a) Interpretation: The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement. Concept introduction: In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the hydrogen of the alkyl halide to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give another more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide. To predict: The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Question

Draw all resonance structures for the following ion: CH₂ Draw all resonance structures on the canvas by choosing buttons from the Tools (for bonds), Atoms, and Advanced Template toolbars, including charges where needed. The single bond is active by default. 2D ד CONT HD EXP CON ? 1 [1] Α 12 Marvin JS by Chemaxon A DOO H C N Br I UZ OSPF

Answer 1

Question

Chapter 7.SE, Problem 27MP

Interpretation Introduction

a)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the hydrogen of the alkyl halide to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give another more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Interpretation Introduction

b)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the hydrogen of the alkyl halide to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give another more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Interpretation Introduction

c)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the H+ of the acid to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give a more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

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Draw all resonance structures for the following ion: CH₂ Draw all resonance structures on the canvas by choosing buttons from the Tools (for bonds), Atoms, and Advanced Template toolbars, including charges where needed. The single bond is active by default. 2D ד CONT HD EXP CON ? 1 [1] Α 12 Marvin JS by Chemaxon A DOO H C N Br I UZ OSPF

What is the average mass of the 10 pennies? Report your value with correct significant figures. What is the error (uncertainty) associated with each mass measurement due to the equipment? What is the uncertainty associated with the average value? Note that the uncertainty of the balance will propagate throughout the calculation. What is the standard deviation of the 10 mass measurements? Explain the difference between the propagated uncertainty and the standard deviation. Which number would you use to describe the uncertainty in the measurement? Calculate the total mass of the pennies with associated uncertainty. Calculate the average density of a penny based on these data. Propagate the uncertainty values for both mass and volume in your calculations.

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Answer 2

Question

Chapter 7.SE, Problem 27MP

Interpretation Introduction

a)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the hydrogen of the alkyl halide to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give another more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Interpretation Introduction

b)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the hydrogen of the alkyl halide to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give another more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Interpretation Introduction

c)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the H+ of the acid to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give a more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

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Answer 3

Question

Chapter 7.SE, Problem 27MP

Interpretation Introduction

a)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the hydrogen of the alkyl halide to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give another more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Interpretation Introduction

b)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the hydrogen of the alkyl halide to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give another more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Interpretation Introduction

c)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the H+ of the acid to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give a more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

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Answer 4

Question

Chapter 7.SE, Problem 27MP

Interpretation Introduction

a)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the hydrogen of the alkyl halide to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give another more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Interpretation Introduction

b)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the hydrogen of the alkyl halide to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give another more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Interpretation Introduction

c)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the H+ of the acid to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give a more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

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Answer 5

Chapter 7.SE, Problem 27MP

Interpretation Introduction

a)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the hydrogen of the alkyl halide to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give another more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Interpretation Introduction

b)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the hydrogen of the alkyl halide to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give another more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Interpretation Introduction

c)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the H+ of the acid to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give a more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Answer 6

Chapter 7.SE, Problem 27MP

Interpretation Introduction

a)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the hydrogen of the alkyl halide to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give another more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Answer 7

Chapter 7.SE, Problem 27MP

Interpretation Introduction

a)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the hydrogen of the alkyl halide to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give another more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Answer 8

Interpretation Introduction

b)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the hydrogen of the alkyl halide to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give another more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Answer 9

Interpretation Introduction

b)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the hydrogen of the alkyl halide to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give another more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Answer 10

Interpretation Introduction

c)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the H+ of the acid to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give a more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Answer 11

Interpretation Introduction

c)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the H+ of the acid to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give a more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Answer 12

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Answer 23

Ch. 7.2 - Calculate the degree of unsaturation in each of...Ch. 7.2 - Prob. 2P Ch. 7.2 - Diazepam, marketed as an antianxiety medication...Ch. 7.3 - Give IUPAC names for the following compounds:Ch. 7.3 - Prob. 5P Ch. 7.3 - Prob. 6P Ch. 7.3 - Prob. 7P Ch. 7.4 - Prob. 8P Ch. 7.4 - Prob. 9P Ch. 7.4 - Prob. 10P

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