Chemistry: Structure and Properties
1st Edition
ISBN: 9780321834683
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 7, Problem 9E
Interpretation Introduction
Interpretation:
“Double bond according to
Concept introduction:
A double bond is formed between two atoms when there are two bonds one sigma and one pi bond. The sigma bond is formed due to head to head overlapping of two hybrid orbitals while pi bond is formed due to sideways overlapping of two orbitals.
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Please predict the products for each of the
following reactions.
Clearly show the regiochemistry (Markovnikov
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(syn- vs anti- or both).
If a mixture of enantiomers is formed, please
draw all the enantiomers.
cold
KMnO4, NaOH
2. DMS
1. 03
CH3OH
Br2
1.
03
2. (CH3)2S
H₂
Pd or Pt (catalyst)
HBr
18
19
20 1
HBr
ROOR (peroxide)
H₂O
H₂SO4
HCI
HI
17
16
6
15
MCPBA
1. BH3 THF
2. H₂O2, NaOH
1. OsO4
2. H₂O₂
110
CH3CO₂H
(peroxyacid)
1. MCPBA
2. H₂O*
Br2
H₂O
BH3 THF
B12
EtOH
Pd or Ni (catalyst)
D₂ (deuterium)
Bra
A
B
C
D
H
OH
H
OH
OH
H
OH
α α α
OH
H
OH
OH
фон
d
H
"H
Briefly indicate the models that describe the structure of the interface: Helmholtz-Perrin, Gouy-Chapman, Stern and Grahame models.
Electrochemistry. Briefly describe the Gibbs model and the Gibbs absorption equation.
Chapter 7 Solutions
Chemistry: Structure and Properties
Ch. 7 - Determine the hybridization about 0 in CH3OH.Ch. 7 - Determine the hybridization about C in H2CO.Ch. 7 - According to the valance bond theory, which kind...Ch. 7 - Use molecular orbital theory to determine the bond...Ch. 7 - Use molecular orbital theory to predict which...Ch. 7 - Use molecular orbital theory to determine which...Ch. 7 - Which hybridization scheme occurs about nitrogen...Ch. 7 - Prob. 8SAQCh. 7 - Prob. 9SAQCh. 7 - Prob. 10SAQ
Ch. 7 - Which type of orbitals overlap to form the sigma...Ch. 7 - Prob. 12SAQCh. 7 - Prob. 1ECh. 7 - What is a chemical bond according to valence bond...Ch. 7 - In valence bond theory, what determines the...Ch. 7 - In valence bond theory, the interaction energy...Ch. 7 - What is hybridization? Why is hybridization...Ch. 7 - How does hybridization of the atomic orbitals in...Ch. 7 - How is the number of hybrid orbitals related to...Ch. 7 - Sketch each hybrid orbital sp sp2 sp3 sp3d sp3d2Ch. 7 - Prob. 9ECh. 7 - Name the hybridization scheme that corresponds to...Ch. 7 - What is a chemical bond according to molecular...Ch. 7 - Explain the difference between hybrid atomic...Ch. 7 - What is a bonding molecular orbital?Ch. 7 - Prob. 14ECh. 7 - What is the role of wave interference in...Ch. 7 - Prob. 16ECh. 7 - Prob. 17ECh. 7 - Prob. 18ECh. 7 - Prob. 19ECh. 7 - Prob. 20ECh. 7 - Prob. 21ECh. 7 - When applying molecular orbital theory to...Ch. 7 - In molecular orbital theory, what is a nonbonding...Ch. 7 - Write a short paragraph describing chemical...Ch. 7 - Prob. 25ECh. 7 - Prob. 26ECh. 7 - Prob. 27ECh. 7 - Prob. 28ECh. 7 - Prob. 29ECh. 7 - Prob. 30ECh. 7 - The valence electron configurations of several...Ch. 7 - The valence electron configurations of several...Ch. 7 - Draw orbital diagrams (boxes with arrows in them)...Ch. 7 - Draw orbital diagrams (boxes with arrows in them)...Ch. 7 - Prob. 35ECh. 7 - Draw orbital diagrams (boxes with arrows in them)...Ch. 7 - Which hybridization scheme allows the formation of...Ch. 7 - Which hybridization scheme allows the central atom...Ch. 7 - Write a hybridization and bonding scheme for each...Ch. 7 - Write a hybridization and bonding scheme for each...Ch. 7 - Write a hybridization and bonding scheme for each...Ch. 7 - Write a hybridization and bonding scheme for each...Ch. 7 - Write a hybridization and bonding scheme for each...Ch. 7 - Write a hybridization and bonding scheme for each...Ch. 7 - Consider the structure of the amino acid alanine...Ch. 7 - Consider the structure of the amino acid aspartic...Ch. 7 - Sketch the bonding molecular orbital that results...Ch. 7 - Sketch the antibonding molecular orbital that...Ch. 7 - Draw an MO energy diagram and predict the bond...Ch. 7 - Draw an MO energy diagram and predict the bond...Ch. 7 - Sketch the bonding and antibonding molecular...Ch. 7 - Sketch the bonding and antibonding molecular...Ch. 7 - Using the molecular orbital energy ordenng for...Ch. 7 - Using the molecular orbital energy ordering for...Ch. 7 - Apply molecular orbital theory to predict if each...Ch. 7 - Apply molecular orbital theory to predict if each...Ch. 7 - According to MO theory, which molecule or ion has...Ch. 7 - According to MO theory, which molecule or ion has...Ch. 7 - Draw an MO energy diagram for CO. (Use the energy...Ch. 7 - Draw an MO energy diagram for HCI. Predict the...Ch. 7 - Prob. 61ECh. 7 - Prob. 62ECh. 7 - Prob. 63ECh. 7 - Prob. 64ECh. 7 - Prob. 65ECh. 7 - Prob. 66ECh. 7 - For each compound, draw the Lewis structure,...Ch. 7 - For each compound, draw the Lewis structure,...Ch. 7 - Amino acids are biological compounds that link...Ch. 7 - The genetic code is based on four different bases...Ch. 7 - The structure of caffeine, present in coffee and...Ch. 7 - The structure of acetylsalicylic acid (aspirin) is...Ch. 7 - Draw a molecular orbital energy diagram for CIF....Ch. 7 - Draw Lewis structures and MO diagrams for CN+, CN,...Ch. 7 - Bromine can form compounds or ions with any number...Ch. 7 - The compound C3H4 has two double bonds. Describe...Ch. 7 - How many hybrid orbitals do we use to describe...Ch. 7 - Prob. 78ECh. 7 - In VSEPR theory, which uses the Lewis model to...Ch. 7 - The resuts of a molecular orbital calculation for...Ch. 7 - Prob. 81ECh. 7 - cis-2-Butene isomerizes (changes its structure) to...Ch. 7 - The ion CH5 + can form under very special...Ch. 7 - Neither the VSEPR model nor the hybridization...Ch. 7 - Prob. 85ECh. 7 - The most stable forms of the nonmetals in groups...Ch. 7 - Consider the bond energies of three iodine...Ch. 7 - How many atomic orbitals form a set of sp3hybrid...
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