Chemistry: An Introduction to General, Organic, and Biological Chemistry, Books a la Carte Edition & Modified MasteringChemistry with Pearson eText -- ValuePack Access Card Package
1st Edition
ISBN: 9780133899573
Author: Karen C. Timberlake
Publisher: PEARSON
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Textbook Question
Chapter 7.1, Problem 7.1QAP
What is a mole?
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You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you
manipulated and exploited the acid-base chemistry of one or more of the compounds in your
mixture to facilitate their separation into different phases. The key to understanding how liquid-
liquid extractions work is by knowing which layer a compound is in, and in what protonation state.
The following liquid-liquid extraction is different from the one you performed in Experiment
4, but it uses the same type of logic. Your task is to show how to separate apart Compound
A and Compound B.
. Complete the following flowchart of a liquid-liquid extraction. Handwritten work is
encouraged.
•
Draw by hand (neatly) only the appropriate organic compound(s) in the boxes.
.
Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4
and 5.
•
Box 7a requires the solvent (name is fine).
•
Box 7b requires one inorganic compound.
• You can neatly complete this assignment by hand and…
b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;'
The compound has the ff electronic transitions: 0%o* and no a*
1H NMR Spectrum
(CDCl3, 400 MHz)
3.5
3.0
2.5
2.0
1.5
1.0
0.5 ppm
13C{H} NMR Spectrum
(CDCl3, 100 MHz)
Solvent
80
70
60
50
40
30
20
10
0 ppm
ppm
¹H-13C me-HSQC Spectrum
ppm
(CDCl3, 400 MHz)
5
¹H-¹H COSY Spectrum
(CDCl3, 400 MHz)
0.5
10
3.5
3.0
2.5
2.0
1.5 1.0
10
15
20
20
25
30
30
-35
-1.0
1.5
-2.0
-2.5
3.0
-3.5
0.5
ppm
3.5
3.0
2.5
2.0
1.5
1.0
0.5
ppm
Show work with explanation. don't give Ai generated solution
Chapter 7 Solutions
Chemistry: An Introduction to General, Organic, and Biological Chemistry, Books a la Carte Edition & Modified MasteringChemistry with Pearson eText -- ValuePack Access Card Package
Ch. 7.1 - What is a mole?Ch. 7.1 - What is Avogadro’s number?Ch. 7.1 - Calculate each of the following: a. number of C...Ch. 7.1 - Calculate each of the following: a. number of Li...Ch. 7.1 - Calculate each of the following quantities in 200...Ch. 7.1 - Calculate each of the following quantities in...Ch. 7.1 - Prob. 7.7QAPCh. 7.1 - Aluminum sulphate, Al2SO43 , is used in some...Ch. 7.2 - Prob. 7.9QAPCh. 7.2 - Prob. 7.10QAP
Ch. 7.2 - Prob. 7.11QAPCh. 7.2 - Prob. 7.12QAPCh. 7.2 - Prob. 7.13QAPCh. 7.2 - Prob. 7.14QAPCh. 7.2 - Prob. 7.15QAPCh. 7.2 - Prob. 7.16QAPCh. 7.2 - Prob. 7.17QAPCh. 7.2 - Prob. 7.18QAPCh. 7.2 - Prob. 7.19QAPCh. 7.2 - Prob. 7.20QAPCh. 7.2 - Prob. 7.21QAPCh. 7.2 - Prob. 7.22QAPCh. 7.2 - Prob. 7.23QAPCh. 7.2 - Prob. 7.24QAPCh. 7.2 - Prob. 7.25QAPCh. 7.2 - Prob. 7.26QAPCh. 7.3 - Determine whether each of the following chemical...Ch. 7.3 - Determine whether each of the following chemical...Ch. 7.3 - Balance each of the following chemical equations:...Ch. 7.3 - Balance each of the following chemical equations:...Ch. 7.3 - Balance each of the following chemical equations:...Ch. 7.3 - Balance each of the following chemical equations:...Ch. 7.4 - Prob. 7.33QAPCh. 7.4 - Prob. 7.34QAPCh. 7.4 - Prob. 7.35QAPCh. 7.4 - Prob. 7.36QAPCh. 7.4 - Prob. 7.37QAPCh. 7.4 - Prob. 7.38QAPCh. 7.5 - Prob. 7.39QAPCh. 7.5 - Prob. 7.40QAPCh. 7.5 - In each of the following, identify the reactant...Ch. 7.5 - In each of the following, identify the reactant...Ch. 7.5 - Prob. 7.43QAPCh. 7.5 - Prob. 7.44QAPCh. 7.5 - Prob. 7.45QAPCh. 7.5 - Prob. 7.46QAPCh. 7.6 - Write all of the mole—mole factors for each of the...Ch. 7.6 - Write all of the mole—mole factors for each of the...Ch. 7.6 - The chemical reaction of hydrogen with oxygen...Ch. 7.6 - Prob. 7.50QAPCh. 7.6 - Carbon disulfide and carbon monoxide are produced...Ch. 7.6 - Prob. 7.52QAPCh. 7.7 - Sodium reacts with oxygen to produce sodium oxide....Ch. 7.7 - Nitrogen gas reacts with hydrogen gas to produce...Ch. 7.7 - Ammonia and oxygen react to form nitrogen and...Ch. 7.7 - Iron(III) oxide reacts with carbon to give iron...Ch. 7.7 - Nitrogen dioxide and water react to produce nitric...Ch. 7.7 - Calcium cyanamide, CaCN2 , reads with water to...Ch. 7.7 - Prob. 7.59QAPCh. 7.7 - When the gases dihydrogen sulfide and oxygen...Ch. 7.8 - Prob. 7.61QAPCh. 7.8 - Prob. 7.62QAPCh. 7.8 - Classify each of the following as exothermic or...Ch. 7.8 - Classify each of the following as exothermic or...Ch. 7.8 - Classify each of the following as exothermic or...Ch. 7.8 - Classify each of the following as exothermic or...Ch. 7.8 - a. What is meant by the rate of a reaction? b. Why...Ch. 7.8 - a. How does a catalyst affect the activation...Ch. 7.8 - Prob. 7.69QAPCh. 7.8 - How would each of the following change the rate of...Ch. 7 - Prob. 7.71UTCCh. 7 - Using the models of the molecules (black = C,...Ch. 7 - A dandruff shampoo contains dipyrithione,...Ch. 7 - Ibuprofen, an anti-inflammatory drug in Advil, has...Ch. 7 - Prob. 7.75UTCCh. 7 - Balance each of the following by adding...Ch. 7 - Prob. 7.77UTCCh. 7 - Prob. 7.78UTCCh. 7 - If blue spheres represent nitrogen atoms, purple...Ch. 7 - Prob. 7.80UTCCh. 7 - Prob. 7.81UTCCh. 7 - Prob. 7.82UTCCh. 7 - Calculate the molar mass for each of the...Ch. 7 - Calculate the molar mass for each of the...Ch. 7 - How many grams are in 0.150 mole of each of the...Ch. 7 - How many grams are in 2.25 moles of each of the...Ch. 7 - How many moles are in 25.0 g of each of the...Ch. 7 - How many moles are in 4.00 g of each of the...Ch. 7 - Identify the type of reaction for each of the...Ch. 7 - Identify the type of reaction for each of the...Ch. 7 - Prob. 7.91AQAPCh. 7 - Prob. 7.92AQAPCh. 7 - Prob. 7.93AQAPCh. 7 - Prob. 7.94AQAPCh. 7 - Identify each of the following as an oxidation or...Ch. 7 - Prob. 7.96AQAPCh. 7 - When ammonia NH3 gas reacts with fluorine gas, the...Ch. 7 - When nitrogen dioxide NO2 gas from car exhaust...Ch. 7 - Pentane gas, C5H12 undergoes combustion with...Ch. 7 - Prob. 7.100AQAPCh. 7 - Prob. 7.101AQAPCh. 7 - The equation for the formation of nitrogen oxide...Ch. 7 - Prob. 7.103CQCh. 7 - Prob. 7.104CQCh. 7 - Prob. 7.105CQCh. 7 - A toothpaste contains 0.240% by mass sodium...Ch. 7 - Prob. 7.107CQCh. 7 - Prob. 7.108CQCh. 7 - Prob. 7.109CQCh. 7 - Prob. 7.110CQ
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- Redraw the flowchartarrow_forwardredraw the flowchart with boxes and molecules written in themarrow_forwardPart I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward
- • Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peakarrow_forwardCould you redraw these and also explain how to solve them for me pleasarrow_forwardNonearrow_forward
- Draw the curved-arrow mechanism with the drawings of the molecules, not just abbreviations. -NO₂ Sn, HCl (aq) E D H (CH3CO)₂O -NH2 CH3arrow_forwardWhat is/are the product(s) of the following reaction? Select all that apply. * HI A B C OD OH A B OH D Carrow_forwardIn the image, the light blue sphere represents a mole of hydrogen atoms, the purple or teal spheres represent a mole of a conjugate base. A light blue sphere by itself is H+. Assuming there is 2.00 L of solution, answer the following: The Ka of the left & right solution is? The pH of the left & right solution is? The acid on the left & right is what kind of acid?arrow_forward
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