Chemistry
13th Edition
ISBN: 9781259911156
Author: Raymond Chang Dr., Jason Overby Professor
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 7.8, Problem 3RCF
Identify the error in each of the following sets of quantum numbers (n, ℓ, mℓ, ms): (a) 2, 0, −1,
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Naming and drawing secondary
Write the systematic (IUPAC) name for each of the following organic molecules:
CH3
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CH3
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CH2
N-CH3
CH3-CH2-CH2-CH-CH3
NH
CH3-CH-CH2-CH2-CH2-CH2-CH2-CH3
Explanation
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This question shows how molecular orbital (MO) theory can be used to understand the chemical
properties of elemental oxygen O₂ and its anionic derivative superoxide Oz.
a)
Draw the MO energy diagram for both O2 and O2. Clearly label your diagram with atomic orbital names
and molecular orbital symmetry labels and include electrons.
Draw the Lewis structure of O2. How does the MO description of O2 differ from the Lewis structure, and
how does this difference relate to the high reactivity and magnetic properties of oxygen?
) Use the MO diagram in (a) to explain the difference in bond length and bond energy between superoxide
ion (Oz, 135 pm, 360 kJ/mol) and oxygen (O2, 120.8 pm, 494 kJ/mol).
Please draw
Chapter 7 Solutions
Chemistry
Ch. 7.1 - What is the wavelength (in meters) of an...Ch. 7.1 - Which of the waves (a)(c) has (i) the highest...Ch. 7.1 - Why is radiation only in the UV but not the...Ch. 7.2 - The energy of a photon is 5.87 1020 J. What is...Ch. 7.2 - The work function of titanium metal is 6.93 1019...Ch. 7.2 - A photon has a frequency of 7.25 1014 s1....Ch. 7.2 - What is the wavelength (in nm) of a photon with...Ch. 7.2 - A clean metal surface is irradiated with light of...Ch. 7.3 - What is the wavelength (in nanometers) of a photon...Ch. 7.3 - Which transition in the hydrogen atom would emit...
Ch. 7.3 - What is the energy of an electron in the n = 4...Ch. 7.3 - What is the wavelength (in nm) of a photon emitted...Ch. 7.4 - Calculate the wavelength (in nanometers) of a H...Ch. 7.4 - Which quantity in Equation (7.8) is responsible...Ch. 7.4 - What is the wavelength (in nm) of a neutron...Ch. 7.5 - Estimate the uncertainty in the speed of an oxygen...Ch. 7.5 - What is the difference between and 2 for the...Ch. 7.5 - A proton is moving at a speed of 6.0 106 m/s. If...Ch. 7.6 - What are the allowed values for m when n = 5 and ...Ch. 7.6 - What are the allowed values of when n = 3?Ch. 7.6 - Give the four quantum numbers for each of the two...Ch. 7.7 - Give the values of the quantum numbers associated...Ch. 7.7 - What is the total number of orbitals associated...Ch. 7.7 - Why is it not possible to have a 2d orbital, but a...Ch. 7.7 - What are the n, , and m values for orbitals in the...Ch. 7.7 - How many orbitals are there in the 5f subshell?Ch. 7.8 - Write the four quantum numbers for an electron in...Ch. 7.8 - Prob. 11PECh. 7.8 - Write a complete set of quantum numbers for each...Ch. 7.8 - The ground-state electron configuration of an atom...Ch. 7.8 - Determine the maximum number of electrons that can...Ch. 7.8 - Identify the error in each of the following sets...Ch. 7.9 - Prob. 13PECh. 7.9 - What element is represented by the following...Ch. 7.9 - Identify the element that has the following...Ch. 7.9 - Write the electron configuration for an atom of...Ch. 7 - What is a wave? Explain the following terms...Ch. 7 - What are the units for wavelength and frequency of...Ch. 7 - List the types of electromagnetic radiation,...Ch. 7 - Give the high and low wavelength values that...Ch. 7 - Briefly explain Plancks quantum theory and explain...Ch. 7 - Prob. 7.6QPCh. 7 - (a) What is the wavelength (in nm) of light having...Ch. 7 - (a) What is the frequency of light having a...Ch. 7 - Prob. 7.9QPCh. 7 - How many minutes would it take a radio wave to...Ch. 7 - The SI unit of time is the second, which is...Ch. 7 - Prob. 7.12QPCh. 7 - What are photons? What role did Einsteins...Ch. 7 - Consider the plots shown here for the...Ch. 7 - A photon has a wavelength of 624 nm. Calculate the...Ch. 7 - The blue color of the sky results from the...Ch. 7 - A photon has a frequency of 6.0 104 Hz. (a)...Ch. 7 - What is the wavelength, in nm, of radiation that...Ch. 7 - When copper is bombarded with high-energy...Ch. 7 - A particular form of electromagnetic radiation has...Ch. 7 - The work function of potassium is 3.68 1019 J....Ch. 7 - When light of frequency equal to 2.11 1015 s1...Ch. 7 - (a) What is an energy level? Explain the...Ch. 7 - Prob. 7.24QPCh. 7 - Explain why elements produce their own...Ch. 7 - Prob. 7.26QPCh. 7 - Prob. 7.27QPCh. 7 - Explain how astronomers are able to tell which...Ch. 7 - Consider the following energy levels of a...Ch. 7 - Prob. 7.30QPCh. 7 - Calculate the wavelength (in nm) of a photon...Ch. 7 - Calculate the frequency (Hz) and wavelength (nm)...Ch. 7 - Prob. 7.33QPCh. 7 - An electron in the hydrogen atom makes a...Ch. 7 - Explain the statement, Matter and radiation have a...Ch. 7 - How does de Broglies hypothesis account for the...Ch. 7 - Why is Equation (7.8) meaningful only for...Ch. 7 - (a) If a H atom and a He atom are traveling at the...Ch. 7 - Prob. 7.39QPCh. 7 - Protons can be accelerated to speeds near that of...Ch. 7 - What is the de Broglie wavelength, in centimeters,...Ch. 7 - What is the de Broglie wavelength (in nm)...Ch. 7 - What are the inadequacies of Bohrs theory?Ch. 7 - What is the Heisenberg uncertainty principle? What...Ch. 7 - Prob. 7.45QPCh. 7 - How is the concept of electron density used to...Ch. 7 - Prob. 7.47QPCh. 7 - Which quantum number defines a shell? Which...Ch. 7 - Which of the following orbitals do not exist: 1p,...Ch. 7 - Which of the four quantum numbers (n, , m, ms)...Ch. 7 - Prob. 7.51QPCh. 7 - An electron in an atom is in the n = 3 quantum...Ch. 7 - Give the values of the quantum numbers associated...Ch. 7 - Give the values of the four quantum numbers of an...Ch. 7 - Prob. 7.55QPCh. 7 - List all the possible subshells and orbitals...Ch. 7 - What is an atomic orbital? How does an atomic...Ch. 7 - Describe the shapes of s, p, and d orbitals. How...Ch. 7 - List the hydrogen orbitals in increasing order of...Ch. 7 - Why is a boundary surface diagram useful in...Ch. 7 - Prob. 7.61QPCh. 7 - What is the difference between a 2px and a 2py...Ch. 7 - Calculate the total number of electrons that can...Ch. 7 - Prob. 7.64QPCh. 7 - Prob. 7.65QPCh. 7 - Indicate the total number of (a) p electrons in N...Ch. 7 - Make a chart of all allowable orbitals in the...Ch. 7 - Why do the 3s, 3p, and 3d orbitals have the same...Ch. 7 - For each of the following pairs of hydrogen...Ch. 7 - Which orbital in each of the following pairs is...Ch. 7 - What is electron configuration? Describe the roles...Ch. 7 - Prob. 7.72QPCh. 7 - Prob. 7.73QPCh. 7 - What is meant by the term shielding of electrons...Ch. 7 - Indicate which of the following sets of quantum...Ch. 7 - The ground-state electron configurations listed...Ch. 7 - The atomic number of an element is 73. Is this...Ch. 7 - Indicate the number of unpaired electrons present...Ch. 7 - State the Aufbau principle and explain the role it...Ch. 7 - Prob. 7.80QPCh. 7 - What is the noble gas core? 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