(a) Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated. Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes . The mechanism of the reaction depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

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Answer 1

Question

Chapter 8, Problem 28P

Interpretation Introduction

(a)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(b)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(c)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(d)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

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When 15.00 mL of 3.00 M NaOH was mixed in a calorimeter with 12.80 mL of 3.00 M HCl, both initially at room temperature (22.00 C), the temperature increased to 29.30 C. The resultant salt solution had a mass of 27.80 g and a specific heat capacity of 3.74 J/Kg. What is heat capacity of the calorimeter (in J/C)? Note: The molar enthalpy of neutralization per mole of HCl is -55.84 kJ/mol.

When 15.00 mL of 3.00 M NaOH was mixed in a calorimeter with 12.80 mL of 3.00 M HCl, both initially at room temperature (22.00 C), the temperature increased to 29.30 C. The resultant salt solution had a mass of 27.80 g and a specific heat capacity of 3.74 J/Kg. What is heat capacity of the calorimeter (in J/C)? Note: The molar enthalpy of neutralization per mole of HCl is -55.84 kJ/mol. Which experimental number must be initialled by the Lab TA for the first run of Part 1 of the experiment? a) the heat capacity of the calorimeter b) Mass of sample c) Ti d) The molarity of the HCl e) Tf

Predict products for the Following organic rxn/s by writing the structurels of the correct products. Write above the line provided" your answer D2 ①CH3(CH2) 5 CH3 + D₂ (adequate)" + 2 mited) 19 Spark Spark por every item. 4 CH 3 11 3 CH 3 (CH2) 4 C-H + CH3OH CH2 CH3 + CH3 CH2OH 0 CH3 fou + KMnDy→ C43 + 2 KMn Dy→→ C-OH ") 0 C-OH 1110 (4.) 9+3 =C CH3 + HNO 3 0 + Heat> + CH3 C-OH + Heat CH2CH3 - 3 2 + D Heat H 3 CH 3 CH₂ CH₂ C = CH + 2 H₂ → 2 2

Answer 2

Question

Chapter 8, Problem 28P

Interpretation Introduction

(a)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(b)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(c)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(d)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

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Answer 3

Question

Chapter 8, Problem 28P

Interpretation Introduction

(a)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(b)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(c)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(d)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

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Answer 4

Question

Chapter 8, Problem 28P

Interpretation Introduction

(a)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(b)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(c)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(d)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

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Answer 5

Chapter 8, Problem 28P

Interpretation Introduction

(a)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(b)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(c)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(d)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Answer 6

Chapter 8, Problem 28P

Interpretation Introduction

(a)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Answer 7

Chapter 8, Problem 28P

Interpretation Introduction

(a)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Answer 8

Interpretation Introduction

(b)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Answer 9

Interpretation Introduction

(b)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Answer 10

Interpretation Introduction

(c)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Answer 11

Interpretation Introduction

(c)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Answer 12

Interpretation Introduction

(d)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Answer 13

Interpretation Introduction

(d)

Interpretation: The alkyl halide which forms the given alkene as the only product in an elimination reaction is to be stated.

Concept introduction: Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 8.1 - Problem 8.1 Label the and carbons in each alkyl...Ch. 8.2 - Problem 8.2 Classify each alkene in the following...Ch. 8.2 - Prob. 3P Ch. 8.2 - Prob. 4P Ch. 8.2 - Problem 8.5 Label each pair of alkenes as...Ch. 8.2 - Problem 8.6 Which alkene in each pair is more...Ch. 8.2 - Problem 8.7 Several factors can affect alkene...Ch. 8.4 - Prob. 8P Ch. 8.4 - Prob. 9P Ch. 8.4 - Prob. 10P

Solution Summary: The author explains that the structure of the alkene indicates that it is formed from a primary halide. Strong bases are usually employed for elimination reactions.

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Chapter 8 Solutions