIn the image, the light blue sphere represents a mole of hydrogen atoms, the purple or teal spheres represent a mole of a conjugate base. A light blue sphere by itself is H+. Assuming there is 2.00 L of solution, answer the following: The Ka of the left & right solution is? The pH of the left & right solution is? The acid on the left & right is what kind of acid?arrow_forward
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