ORGANIC CHEMISTRY (LOOSELEAF)
ORGANIC CHEMISTRY (LOOSELEAF)
6th Edition
ISBN: 9781260475630
Author: SMITH
Publisher: MCG
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Chapter 7.8, Problem 15P
Interpretation Introduction

(a)

Interpretation: The stronger nucleophile out of Br and Cl in a polar protic solvent is to be identified.

Concept introduction: Solvent is required to dissolve the starting material in it. The substitution reaction involves polar starting reactant which is soluble in polar solvent. A solvent in which hydrogen atom is bonded to electronegative O or N atom is termed as polar protic solvent. The nucleophilicity of anion that has small size is higher than the anion that has larger size.

Interpretation Introduction

(b)

Interpretation: The stronger nucleophile out of Br and Cl in a polar aprotic solvent is to be identified.

Concept introduction: Solvent is required to dissolve the starting material in it. The substitution reaction involves polar starting reactant which is soluble in polar solvent. A solvent in which hydrogen atom is bonded to electronegative O or N atom is termed as polar protic solvent. However, in polar aprotic solvent, OH bond or NH is absent.

Interpretation Introduction

(c)

Interpretation: The stronger nucleophile out of HS and F in a polar protic solvent is to be identified.

Concept introduction: Solvent is required to dissolve the starting material in it. The substitution reaction involves polar starting reactant which is soluble in polar solvent. A solvent in which hydrogen atom is bonded to electronegative O or N atom is termed as polar protic solvent. The nucleophilicity of anion that has small size is higher than the anion that has larger size.

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