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Science Chemistry ORGANIC CHEMISTRY-W/STUD.SOLN.MAN.

The major product, out of two alkenes obtained by acid-catalyzed dehydration of each of the given alcohols, is to be identified on the basis of Zaitsev rule. Concept introduction: > The dehydration of alcohol results in the loss of molecule and formation of the corresponding alkene. > The H and OH are lost from adjacent carbons. > In case of primary alcohols, only one product is formed, but in case of secondary and tertiary alcohols, there is a possibility of more than one product formation whenthecarbon attached to the OH group is bonded to nonequivalent adjacent carbons. > According to Zaitsev rule, the most substituted alkene is the major product.

The major product, out of two alkenes obtained by acid-catalyzed dehydration of each of the given alcohols, is to be identified on the basis of Zaitsev rule. Concept introduction: > The dehydration of alcohol results in the loss of molecule and formation of the corresponding alkene. > The H and OH are lost from adjacent carbons. > In case of primary alcohols, only one product is formed, but in case of secondary and tertiary alcohols, there is a possibility of more than one product formation whenthecarbon attached to the OH group is bonded to nonequivalent adjacent carbons. > According to Zaitsev rule, the most substituted alkene is the major product.

Solution Summary: The author explains the major product, out of two alkenes obtained by acid-catalyzed dehydration of each of the given alcohols, according to Zaitsev rule.

ORGANIC CHEMISTRY-W/STUD.SOLN.MAN.

ORGANIC CHEMISTRY-W/STUD.SOLN.MAN.

10th Edition

ISBN: 9781260001099

Author: Carey

Publisher: MCG

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Question

Chapter 7.10, Problem 17P

Interpretation Introduction

Interpretation:

The major product, out of two alkenes obtained by acid-catalyzed dehydration of each of the given alcohols, is to be identified on the basis of Zaitsev rule.

Concept introduction:
>
The dehydration of alcohol results in the loss of molecule and formation of the corresponding alkene.
>
The H and OH are lost from adjacent carbons.
>
In case of primary alcohols, only one product is formed, but in case of secondary and tertiary alcohols, there is a possibility of more than one product formation whenthecarbon attached to the OH group is bonded to nonequivalent adjacent carbons.
>
According to Zaitsev rule, the most substituted alkene is the major product.

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Chapter 7.9, Problem 16P

Chapter 7.11, Problem 18P

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Chapter 7 Solutions

ORGANIC CHEMISTRY-W/STUD.SOLN.MAN.

Ch. 7.1 - Name each of the following using IUPAC...Ch. 7.1 - Prob. 2P Ch. 7.2 - How many carbon atoms are sp2-hybridized in the...Ch. 7.3 - Prob. 4P Ch. 7.3 - Are cis-2-hexene and trans-3-hexene stereoisomers?...Ch. 7.4 - Prob. 6P Ch. 7.4 - Prob. 7P Ch. 7.4 - Give the IUPAC name of each of the compounds in...Ch. 7.5 - Arrange the following in order of increasing...Ch. 7.6 - Prob. 10P

Ch. 7.6 - Standard enthalpies of formation are known for all...Ch. 7.6 - Prob. 12P Ch. 7.6 - Despite numerous attempts, the alkene...Ch. 7.6 - Write structural formulas for the six isomeric...Ch. 7.7 - Place a double bond in the carbon skeleton shown...Ch. 7.9 - Identify the alkene obtained on dehydration of...Ch. 7.10 - Prob. 17P Ch. 7.11 - Prob. 18P Ch. 7.12 - Prob. 19P Ch. 7.13 - The alkene mixture obtained on dehydration of...Ch. 7.14 - Write the structures of all the alkenes that can...Ch. 7.14 - Write structural formulas for all the alkenes that...Ch. 7.15 - A study of the hydrolysis behavior of...Ch. 7.15 - Use curved arrows to illustrate the electron flow...Ch. 7.15 - Predict the major product of the reaction shown.Ch. 7.16 - Prob. 26P Ch. 7.17 - Prob. 27P Ch. 7.18 - Prob. 28P Ch. 7.19 - Predict the major organic product of each of the...Ch. 7.19 - A standard method for the synthesis of ethers is...Ch. 7 - Write structural formulas for each of the...Ch. 7 - Prob. 32P Ch. 7 - Give an IUPAC name for each of the following...Ch. 7 - A hydrocarbon isolated from fish oil and from...Ch. 7 - Prob. 35P Ch. 7 - Prob. 36P Ch. 7 - Prob. 37P Ch. 7 - Prob. 38P Ch. 7 - Choose the more stable alkene in each of the...Ch. 7 - Suggest an explanation for the fact that...Ch. 7 - Prob. 41P Ch. 7 - Write structural formulas for all the alkene...Ch. 7 - Prob. 43P Ch. 7 - Prob. 44P Ch. 7 - Predict the major organic product of each of the...Ch. 7 - Prob. 46P Ch. 7 - Prob. 47P Ch. 7 - The rate of the reaction In the first order in...Ch. 7 - Prob. 49P Ch. 7 - Prob. 50P Ch. 7 - You have available 2,2-dimethylcyclopentanol (A)...Ch. 7 - Prob. 52P Ch. 7 - Prob. 53P Ch. 7 - Prob. 54P Ch. 7 - Acid-catalyzed dehydration of...Ch. 7 - The ratio of elimination to substitution is...Ch. 7 - Prob. 57P Ch. 7 - Prob. 58DSP Ch. 7 - Prob. 59DSP Ch. 7 - Prob. 60DSP Ch. 7 - Prob. 61DSP Ch. 7 - A Mechanistic Preview of Addition Reactions The...Ch. 7 - Prob. 63DSP Ch. 7 - Prob. 64DSP Ch. 7 - Prob. 65DSP

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