
a)

Interpretation:
Assuming Markovnikov’s rule is valid, the major alcohol product obtainable by the acid-catalyzed addition of water to 3-methyl-3-butene is to be predicted.
Concept introduction:
Markovnikov’s rule can be used to decide on the orientation in electrophilic addition reactions. According to this rule, in the addition of HX to an
To state:
The major alcohol product obtainable by the acid-catalyzed addition of water to 3-methyl-3-butene assuming that Markovnikov’s rule is valid.
b)
Interpretation:
Assuming Markovnikov’s rule is valid, the major alcohol product obtainable by the acid-catalyzed addition of water to methylidenecyclohexene is to be predicted.
Concept introduction:
Markovnikov’s rule can be used to decide on the orientation in electrophilic addition reactions. According to this rule, in the addition of HX to an alkene, the H attaches itself with the carbon with fewer alkyl substituents and the X attaches itself with the carbon with more alkyl substituents.
To state:
The major alcohol product obtainable by the acid-catalyzed addition of water to methylidenecyclohexene assuming that Markovnikov’s rule is valid.
c)
Interpretation:
Assuming Markovnikov’s rule is valid, the major alcohol product obtainable by the acid-catalyzed addition of water to 4- methyl-1-pentene is to be predicted.
Concept introduction:
Markovnikov’s rule can be used to decide on the orientation in electrophilic addition reactions. According to this rule, in the addition of HX to an alkene, the H attaches itself with the carbon with fewer alkyl substituents and the X attaches itself with the carbon with more alkyl substituents.
To state:
The major alcohol product obtainable by the acid-catalyzed addition of water to 4- methyl-1-pentene assuming that Markovnikov’s rule is valid.

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Chapter 7 Solutions
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