1-Heptanol is synthesised using given synthetic scheme has to be shown. Concept introduction: The Lindlar catalyst is a deactivated hydrogenation catalyst that stops alkyne hydrogenation at the alkene stage, allowing conversion of alkynes to cis- alkenes . Hydroboration followed by an acid workup (instead of basic peroxide) also gives cis- alkenes from alkynes. Hydroboration–protonolysis is an alternative way to prepare a cis- alkene from an alkyne. Hydroboration–protonolysis is an alternative way to prepare a cis- alkene from an alkyne.

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MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10 Consider the following reaction: CH3OH(g) CO(g) + 2H2(g) (Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.) Part A Calculate AG for this reaction at 25 °C under the following conditions: PCH₂OH Pco PH2 0.815 atm = 0.140 atm 0.170 atm Express your answer in kilojoules to three significant figures. Ο ΑΣΦ AG = -150 Submit Previous Answers Request Answer □? kJ × Incorrect; Try Again; 2 attempts remaining Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship: AGrxn = AGrxn + RTInQ, AGxn+RTInQ, where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a is the reaction quotient. Provide Feedback Next >

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Chapter 7.9, Problem 7.6P

(a)

Interpretation Introduction

Interpretation:

1-Heptanol is synthesised using given synthetic scheme has to be shown.

Concept introduction:

The Lindlar catalyst is a deactivated hydrogenation catalyst that stops alkyne hydrogenation at the alkene stage, allowing conversion of alkynes to cis-alkenes. Hydroboration followed by an acid workup (instead of basic peroxide) also gives cis-alkenes from alkynes. Hydroboration–protonolysis is an alternative way to prepare a cis-alkene from an alkyne.

Hydroboration–protonolysis is an alternative way to prepare a cis-alkene from an alkyne.

(b)

Interpretation Introduction

Interpretation:

2-Heptanol is synthesised using given synthetic scheme has to be shown.

Concept introduction:

The Lindlar catalyst is a deactivated hydrogenation catalyst that stops alkyne hydrogenation at the alkene stage, allowing conversion of alkynes to cis-alkenes. Hydroboration followed by an acid workup (instead of basic peroxide) also gives cis-alkenes from alkynes. Hydroboration–protonolysis is an alternative way to prepare a cis-alkene from an alkyne.

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MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10 Consider the following reaction: CH3OH(g) CO(g) + 2H2(g) (Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.) Part A Calculate AG for this reaction at 25 °C under the following conditions: PCH₂OH Pco PH2 0.815 atm = 0.140 atm 0.170 atm Express your answer in kilojoules to three significant figures. Ο ΑΣΦ AG = -150 Submit Previous Answers Request Answer □? kJ × Incorrect; Try Again; 2 attempts remaining Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship: AGrxn = AGrxn + RTInQ, AGxn+RTInQ, where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a is the reaction quotient. Provide Feedback Next >

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