(a)
Interpretation:
The major and minor product must be predicted for the given E2 reaction.
Concept Introduction :
Unless the bulky base is used generally more substituted
(b)
Interpretation:
The major and minor products must be predicted for the given E2 reaction.
Concept Introduction :
In E2 reaction if bulky base is used, then hydrogen abstraction takes place from less hindered carbon.
(c)
Interpretation:
The major and minor products must be predicted for the given E2 reaction.
Concept Introduction :
Tertiary alkyl iodide undergoes E2 reaction to produce more substituted alkene as the major product.
(d)
Interpretation:
The major and minor products must be predicted for the given E2 reaction.
Concept Introduction :
The bulky base in E2 reaction produces less substituted alkene as the major product.
(e)
Interpretation:
The major and minor products must be identified for the given E2 reaction.
Concept Introduction :
The less bulky bases prefer to take hydrogen from more hindered carbon in order to produce most substituted alkene as the major product.
(f)
Interpretation:
The major and minor products must be identified for the given E2 reaction.
Concept Introduction :
The bulky bases prefer to take hydrogen from less hindered carbon in order to produce less substituted alkene as the major product.

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Chapter 7 Solutions
ORGANIC CHEMISTRY(EBOOK)-W/WILEYPLUS
- Potential Energy (kJ) 1. Consider these three reactions as the elementary steps in the mechanism for a chemical reaction. AH = -950 kJ AH = 575 kJ (i) Cl₂ (g) + Pt (s) 2C1 (g) + Pt (s) Ea = 1550 kJ (ii) Cl (g)+ CO (g) + Pt (s) → CICO (g) + Pt (s) (iii) Cl (g) + CICO (g) → Cl₂CO (g) Ea = 2240 kJ Ea = 2350 kJ AH = -825 kJ 2600 2400 2200 2000 1800 1600 1400 1200 1000 a. Draw the potential energy diagram for the reaction. Label the data points for clarity. The potential energy of the reactants is 600 kJ 800 600 400 200 0 -200- -400 -600- -800- Reaction Progressarrow_forwardCan u help me figure out the reaction mechanisms for these, idk where to even startarrow_forwardHi, I need your help with the drawing, please. I have attached the question along with my lab instructions. Please use the reaction from the lab only, as we are not allowed to use outside sources. Thank you!arrow_forward
- Hi, I need your help i dont know which one to draw please. I’ve attached the question along with my lab instructions. Please use the reaction from the lab only, as we are not allowed to use outside sources. Thank you!arrow_forward5. Write the formation reaction of the following complex compounds from the following reactants: 6. AgNO₃ + K₂CrO₂ + NH₄OH → 7. HgNO₃ + excess KI → 8. Al(NO₃)₃ + excess NaOH →arrow_forwardIndicate whether the product formed in the reaction exhibits tautomerism. If so, draw the structure of the tautomers. CO₂C2H5 + CH3-NH-NH,arrow_forward
- Draw the major product of this reaction N-(cyclohex-1-en-1-yl)-1-(pyrrolidino) reacts with CH2=CHCHO, heat, H3O+arrow_forwardDraw the starting material that would be needed to make this product through an intramolecular Dieckmann reactionarrow_forwardDraw the major product of this reaction. Nitropropane reacts + pent-3-en-2-one reacts with NaOCH2CH3, CH3CHOHarrow_forward
- Indicate whether the product formed in the reaction exhibits tautomerism. If so, draw the structure of the tautomers. OC2H5 + CoHs-NH-NH,arrow_forwardExplain how substitutions at the 5-position of barbituric acid increase the compound's lipophilicity.arrow_forwardExplain how substitutions at the 5-position of phenobarbital increase the compound's lipophilicity.arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning

