Chemistry: Structure and Properties
1st Edition
ISBN: 9780321834683
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 8, Problem 36E
Consider the unbalanced equation for the neutralization of acetic acid HC2H3O2(aq) + Ba(OH)2(aq) → H2O(l) + Ba(Ca2Ha3O2)2(aq)
Balance the equation and determine how many moles of Ba(OH)2 are required to completely neutralize 0.461 mole of HC2H3O2.
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each pair of substrates below, choose the one that will react faster in a substitution reaction, assuming that:
1. the rate of substitution doesn't depend on nucleophile concentration and
2. the products are a roughly 50/50 mixture of enantiomers.
Substrate A
Substrate B
Faster Rate
X
Ś
CI
(Choose one)
(Choose one)
CI
Br
Explanation
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Br
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
4.1 ppm? Select the single best answer.
The
H
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HỌC—C—0—CH, CH,
2
A
ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
Check
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B
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B
C
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
Chapter 8 Solutions
Chemistry: Structure and Properties
Ch. 8 - What are the correct coefficients (reading from...Ch. 8 - Prob. 2SAQCh. 8 - Prob. 3SAQCh. 8 - For the reaction shown here, 3.5 mol A is mixed...Ch. 8 - Manganese(IV) oxide reacts with aluminum to form...Ch. 8 - Sodium and chlorine react to form sodium chloride....Ch. 8 - Sulfur and fluorine react to form sulfur...Ch. 8 - A reaction has a theoretical yield of 45.8 g. When...Ch. 8 - Prob. 9SAQCh. 8 - Solid potassium chlorate (KCIO3) decomposes into...
Ch. 8 - Prob. 1ECh. 8 - Prob. 2ECh. 8 - What is the difference between a physical change...Ch. 8 - What is the difference between a physical property...Ch. 8 - What is a balanced chemical equation?Ch. 8 - Why must chemical equations be balanced?Ch. 8 - What is reaction stoichiometry? What is the...Ch. 8 - In a chemical reaction, what is the limiting...Ch. 8 - In a chemical reaction, what is the theoretical...Ch. 8 - We typically calculate the percent yield using the...Ch. 8 - Prob. 11ECh. 8 - Prob. 12ECh. 8 - Write a general equation for the reaction of an...Ch. 8 - Prob. 14ECh. 8 - Classify each change as physical or chemical....Ch. 8 - Prob. 16ECh. 8 - Prob. 17ECh. 8 - Prob. 18ECh. 8 - Classify each of the listed properties of...Ch. 8 - Prob. 20ECh. 8 - Classify each property as physical or chemical the...Ch. 8 - Prob. 22ECh. 8 - Sulfuric acid (H2SO4) is a component of acid rain...Ch. 8 - Nitric acid (HNO3) is a component of acid rain...Ch. 8 - Prob. 25ECh. 8 - Prob. 26ECh. 8 - Write a balanced chemical equation for the...Ch. 8 - Write a balanced equation for the photosynthesis...Ch. 8 - Write a balanced chemical equation for each...Ch. 8 - Write a balanced chemical equation for each...Ch. 8 - Write a balanced chemical equation for the...Ch. 8 - Write a balanced chemical equation for the...Ch. 8 - Balance each chemical equation. CO2(g) + CaSiO3(s)...Ch. 8 - Balance each chemical equation. Na2S(aq) +...Ch. 8 - Prob. 35ECh. 8 - Consider the unbalanced equation for the...Ch. 8 - Calculate how many moles of NO2 form when each...Ch. 8 - Calculate how many moles of NH3 form when each...Ch. 8 - Consider the balanced equation: SiO2(s) + 3 C(s)...Ch. 8 - Consider the balanced equation: 2 N2H4(s) +...Ch. 8 - Hydrobromic acid (HBr) dissolves solid iron...Ch. 8 - Sulfuric acid (H2SO4) dissolves aluminum metal...Ch. 8 - For each of the reactions, calculate the mass (in...Ch. 8 - For each of the reactions, calculate the mass (in...Ch. 8 - For the following reaction, determine the limiting...Ch. 8 - Find the limiting reactant for each initial amount...Ch. 8 - Consider the reaction: HCl(g) + O2(g) 2 H2O(g) +...Ch. 8 - Consider the reaction: 2 CH 3 OH(g)+3 O 2 (g)2 CO...Ch. 8 - Calculate the theoretical yield of the product (in...Ch. 8 - Calculate the theoretical yield of product (in...Ch. 8 - Zinc sulfide reacts with oxygen according to the...Ch. 8 - Iron(ll) sulfide reacts with hydrochloric acid...Ch. 8 - For the reaction shown, calculate the theoretical...Ch. 8 - For the reaction shown, calculate the theoretical...Ch. 8 - Iron(lll) oxide reacts with carbon monoxide...Ch. 8 - Elemental phosphorus reacts with chlorine gas...Ch. 8 - Lead(ll) ions can be removed from solution with...Ch. 8 - Prob. 58ECh. 8 - Urea (CH4N2O) is a common fertilizer that is...Ch. 8 - Prob. 60ECh. 8 - Prob. 61ECh. 8 - Complete and balance each combustion reaction...Ch. 8 - Prob. 63ECh. 8 - Prob. 64ECh. 8 - Prob. 65ECh. 8 - Prob. 66ECh. 8 - Prob. 67ECh. 8 - Prob. 68ECh. 8 - Prob. 69ECh. 8 - Prob. 70ECh. 8 - Aspirin can be made in the laboratory by reacting...Ch. 8 - The combustion of liquid ethanol (C2H5OH) produces...Ch. 8 - Prob. 73ECh. 8 - Prob. 74ECh. 8 - Prob. 75ECh. 8 - An important reaction that takes place in a blast...Ch. 8 - A liquid fuel mixture contains 30.35% hexane...Ch. 8 - Titanium occurs in the magnetic mineral ilmenite...Ch. 8 - A mixture of C3H8 and C2H2 has a mass of 2.0 g. It...Ch. 8 - Prob. 80ECh. 8 - Lead poisoning is a serious condition resulting...Ch. 8 - Prob. 82ECh. 8 - Metallic aluminum reacts with MnO2 at elevated...Ch. 8 - Prob. 84ECh. 8 - Consider the reaction: 4K(s)+O2(g)2K2O(s) The...Ch. 8 - Prob. 86ECh. 8 - Consider the reaction:...
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- in the kinetics experiment, what were the values calculated? Select all that apply.a) equilibrium constantb) pHc) order of reactiond) rate contstantarrow_forwardtrue or false, given that a 20.00 mL sample of NaOH took 24.15 mL of 0.141 M HCI to reach the endpoint in a titration, the concentration of the NaOH is 1.17 M.arrow_forwardin the bromothymol blue experiment, pKa was measured. A closely related compound has a Ka of 2.10 x 10-5. What is the pKa?a) 7.1b) 4.7c) 2.0arrow_forward
- calculate the equilibrium concentration of H2 given that K= 0.017 at a constant temperature for this reaction. The inital concentration of HBr is 0.050 M.2HBr(g) ↔ H2(g) + Br2(g)a) 4.48 x 10-2 M b) 5.17 x 10-3 Mc) 1.03 x 10-2 Md) 1.70 x 10-2 Marrow_forwardtrue or falsegiven these two equilibria with their equilibrium constants:H2(g) + CI2(l) ↔ 2HCI(g) K= 0.006 CI2(l) ↔ CI2(g) K= 0.30The equilibrium contstant for the following reaction is 1.8H2(g) + CI2 ↔ 2HCI(g)arrow_forwardI2(g) + CI2(g) ↔ 2ICIK for this reaction is 81.9. Find the equilibrium concentration of I2 if the inital concentration of I2 and CI2 are 0.010 Marrow_forward
- true or false,the equilibrium constant for this reaction is 0.50.PCI5(g) ↔ PCI3(g) + CI2(g)Based on the above, the equilibrium constant for the following reaction is 0.25.2PCI5(g) ↔. 2PCI3(g) + 2CI2(g)arrow_forwardtrue or false, using the following equilibrium, if carbon dioxide is added the equilibrium will shift toward the productsC(s) + CO2(g) ↔ 2CO(g)arrow_forward2S2O2/3- (aq) + I2 (aq) ---> S4O2/6- (aq) +2I- (aq) Experiment I2 (M) S2O3- (M) Initital Rate (M/s) 1 0.01 0.01 0.0004 2 0.01 0.02 0.0004 3 0.02 0.01 0.0008 Calculate the overall order for this reaction using the table data a) 3b) 0c) 2d) 1arrow_forward
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