Concept explainers
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(a)
Interpretation:
For the given IUPAC name of the compound, bond-line structure has to be drawn and identified.
Concept introduction:
Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts in major namely Prefix suffix and root word.
Prefix represents the substituent present in the molecule and its position in the parent chain.
Suffix denotes the presence of
Root word represents the longest continuous carbon skeleton of the organic molecule.
The structure of a molecule can be drawn by analyzing the presence of prefix, suffix and root word in the given IUPAC name.
In bond-line structure the carbon atoms and the hydrogen atoms which are attached to that carbon atom are not to show, they are drawn as line segments. For acyclic carbon chains it draws as in a zig-zag fashion and for cyclic chains of carbon it draws as a cyclic polygon. For representing a heteroatom attached to the carbon, use a labelled line segment.
(b).
Interpretation:
For the given IUPAC name of the compound, bond-line structure has to be drawn and identified.
Concept introduction:
Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts in major namely Prefix suffix and root word.
Prefix represents the substituent present in the molecule and its position in the parent chain.
Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. The position of this fictional group is represented just before the root name.
Root word represents the longest continuous carbon skeleton of the organic molecule.
The structure of a molecule can be drawn by analyzing the presence of prefix, suffix and root word in the given IUPAC name.
In bond-line structure the carbon atoms and the hydrogen atoms which are attached to that carbon atom are not to show, they are drawn as line segments. For acyclic carbon chains it draws as in a zig-zag fashion and for cyclic chains of carbon it draws as a cyclic polygon. For representing a heteroatom attached to the carbon, use a labelled line segment.
(c).
Interpretation:
For the given IUPAC name of the compound, bond-line structure has to be drawn and identified.
Concept introduction:
Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts in major namely Prefix suffix and root word.
Prefix represents the substituent present in the molecule and its position in the parent chain.
Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. The position of this fictional group is represented just before the root name.
Root word represents the longest continuous carbon skeleton of the organic molecule.
The structure of a molecule can be drawn by analyzing the presence of prefix, suffix and root word in the given IUPAC name.
In bond-line structure the carbon atoms and the hydrogen atoms which are attached to that carbon atom are not to show, they are drawn as line segments. For acyclic carbon chains it draws as in a zig-zag fashion and for cyclic chains of carbon it draws as a cyclic polygon. For representing a heteroatom attached to the carbon, use a labelled line segment.
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Chapter 7 Solutions
KLEIN'S ORGANIC CHEMISTRY
- Predict the major products of this organic reaction: H OH 1. LiAlH4 2. H₂O ? Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. G C टेarrow_forwardFor each reaction below, decide if the first stable organic product that forms in solution will create a new C-C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. NH2 CI MgCl ? Will the first product that forms in this reaction create a new CC bond? Yes No MgBr ? Will the first product that forms in this reaction create a new CC bond? Yes No G टेarrow_forwardFor each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. དྲ。 ✗MgBr ? O CI Will the first product that forms in this reaction create a new C-C bond? Yes No • ? Will the first product that forms in this reaction create a new CC bond? Yes No × : ☐ Xarrow_forward
- Predict the major products of this organic reaction: OH NaBH4 H ? CH3OH Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. ☐ : Sarrow_forwardPredict the major products of this organic reaction: 1. LIAIHA 2. H₂O ? Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. X : ☐arrow_forwardFor each reaction below, decide if the first stable organic product that forms in solution will create a new C - C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. NH2 tu ? ? OH Will the first product that forms in this reaction create a new CC bond? Yes No Will the first product that forms in this reaction create a new CC bond? Yes No C $ ©arrow_forward
- As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C-C bond as its major product: 1. MgCl ? 2. H₂O* If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. This reaction will not make a product with a new CC bond. G marrow_forwardIncluding activity coefficients, find [Hg22+] in saturated Hg2Br2 in 0.00100 M NH4 Ksp Hg2Br2 = 5.6×10-23.arrow_forwardgive example for the following(by equation) a. Converting a water insoluble compound to a soluble one. b. Diazotization reaction form diazonium salt c. coupling reaction of a diazonium salt d. indacator properties of MO e. Diazotization ( diazonium salt of bromobenzene)arrow_forward
- 2-Propanone and ethyllithium are mixed and subsequently acid hydrolyzed. Draw and name the structures of the products.arrow_forward(Methanesulfinyl)methane is reacted with NaH, and then with acetophenone. Draw and name the structures of the products.arrow_forward3-Oxo-butanenitrile and (E)-2-butenal are mixed with sodium ethoxide in ethanol. Draw and name the structures of the products.arrow_forward
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