GENERAL,ORGANIC,+BIOCHEMISTRY
10th Edition
ISBN: 9781260148954
Author: Denniston
Publisher: RENT MCG
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Chapter 7.4, Problem 7.14Q
Interpretation Introduction
Interpretation:
If the rate of forward reaction in an equilibrium process is increased, the product formed will be increased, decreased, or remain the same has to be explained.
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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass
spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained.
Draw the structures of these fragments.
For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.
Chapter 7 Solutions
GENERAL,ORGANIC,+BIOCHEMISTRY
Ch. 7.1 - Prob. 7.1PPCh. 7.1 - Are the following processes exothermic or...Ch. 7.1 - Prob. 7.2QCh. 7.1 - Prob. 7.3QCh. 7.1 - Prob. 7.4QCh. 7.1 - Prob. 7.2PPCh. 7.1 - Predict whether a reaction with positive ΔH and...Ch. 7.1 - Prob. 7.6QCh. 7.2 - Prob. 7.3PPCh. 7.2 - Prob. 7.4PP
Ch. 7.2 - Prob. 7.7QCh. 7.2 - Prob. 7.8QCh. 7.2 - Prob. 7.5PPCh. 7.3 - Prob. 7.9QCh. 7.3 - Prob. 7.10QCh. 7.3 - Prob. 7.11QCh. 7.3 - Prob. 7.12QCh. 7.3 - Prob. 7.6PPCh. 7.4 - Prob. 7.13QCh. 7.4 - Prob. 7.14QCh. 7.4 - Prob. 7.15QCh. 7.4 - Prob. 7.16QCh. 7.4 - Prob. 7.7PPCh. 7.4 - Prob. 7.8PPCh. 7.4 - Prob. 7.17QCh. 7.4 - Prob. 7.18QCh. 7.4 - Prob. 7.9PPCh. 7.4 - Prob. 7.10PPCh. 7.4 - Prob. 7.11PPCh. 7 - Prob. 7.19QPCh. 7 - State the second law of thermodynamics.
Ch. 7 - Describe what is meant by an exothermic reaction.
Ch. 7 - Describe what is meant by an endothermic...Ch. 7 - Prob. 7.23QPCh. 7 - Prob. 7.24QPCh. 7 - Explain what is meant by the term free energy....Ch. 7 - Prob. 7.26QPCh. 7 - Prob. 7.27QPCh. 7 - Prob. 7.28QPCh. 7 - Predict whether each of the following processes...Ch. 7 - Predict whether each of the following processes...Ch. 7 - Prob. 7.31QPCh. 7 - Energy is required to break chemical bonds during...Ch. 7 - Prob. 7.33QPCh. 7 - Prob. 7.34QPCh. 7 - Prob. 7.35QPCh. 7 - Prob. 7.36QPCh. 7 - Prob. 7.37QPCh. 7 - Prob. 7.38QPCh. 7 - What are the energy units most commonly employed...Ch. 7 - What energy unit is commonly employed in nutrition...Ch. 7 - Prob. 7.41QPCh. 7 - Prob. 7.42QPCh. 7 - A 5.00-g sample of octane is burned in a bomb...Ch. 7 - Prob. 7.44QPCh. 7 - A 30-g sample of chips is burned in a bomb...Ch. 7 - Prob. 7.46QPCh. 7 - Prob. 7.47QPCh. 7 - Prob. 7.48QPCh. 7 - Prob. 7.49QPCh. 7 - Prob. 7.50QPCh. 7 - Prob. 7.51QPCh. 7 - Prob. 7.52QPCh. 7 - Prob. 7.53QPCh. 7 - Prob. 7.54QPCh. 7 - Prob. 7.55QPCh. 7 - Lactase is an enzyme featured in Chapter 16,...Ch. 7 - Prob. 7.57QPCh. 7 - Prob. 7.58QPCh. 7 - Prob. 7.59QPCh. 7 - Prob. 7.60QPCh. 7 - Prob. 7.61QPCh. 7 - Prob. 7.62QPCh. 7 - Prob. 7.63QPCh. 7 - Prob. 7.64QPCh. 7 - For the equilibrium
the rate law is:
at 23°C, k...Ch. 7 - Prob. 7.66QPCh. 7 - Prob. 7.67QPCh. 7 - Prob. 7.68QPCh. 7 - Prob. 7.69QPCh. 7 - Prob. 7.70QPCh. 7 - Prob. 7.71QPCh. 7 - Prob. 7.72QPCh. 7 - Prob. 7.73QPCh. 7 - Label each of the following statements as true or...Ch. 7 - Prob. 7.75QPCh. 7 - Prob. 7.76QPCh. 7 - Prob. 7.77QPCh. 7 - Prob. 7.78QPCh. 7 - Prob. 7.79QPCh. 7 - Prob. 7.80QPCh. 7 - Prob. 7.81QPCh. 7 - Prob. 7.82QPCh. 7 - Prob. 7.83QPCh. 7 - Prob. 7.84QPCh. 7 - Prob. 7.85QPCh. 7 - Prob. 7.86QPCh. 7 - Prob. 7.87QPCh. 7 - Prob. 7.88QPCh. 7 - Prob. 7.89QPCh. 7 - Prob. 7.90QPCh. 7 - Prob. 7.91QPCh. 7 - Prob. 7.92QPCh. 7 - Prob. 7.93QPCh. 7 - Prob. 7.94QPCh. 7 - Prob. 7.95QPCh. 7 - Prob. 7.96QPCh. 7 - Prob. 7.97QPCh. 7 - Prob. 7.98QPCh. 7 - Prob. 7.99QPCh. 7 - Prob. 7.100QPCh. 7 - Prob. 7.101QPCh. 7 - Prob. 7.102QPCh. 7 - Prob. 7.103QPCh. 7 - Prob. 7.104QPCh. 7 - Prob. 7.105QPCh. 7 - Prob. 7.106QPCh. 7 - Prob. 1MCPCh. 7 - Prob. 2MCPCh. 7 - Prob. 3MCPCh. 7 - Prob. 4MCPCh. 7 - Prob. 7MCPCh. 7 - Prob. 9MCPCh. 7 - Prob. 10MCP
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