Chemistry: An Introduction to General, Organic, and Biological Chemistry Plus Mastering Chemistry with Pearson eText -- Access Card Package (13th Edition)
13th Edition
ISBN: 9780134416793
Author: Karen C Timberlake
Publisher: PEARSON
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Textbook Question
Chapter 7.9, Problem 7.73PP
a. What is meant by the
b. Why does bread grow mold more quickly at room temperature than in the refrigerator?
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Students have asked these similar questions
Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 7 Solutions
Chemistry: An Introduction to General, Organic, and Biological Chemistry Plus Mastering Chemistry with Pearson eText -- Access Card Package (13th Edition)
Ch. 7.1 - What is a mole?Ch. 7.1 - What is Avogadro’s number?Ch. 7.1 - Calculate each of the following: a. number of C...Ch. 7.1 - Calculate each of the following: a. number of Li...Ch. 7.1 - Calculate each of the following quantities in 200...Ch. 7.1 - Calculate each of the following quantities in...Ch. 7.1 - Quinine, C20H24N2O2 , is a component of tonic...Ch. 7.1 - Aluminum sulphate, Al2SO43 , is used in some...Ch. 7.1 - Naproxen, found in Aleve, is used to treat the...Ch. 7.1 - Benadryl is an over-the-counter drug used to treat...
Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.2 - Calculate the molar mass for each of the...Ch. 7.3 - Calculate the mass, in grams, for each of the...Ch. 7.3 - Calculate the mass, in grams, for each of the...Ch. 7.3 - Calculate the mass, in grams, in 0.150 mole of...Ch. 7.3 - Calculate the mass, in grams, in 2.28 moles of...Ch. 7.3 - Calculate the number of moles in each of the...Ch. 7.3 - Calculate the number of moles in each of the...Ch. 7.3 - Calculate the number of moles in 25.0 g of each of...Ch. 7.3 - Calculate the number of moles in 4.00 g of each of...Ch. 7.3 - Chloroethane, C2H5Cl , is used to diagnose dead...Ch. 7.3 - Allyl sulfide, C3H52S , gives garlic, onions, and...Ch. 7.3 - a. The compound MgSO4 , Epsom salts, is used to...Ch. 7.3 - a. Cyclopropane, C3H6 , is an anesthetic given by...Ch. 7.3 - Dinitrogen oxide (or nitrous oxide), N2O , also...Ch. 7.3 - Chloroform, CHCl3 , was formerly used as an...Ch. 7.4 - Determine whether each of the following chemical...Ch. 7.4 - Determine whether each of the following chemical...Ch. 7.4 - Balance each of the following chemical equations:...Ch. 7.4 - Balance each of the following chemical equations:...Ch. 7.4 - Balance each of the following chemical equations:...Ch. 7.4 - Balance each of the following chemical equations:...Ch. 7.5 - Prob. 7.41PPCh. 7.5 - Prob. 7.42PPCh. 7.5 - Prob. 7.43PPCh. 7.5 - Prob. 7.44PPCh. 7.6 - Prob. 7.45PPCh. 7.6 - Prob. 7.46PPCh. 7.6 - In each of the following, identify the reactant...Ch. 7.6 - In each of the following, identify the reactant...Ch. 7.6 - Prob. 7.49PPCh. 7.6 - Prob. 7.50PPCh. 7.6 - Prob. 7.51PPCh. 7.6 - Prob. 7.52PPCh. 7.7 - Write all of the mole—mole factors for each of the...Ch. 7.7 - Write all of the mole—mole factors for each of the...Ch. 7.7 - The chemical reaction of hydrogen with oxygen...Ch. 7.7 - Ammonia is produced by the chemical reaction of...Ch. 7.7 - Carbon disulfide and carbon monoxide are produced...Ch. 7.7 - In the acetylene torch, acetylene gas C2H2 burns...Ch. 7.8 - Sodium reacts with oxygen to produce sodium oxide....Ch. 7.8 - Nitrogen gas reacts with hydrogen gas to produce...Ch. 7.8 - Ammonia and oxygen react to form nitrogen and...Ch. 7.8 - Iron(III) oxide reacts with carbon to give iron...Ch. 7.8 - Nitrogen dioxide and water react to produce nitric...Ch. 7.8 - Calcium cyanamide, CaCN2 , reads with water to...Ch. 7.8 - When solid lead(II) sulfide reacts with oxygen...Ch. 7.8 - When the gases dihydrogen sulfide and oxygen...Ch. 7.9 - Prob. 7.67PPCh. 7.9 - a. What is measured by the heat of reaction? b. In...Ch. 7.9 - Classify each of the following as exothermic or...Ch. 7.9 - Classify each of the following as exothermic or...Ch. 7.9 - Classify each of the following as exothermic or...Ch. 7.9 - Classify each of the following as exothermic or...Ch. 7.9 - a. What is meant by the rate of a reaction? b. Why...Ch. 7.9 - a. How does a catalyst affect the activation...Ch. 7.9 - Prob. 7.75PPCh. 7.9 - How would each of the following change the rate of...Ch. 7.9 - a. During cellular respiration, aqueous C6H12O6...Ch. 7.9 - Fatty acids undergo reaction with oxygen gas and...Ch. 7 - Prob. 7.79UTCCh. 7 - Using the models of the molecules (black = C,...Ch. 7 - A dandruff shampoo contains dipyrithione,...Ch. 7 - Ibuprofen, an anti-inflammatory drug in Advil, has...Ch. 7 - Prob. 7.83UTCCh. 7 - Balance each of the following by adding...Ch. 7 - Prob. 7.85UTCCh. 7 - Prob. 7.86UTCCh. 7 - If blue spheres represent nitrogen atoms, purple...Ch. 7 - Prob. 7.88UTCCh. 7 - Prob. 7.89UTCCh. 7 - Prob. 7.90UTCCh. 7 - Calculate the molar mass for each of the...Ch. 7 - Calculate the molar mass for each of the...Ch. 7 - How many grams are in 0.150 mole of each of the...Ch. 7 - How many grams are in 2.25 moles of each of the...Ch. 7 - How many moles are in 25.0 g of each of the...Ch. 7 - How many moles are in 4.00 g of each of the...Ch. 7 - Identify the type of reaction for each of the...Ch. 7 - Identify the type of reaction for each of the...Ch. 7 - Prob. 7.99APPCh. 7 - Prob. 7.100APPCh. 7 - Identify each of the following as an oxidation or...Ch. 7 - Identify each of the following as an oxidation or...Ch. 7 - When ammonia NH3 gas reacts with fluorine gas, the...Ch. 7 - When nitrogen dioxide NO2 gas from car exhaust...Ch. 7 - Pentane gas, C5H12 undergoes combustion with...Ch. 7 - Prob. 7.106APPCh. 7 - Prob. 7.107APPCh. 7 - The equation for the formation of nitrogen oxide...Ch. 7 - Prob. 7.109CPCh. 7 - Prob. 7.110CPCh. 7 - Prob. 7.111CPCh. 7 - A toothpaste contains 0.240% by mass sodium...Ch. 7 - Prob. 7.113CPCh. 7 - Prob. 7.114CPCh. 7 - Prob. 7.115CPCh. 7 - Prob. 7.116CP
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- Nonearrow_forwardPart II. Given below are the 'H-NMR spectrum at 300 MHz in CDC13 and mass spectrum using electron ionization of compound Brian. The FTIR of the said compound showed a strong peak at 1710 cm"). Determine the following: (a) molecular Formula and Degree of unsaturation of compound Brian (b) Basing on the given H-NMR spectrum tabulate the following (i) chemical shifts (ii) integration, ciii) multiplicity and (iv) interferences made for each signal (c) Draw the structure of compound Brian. ) ΕΙ 43 41 27 71 114 (M+) Hmmm 20 30 40 50 60 70 80 90 100 110 120 1H NMR spectrum 300 MHz in CDCl3 2.0 alle 1.0arrow_forwardThe iron-iron carbide phase diagram. In the diagram, the letter L indicates that it is a liquid. Indicate what its components are. Temperature (°C) 1600 10 Composition (at% C) 15 25 1538°C -1493°C 8 1400 1200 1394°C y+L L 2500 1147°C y. Austenite 2.14 4.30 2000 1000 912°C y + Fe3C 800ㅏ 0.76 0.022 600 a, Ferrite a + Fe3C 400 0 (Fe) Composition (wt% C) 727°C 1500 Cementite (Fe3C) 1000 6 6.70 Temperature (°F)arrow_forward
- Part V. Choose which isomer would give the 1H-NMR spectrum below. Justify your reasoning by assigning important signals to the Corresponding protons of the correct molecule. A D on of of of H H 88 2 90 7.8 7.6 7.4 80 5 6 [ppm] 7.2 6.8 6.6 6.4 ō [ppm]arrow_forwardShow work with explanation. don't give Ai generated solutionarrow_forwardQ7. a. Draw the line-bond structure of the major product for the following reaction, if a reaction occurs, assume monohalogenation. b. Calculate the product ratios using the following information (hint: use the number of hydrogens in each category present to calculate the ratios). Chlorination: 1° Reactivity=1 2° Reactivity=4 Heat + Cl2 3° Reactivity=5arrow_forward
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