ACCESS CODE W/E TEXT CONNECT
5th Edition
ISBN: 9781260162660
Author: BAUER
Publisher: MCG
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Textbook Question
Chapter 8, Problem 15QP
Predict whether each of the following substances is likely to have a relatively high or low boiling point.
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Students have asked these similar questions
Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 8 Solutions
ACCESS CODE W/E TEXT CONNECT
Ch. 8 - Prob. 1QCCh. 8 - Prob. 2QCCh. 8 - Prob. 3QCCh. 8 - Prob. 4QCCh. 8 - Prob. 5QCCh. 8 - Prob. 1PPCh. 8 - Prob. 2PPCh. 8 - Prob. 3PPCh. 8 - Prob. 4PPCh. 8 - Prob. 5PP
Ch. 8 - Prob. 6PPCh. 8 - Prob. 7PPCh. 8 - Prob. 8PPCh. 8 - Prob. 9PPCh. 8 - Prob. 10PPCh. 8 - Prob. 11PPCh. 8 - Prob. 1QPCh. 8 - Prob. 2QPCh. 8 - What is a chemical bond?Ch. 8 - Describe the difference between ionic and covalent...Ch. 8 - Which type of elements are most likely to form...Ch. 8 - Which type of elements are most likely to form...Ch. 8 - Prob. 7QPCh. 8 - Which of the following compounds are likely to...Ch. 8 - Prob. 9QPCh. 8 - Prob. 10QPCh. 8 - Prob. 13QPCh. 8 - Which of the following compounds are likely to...Ch. 8 - Predict whether each of the following substances...Ch. 8 - Prob. 16QPCh. 8 - Describe how electronegativity values change going...Ch. 8 - Compare the electronegativity of metallic and...Ch. 8 - What kind of bonds are always nonpolar?Ch. 8 - Describe how to decide whether a bond is polar.Ch. 8 - Prob. 21QPCh. 8 - Using periodic trends, arrange the following atoms...Ch. 8 - Prob. 23QPCh. 8 - Prob. 24QPCh. 8 - Prob. 25QPCh. 8 - Arrange the following bonds in order of increasing...Ch. 8 - What information can be determine from Lewis...Ch. 8 - What is the maximum number of valence electrons...Ch. 8 - Draw Lewis symbols showing the valence electrons...Ch. 8 - Draw Lewis symbols showing the valence electrons...Ch. 8 - Draw Lewis symbols showing the valence electrons...Ch. 8 - Prob. 32QPCh. 8 - Write a formula for each of the following ionic...Ch. 8 - Write a formula for each of the following ionic...Ch. 8 - Prob. 35QPCh. 8 - Prob. 36QPCh. 8 - Prob. 37QPCh. 8 - Prob. 38QPCh. 8 - Prob. 39QPCh. 8 - What holds ions together in a crystal lattice?Ch. 8 - Describe the sodium chloride structure shown in...Ch. 8 - Describe the cesium chloride structure shown in...Ch. 8 - Why does CaF2 have a different crystal structure...Ch. 8 - Prob. 44QPCh. 8 - Draw the Lewis structures for O2andF2. (a) How...Ch. 8 - Draw the Lewis structures for I2andN2. (a) How...Ch. 8 - Why does hydrogen exist as a diatomic molecules?Ch. 8 - How many electrons does each hydrogen have in the...Ch. 8 - How many single bonds are typically formed by the...Ch. 8 - How many single bonds are typically formed by the...Ch. 8 - Identify a main-group element (X) could form each...Ch. 8 - Identify a main-group element (X) could form each...Ch. 8 - Prob. 53QPCh. 8 - Draw a Lewis structure for each of the following:...Ch. 8 - Draw a Lewis structure for each of the following:...Ch. 8 - Prob. 56QPCh. 8 - Prob. 57QPCh. 8 - Prob. 58QPCh. 8 - Prob. 59QPCh. 8 - How is the concept of resonance consistence with...Ch. 8 - Prob. 61QPCh. 8 - Indicate whether or not each of the following...Ch. 8 - Draw a Lewis structure, include the resonance...Ch. 8 - Prob. 64QPCh. 8 - In HF, the hydrogen atoms shares two electrons...Ch. 8 - Describe the bonding in S2Cl2. The atom are...Ch. 8 - Decide whether the indicated atoms obeys the octet...Ch. 8 - Decide whether the indicated atom obeys the octet...Ch. 8 - An atom of the following molecules does not obey...Ch. 8 - An atom of the following molecules does not obey...Ch. 8 - Prob. 71QPCh. 8 - Prob. 72QPCh. 8 - Draw the Lewis structure of benzene, C6H6, a...Ch. 8 - Prob. 74QPCh. 8 - Prob. 75QPCh. 8 - Prob. 76QPCh. 8 - Prob. 77QPCh. 8 - Prob. 78QPCh. 8 - Identify the class of class of substance for each...Ch. 8 - Prob. 80QPCh. 8 - Draw the Lewis structure for an aldehyde that has...Ch. 8 - Draw the Lewis structure for ketone that has the...Ch. 8 - Prob. 83QPCh. 8 - Why are unshared pairs of electrons on a central...Ch. 8 - Why is it important to draw Lewis structures...Ch. 8 - Explain how nonbonding pairs of electrons...Ch. 8 - Draw each of the following geometric arrangements....Ch. 8 - In which of the following molecular shapes would...Ch. 8 - Predict the parent structures of the following...Ch. 8 - Predict the parent structures of the following...Ch. 8 - Predict the parent structures of the following...Ch. 8 - Predict the shapes and gives approximate bond...Ch. 8 - Predict the bond angles in the following...Ch. 8 - Predict the bond angles in the following...Ch. 8 - Prob. 95QPCh. 8 - Prob. 96QPCh. 8 - Prob. 97QPCh. 8 - Prob. 98QPCh. 8 - Is this the shape of NO3 or ClO3?Ch. 8 - Is this shape of
Ch. 8 - Which of the following molecules or ions have...Ch. 8 - Which of the following molecules or ions have...Ch. 8 - Hydrazine, N2H4, is a colorless, oily liquid that...Ch. 8 - Oxalic acid, H2C2O4, a poisonous colorless solid,...Ch. 8 - Chloropicrin, Cl3CNO2, is an insecticide that has...Ch. 8 - Fuel cell are used in many areas, such as the...Ch. 8 - Distinguish between bond polarity and molecular...Ch. 8 - Why does molecular polarity depend not only on...Ch. 8 - Explain how carbon tetrachloride can have polar...Ch. 8 - Explain why hydrocarbons are all essentially...Ch. 8 - Are the following molecules polar or nonpolar?...Ch. 8 - Are the following molecules polar or nonpolar?...Ch. 8 - For each pair of molecules decide which molecule...Ch. 8 - Explain why the first molecule of each pair is...Ch. 8 - Prob. 115QPCh. 8 - Prob. 116QPCh. 8 - Which molecule, CF4orCCl2F2, is most likely to be...Ch. 8 - Which molecule, SO2orCO2, is most likely to be...Ch. 8 - Which of these molecules is polar? Assume the...Ch. 8 - Which of these molecules is polar? Assume the...Ch. 8 - Draw Lewis symbols showing the valence electrons...Ch. 8 - Draw Lewis symbols showing the valence electrons...Ch. 8 - Arrange the following atoms in order of decreasing...Ch. 8 - Prob. 124QPCh. 8 - Classify each of the following substances...Ch. 8 - Draw a Lewis structure for each of the following....Ch. 8 - Prob. 127QPCh. 8 - Draw a Lewis structure, including the resonance...Ch. 8 - Draw the Lewis structure for each of the...Ch. 8 - Gaseous aluminium chloride exists as a dimer,...Ch. 8 - Describe the molecular shape of each of the...Ch. 8 - Describe the structure and bonding in sulfuric...Ch. 8 - Decide which of each pair of gaseous molecules is...Ch. 8 - Which of the following are nonpolar molecules,...Ch. 8 - For each pair of molecules decide which molecule...Ch. 8 - Prob. 136QPCh. 8 - Predict whether each of the following substances...Ch. 8 - Predict whether each of the following substances...Ch. 8 - Prob. 139QPCh. 8 - Prob. 140QPCh. 8 - There are two different alcohols with the formula...Ch. 8 - The proteins in our bodies are built from small...Ch. 8 - Prob. 143QPCh. 8 - Plastic food storage containers are often made of...Ch. 8 - Draw the Lewis structure for a ketone containing...Ch. 8 - Compare the molecular shape around each carbon...Ch. 8 - Which compound contains both covalent and ionic...Ch. 8 - The bonds in O3 are expected to be A. ionic...Ch. 8 - Which of the following is a true statement about...Ch. 8 - Which of the following bonds is most polar?...Ch. 8 - Which of the following always violets the octet...Ch. 8 - Identify the main-group element X that could form...Ch. 8 - Which of the following has a Lewis structure most...Ch. 8 - Which of the following has a double bond?...Ch. 8 - Which of the following statements about resonance...Ch. 8 - Prob. 156QPCh. 8 - Which of the following molecules has a bent...Ch. 8 - Which of the following molecules is polar?...
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- Nonearrow_forwardPart II. Given below are the 'H-NMR spectrum at 300 MHz in CDC13 and mass spectrum using electron ionization of compound Brian. The FTIR of the said compound showed a strong peak at 1710 cm"). Determine the following: (a) molecular Formula and Degree of unsaturation of compound Brian (b) Basing on the given H-NMR spectrum tabulate the following (i) chemical shifts (ii) integration, ciii) multiplicity and (iv) interferences made for each signal (c) Draw the structure of compound Brian. ) ΕΙ 43 41 27 71 114 (M+) Hmmm 20 30 40 50 60 70 80 90 100 110 120 1H NMR spectrum 300 MHz in CDCl3 2.0 alle 1.0arrow_forwardThe iron-iron carbide phase diagram. In the diagram, the letter L indicates that it is a liquid. Indicate what its components are. Temperature (°C) 1600 10 Composition (at% C) 15 25 1538°C -1493°C 8 1400 1200 1394°C y+L L 2500 1147°C y. Austenite 2.14 4.30 2000 1000 912°C y + Fe3C 800ㅏ 0.76 0.022 600 a, Ferrite a + Fe3C 400 0 (Fe) Composition (wt% C) 727°C 1500 Cementite (Fe3C) 1000 6 6.70 Temperature (°F)arrow_forward
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